Increased hydroxyl concentration by tungsten oxide modified h-BN promoted catalytic performance in partial oxidation of methane

Hexagonal boron nitride (h-BN) as a layered inorganic nonmetallic material has been widely used. Hydrogen peroxide (H₂O₂) modification can trigger exfoliation and afford abundant B–OH active sites at edge of h-BN, which can enhance methane activation ability. Introducing tungsten oxide (WO₃) to h-BN produces a similar effect, because doping WO₃ into h-BN resulted in electron transfer to N, inducing fracture of B–N bond, resulting in N vacancy (triboron center), exposing more B sites and promoting the generation of B–OH. Significantly, the introduction of WO₃ on the modified h-BN dramatically increased the concentration of B–OH compared with the unmodified h-BN, because H₂O₂ modification weakened B–N bond. By means of XRD, TEM, XPS,EPR, FT-IR, it is proved that the high concentration of B–OH active sites contributed to activating C–H bond, thus methane conversion and CO and H₂ selectivity were significantly improved.     

Weighted regularized extreme learning machine to model the discharge coefficient of side slots

In the current research, a modern learning machine algorithm named “Weighted Regularized Extreme Learning Machine (WRELM)" is implemented for the first time for the simulation of the coefficient of discharge of side slots. For this purpose, an effective variable on the coefficient of discharge of side slots is firstly introduced, then five distinctive WRELM models are produced by it for the estimation of the coefficient. In the next stage, a database is created for verification of WRELM results. it should be mentioned that 70% of the data are utilized for training the WRELM models, while the rest (i.e. 30%) for testing them. After that, the optimal number of hidden layer neurons as well as the best activation function of the WRELM algorithm are chosen. In addition, the best regularization parameter and also the weight function of the WRELM are achieved. By conducting a sensitivity analysis, the most effective variable for the simulation of the coefficient of discharge along with the WRELM superior model is introduced. The WRELM superior model estimates values of the coefficient of discharge with the maximum exactness and the highest correlation. For instance, the estimations of the correlation coefficient and scatter index for this model are computed to be 0.930 and 0.051, respectively. The sensitivity analysis shows that the ratio of the side slot crest height to its length and the Froude number should be considered as the most important input variables. A comparison between the WRELM with the ELM displays that the former works much better. Furthermore, an uncertainty analysis is executed for both models. Eventually, an equation is suggested for the estimation of the coefficient of discharge and a partial derivative sensitivity analysis is performed on it.     

Application of Vis–NIR hyperspectral imaging in classification between fresh and frozen-thawed pork Longissimus Dorsi muscles

Fresh and frozen-thawed (F-T) pork meats were classified by Vis–NIR hyperspectral imaging. Eight optimal wavelengths (624, 673, 460, 588, 583, 448, 552 and 609 nm) were selected by successive projections algorithm (SPA). The first three principal components (PCs) obtained by principal component analysis (PCA) accounted for over 99.98% of variance. Gray-level-gradient co-occurrence matrix (GLGCM) was applied to extract 45 textural features from the PC images. The correct classification rate (CCR) was employed to evaluate the performance of the partial least squares-discriminate analysis (PLS-DA) models, by using (A) the reflected spectra at full wavelengths and (B) those at the optimal wavelengths, (C) the extracted textures based on the PC images, and (D) the fused variables combining spectra at the optimal wavelengths and textures. The results showed that the best CCR of 97.73% was achieved by applying (D), confirming the high potential of textures for fresh and F-T meat discrimination.     

基于自适应融合的手掌静脉增强方法

针对掌脉轮廓不清晰，图像对比度低、亮度低，进而导致识别性能降低的现象，提出一种自适应融合的手掌静脉增强方法。首先，基于暗原色先验（DCP）去雾算法，根据掌脉图像变异系数自适应选择去雾系数，得到DCP增强图像，并且基于部分子块重叠直方图均衡（POSHE）算法得到POSHE增强图像；然后，将图像分为16个子块，依据图像灰度均值与标准差确定各子块权重；最后，根据各子块权重对DCP和POSHE增强图像进行自适应融合，得到最终增强图像。该方法既保留了DCP算法在增强图像对比度和亮度的同时不引入明显噪声的优点，又保留了POSHE算法在增强图像对比度和亮度的同时不损失局部细节的特点；同时，两者的自适应融合既解决了DCP图像阴影部分掌脉缺失现象，又削弱了POSHE产生的块效应。在对两个公开库和自建库分别进行的实验中，三个数据库的等错误率分别为0.0004、0.0472、0.0579，识别率分别为99.98%、94.27%、92.05%。实验结果表明，与现有的图像增强方法相比，该方法降低了等错误率，提高了识别精度。     

Chromatic processing for feature extraction of PD-induced UHF signals in GIS

Partial discharge (PD) detection is an effective means of discovering insulation faults in gas-insulated switchgear (GIS). One of the most extensively used methods in PD detection has historically been the ultrahigh frequency (UHF) method. This study evaluates the chromatic processing methodology and its key factors for feature extraction of UHF signals in GIS. Three types of artificial defects are installed in the GIS tank at 0°, 90°, and 180°, respectively. The features of the UHF signals are extracted in the chromatic space, and PD discrimination of the defects is achieved. The influences of processors are studied before the feature selections are suggested. The time-stepping method is proposed to determine the rules of UHF signal frequency characteristics that vary with time. Finally, the process and options of the chromatics-inspired methodology are summarized.     

