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排序方式: 共有5603条查询结果,搜索用时 15 毫秒
1.
A new aqueous slurry-based laminated object manufacturing process for porous ceramics is proposed: firstly, an organic mesh sheet is pre-paved as a pore-forming template before slurry layer scraping; secondly, the 2D pattern is built with laser outline cutting of the dried mesh–ceramic composite layer; finally, the pore structure is formed after degreasing and sintering. Alumina parts with porosities of 51.5 %, round hole diameters of 80 ± 5 μm were fabricated using 70 wt. % solid content slurry and 100 mesh nylon net. Using an organic mesh as the framework and template not only reduces the risk of damage of the green body but also ensures the regularity, uniformity and connectivity of the micron scaled pore network. The layer-by-layer drying method avoids the delamination phenomenon and improves the paving density. The new method can realize the flexible design of the pore structure by using various organic mesh templates. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(33):15084-15093
The effect of ammonia (NH3) contained in hydrogen (H2) gas on hydrogen environment embrittlement (HEE) of SCM440 low-alloy steel was studied in association with the NH3 concentration, loading rate, and gas pressure. NH3 worked as both mitigator of the HEE and inducer of hydrogen embrittlement (HE) depending on the testing conditions. The mitigation of the HEE was achieved by the deactivation of the iron (Fe) surface for H2 dissociation caused by the preferential adsorption of NH3 on the Fe surface, which is enhanced by the increase in the NH3 concentration and decrease in the H2 gas pressure. NH3 induced HE was caused due to creating hydrogen by the NH3 decomposition. Since the NH3 decomposition rate is low, the induction effect was observed when the loading rate was low. The effect of NH3 was determined by the competition of the mitigation and induction effects. 相似文献
3.
《Ceramics International》2022,48(14):20158-20167
Vacuum induction melting is a potential process for the preparation of TiAl alloys with good homogeneity and low cost. But the crucial problem is a selection of high stability refractory. In this study, a BaZrO3/Y2O3 dual-phase refractory was prepared and its performance for melting TiAl alloys was studied and compared with that of a Y2O3 refractory. The results showed the dual-phase refractory consisted of BaZr1-xYxO3-δ and Y2O3(ZrO2), exhibited a thinner interaction layer (30 μm) than the Y2O3 refractory (90 μm) after melting the TiAl alloy. Although the TiAl alloys melted in the dual-phase and Y2O3 refractory exhibited similar oxygen contamination (<0.1 wt%), the alloy melted in the dual-phase refractory had smaller Y2O3 inclusion content and size than that in the Y2O3 refractory, indicating that the dual-phase refractory exhibited a better melting performance than the Y2O3 refractory. This study provides insights into the process of designing highly stable refractory for melting TiAl alloys. 相似文献
4.
Jinfeng Zeng Zhiting Liu Hanbo Zou Wei Yang Haosen Fan Haijun Yu Shengzhou Chen 《金属学报(英文版)》2021,34(8):1153-1162
A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion. 相似文献
5.
Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor
In this paper, nitrogen-doped hierarchical porous carbon (N-HPC) was prepared from polyaniline (PANI)/silica self-aggregates. H-bonding between N-H groups in aniline/PANI and -OH groups in nano silica template led to a self-assembly type, which enabled the formation of uniform N-HPC nanoparticles. Silica self-aggregates provided macroporous channels resulted in a decreased diffusion distance. After removing the hard template, the N-HPC had a high surface area (899 m2·g-1). Owing to two co-existed synergetic energy-storage mechanisms and the hierarchical porous structure, the obtained N-HPC exhibited a high specific capacitance of 218.75 F·g-1 at 0.5 A·g-1, compared with the nonporous nitrogen-doped carbon (N-C) derived from pure PANI. Moreover, the N-HPC electrode demonstrated excellent cycle life, retaining 99% of its initial specific capacitance after 1000 cycles. 相似文献
6.
Jiming Xu Howard M. Heys 《International Journal of Circuit Theory and Applications》2019,47(6):971-990
Side-channel attacks have shown to be efficient tools in breaking cryptographic hardware. Many conventional algorithms have been proposed to perform side-channel attacks exploiting the dynamic power leakage. In recent years, with the development of processing technology, static power has emerged as a new potential source for side-channel leakage. Both types of power leakage have their advantages and disadvantages. In this work, we propose to use the deep neural network technique to combine the benefits of both static and dynamic power. This approach replaces the classifier in template attacks with our proposed long short-term memory network schemes. Hence, instead of deriving a specific probability density model for one particular type of power leakage, we gain the ability of combining different leakage sources using a structural algorithm. In this paper, we propose three schemes to combine the static and dynamic power leakage. The performance of these schemes is compared using simulated test circuits designed with a 45-nm library. 相似文献
7.
Mohamed R. Rizk Muhammad G. Abd El-Moghny 《International Journal of Hydrogen Energy》2021,46(1):645-655
We report on glycerol electro-oxidation in alkaline medium at macroporous Ni electrodes decorated with Cu particles. Macroporous Ni film is electrodeposited, using hydrogen bubbles as dynamic templates, atop of a Cu substrate. This film shows good electrocatalytic activity towards glycerol oxidation reaction (GOR). The Ni film is further decorated with Cu via spontaneous deposition from CuSO4 solution. This is done to enhance the catalytic activity of the film towards GOR. The morphology of the Cu-decorated Ni film is controlled using various additives such as KCl and (NH4)2SO4 which are added to the Cu deposition bath. The as-prepared Cu-decorated Ni films are characterized by electrochemical measurements, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). It is found that these additives have tremendous effects on the morphology and the electrocatalytic activity of the decorating Cu particles.The decorated Ni foam showed superior electrocatalytic activity towards the GOR, as confirmed by the negative shift in the onset oxidation potential (ca. 100 mV) together with an increase in oxidation current that is up to 1.5-fold during the cyclic voltammetry (CV) measurements, compared to the undecorated Ni foam. 相似文献
8.
介绍了采用软模板法和硬模板法制备介孔TiO_2的方法及其优缺点。软模板法和硬模板法制备介孔TiO_2的原理都是先将钛前驱体与模板进行组装,再通过焙烧等方式去除模板得到介孔结构。二者之间的区别在于所使用的模板不同,软模板容易得到,种类较多且方法简单,但不易控制介孔的结构;硬模板虽然种类较少,但胜在可以控制介孔的结构和性能。 相似文献
9.
Induction machines have recently been very popular in variable-speed drives, because of their robust construction and relatively low manufacturing costs (brushless), maintenance-free and well-matured control methods. However, for high-precision control and efficiency optimization one needs the information on the rotor speed which can be measured using different speed sensors. All sensors require a mounting space and cabling, they also generate extra costs and reduce system reliability. Therefore, many of the recent research efforts have been dedicated to sensorless or encoderless electrical drives offering such considerable advantages as: lower cost, reduced size and hardware complexity of the drive system, elimination of sensor cables, lower maintenance requirements, possible operation in aggressive environment, higher noise immunity, reliable and user friendly operation. In this article all well-known sensorless techniques are shortly addressed, but the main focus is on the solutions based on the Model Reference Adaptive System (MRAS) concept. The mathematical models and schemes of all types of MRAS-type speed estimators known from the literature are gathered in this article. The comparative analysis of these speed estimators is done from the following points of view: the speed adaptation mechanism derivation based on the Lyapunov theory, stability problems near zero speed and in the regenerating operation mode, and the sensitivity of MRAS estimators to induction machine parameter changes. 相似文献
10.
Lijun Ji Mindong Gong Tong Xu Jun Gu Xu Jiang Taotao Liang Yu Chen Qingren Liu 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(52)
The interactions of ions and molecules with material surface are highly dependent on the surface properties of the material. Therefore, the distribution of ions or molecules near the material surface may be affected by the surface properties. This phenomenon can be significant enough for controlling the structure of a material synthesized in the sub‐micrometer scale confinement space of a template. This work confirms that inverse opals are perfect templates for offering confinement space, while their different surface properties can strongly affect ion and block copolymer distribution in the confinement space. This surface effect principle can be used for the controlled synthesis of colloids with complex composition. As an example, four kinds of mesoporous magnetic bioactive glass colloids with ordered mesopores, core–shell structure, open surface pores, or disordered mesopores are prepared by using polystyrene and carbon inverse opal templates. This work reveals that inverse opal templates possess great advantage in controlled synthesizing colloidal structures due to their surface effect on ions and molecules and confinement space. 相似文献