Performance evaluation of noise reduction method during on-line monitoring of MV switchgear for PD measurements by non-intrusive sensors

Partial Discharge (PD) measurement is a globally accepted method for insulation diagnosis of electrical assets. The consequences of insulation breakdown are well known. The trend is to move from conventional offline testing to online monitoring for insulation life prediction, which results in the inclusion of high frequency noise in the captured signals. Therefore de-noising is of paramount importance in online monitoring to obtain useful information from the signal.In this research, a 20 kV switchgear panel has been subjected to PD faults in the laboratory and measurements have been carried out by using different non-intrusive sensors including a novel sensor, the D-dot sensor and recorded by a high frequency oscilloscope. The measured results show the effective applicability of sensors for switchgear. The Discrete Wavelet Transform (DWT) has been used to de-noise PD signals in this paper. Time domain and frequency domain comparison of original and de-noised PD signals reveals the significance of this technique for online monitoring of Medium Voltage (MV) switchgear. Finally, an adaptive online de-noising concept, based on automatic de-noising is also proposed in this paper.     

Young’s modulus evolution during heating,re-sintering and cooling of partially sintered alumina ceramics

The Young modulus of partially and fully sintered alumina ceramics, obtained by firing to different temperatures (range 1200–1600°C), has been determined via impulse excitation, and the evolution of Young’s modulus of partially sintered alumina with temperature has been monitored from room temperature to 1600°C. As expected, the room-temperature Young modulus of the partially sintered materials is lower than all theoretical predictions. With increasing temperature Young’s modulus decreases, until the original firing temperature is exceeded and sintering (densification) continues, resulting in a steep Young’s modulus increase. During heating and cooling the temperature dependence obeys a master curve for alumina, unless the temperature of the original firing is excessively low.     

How to perform and report an impactful analysis using partial least squares: Guidelines for confirmatory and explanatory IS research

Partial least squares path modeling (PLS-PM) is an estimator that has found widespread application for causal information systems (IS) research. Recently, the method has been subject to many improvements, such as consistent PLS (PLSc) for latent variable models, a bootstrap-based test for overall model fit, and the heterotrait-to-monotrait ratio of correlations for assessing discriminant validity. Scholars who would like to rigorously apply PLS-PM need updated guidelines for its use. This paper explains how to perform and report empirical analyses using PLS-PM including the latest enhancements, and illustrates its application with a fictive example on business value of social media.     

Positioning of PV panels for reduction in line losses and mismatch losses in PV array

Partial shading decreases the power output of PV arrays due to mismatch losses. These losses are dependent on the shading pattern and the relative positions of shaded modules in the array. Various static and dynamic reconfiguration techniques have earlier been proposed to mitigate these losses. In an earlier proposed static reconfiguration technique, the power generation is enhanced by altering the physical location of the PV panels using a random Sudoku configuration without modifying the TCT (Total-Cross-Tied) based electrical connections. However, this arrangement faces drawbacks due to ineffective dispersion of shade and significant increase in wiring required. In this work, an optimal Sudoku arrangement to overcome these drawbacks is formulated. Further analysis indicate that the global peak of the optimal Sudoku based PV array occurs as the right most peak in the curve for most shading conditions, thus evidently obviating the need for complex MPPT (Maximum-Power-Point-Tracking) algorithms. The proposed configuration is compared with various other existing reconfiguration schemes in terms of power output and the comparison is presented. In addition, a general formulation is proposed to expand this pattern to any generic array. A strategy is also proposed to make such an interconnection practicable for very large size PV arrays.     

Solubility and partial molar volume of N,N-dimethylformamide diethyl acetal in supercritical carbon dioxide: Measurement and correlations

The solubilities of N,N-dimethylformamide diethyl acetal were measured at temperatures ranging from 313 to 353 K and pressures from 7.8 to 13.3 MPa in supercritical carbon dioxide. The measured solubility data were correlated using the Chrastil, Sung and Shim (SS), and Jouyban–Chan–Foster (JCF) semiempirical models. Consequently, the calculated results showed satisfactory agreement with experimental data and differed from the measured values by between 4.56 and 6.10%. The correlated results indicated that the JCF model provided the best fitness. Solubility data were also utilized to estimate the partial molar volume for the compound in the supercritical phase using the theory developed by Kumar and Johnston.