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1.
Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe3O4-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe3O4-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m2·g-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe3O4-CSPs composites and promoting the practical implementation of Pd/Fe3O4-CSPs catalysts for organic transformation processes. 相似文献
2.
Callistus Nonso Ude Dominic Okechukwu Onukwuli Jonah Chukwudi Umeuzuegbu Chinemelum Chukwujekwu Chukwuka 《化学工程与技术》2021,44(1):65-76
The heterogeneous catalysis of transesterification of gmelina seed oil to biodiesel is evaluated. The oil was extracted from the seeds with n‐hexane by solvent extraction and characterized to determine its physiochemical properties. Response surface methodology was applied to optimize the effect of process variables on the biodiesel yield. The base‐activated clay catalyst performed as montmorillonite clay with the characteristic property of a Brønsted acid. It has an improved surface area after activation that enhanced its catalytic activity on transesterification reaction. Under optimal conditions, the biodiesel yield was 70.1 %, thus demonstrating that the model predicted well the biodiesel production. 相似文献
3.
The primary objective of this study is to develop teaching materials for chemical engineering students (or students pursuing other related B.Sc./M.Sc. degrees) that encourage self-learning to facilitate understanding and the development of problem-solving skills. Tools are oriented to support the teaching of “Introduction to Chemical Engineering” courses to 1st year B.Sc. students in Chemical Engineering, 2nd year B.Sc. students in Chemistry, and 3rd year B.Sc. students in Biochemistry at the Universidad Complutense de Madrid (UCM). Problem generators of standard exercises, as an additional complement to the exercises that are used in the lectures, seminars, and assignments to facilitate the learning of the students, have been developed. These generators provide exercises to students with “unlimited” initial values (with certain restrictions). The software that was used to develop these materials was Jupyter Notebook, which runs under the Python 3.6 language. The problem generators can be classified into fixed problem generators, case-based generators, and random problem generators. Additionally, lecturing tools have been developed to support teaching using live/interactive examples. These examples can learning understanding of various topics of the courses. 相似文献
4.
In this work, we designed a magnetically-separable Fe3O4-rGO-ZnO ternary catalyst, ZnO anchored on the surface of reduced graphene oxide (rGO)-wrapped Fe3O4 magnetic nanoparticles, where rGO, as an effective interlayer, can enhance the synergistic effect between ZnO and Fe3O4. The effects of three operational parameters, namely irradiation time, hydrogen peroxide dosage, and the catalyst dosage, on the photo-Fenton degradation of methylene blue and methyl orange were investigated. The results showed that the Fe3O4-rGO-ZnO had great potential for the destruction of organic compounds from wastewater using the Fenton chemical oxidation method at neutral pH. Repeatability of the photocatalytic activity after 5 cycles showed only a tiny drop in the catalytic efficiency. 相似文献
5.
《Food Control》2018
Sampling plans for food safety hazards are aimed to be used to determine whether a lot of food is contaminated (with microbiological or chemical hazards) or not. One of the components of sampling plans is the sampling strategy. The aim of this study was to compare the performance of three different sampling strategies, being simple random sampling (SRS), stratified random sampling (STRS), and systematic sampling (SS), with each other for their probability of detecting a heterogeneously distributed contamination in a lot of herbs or spices (i.e., a dry food product). To this end, a simulation model was developed, and applied to different scenarios for contamination level and numbers of samples collected. In addition, as a case study, the sampling plan of a company processing herbs and spices was evaluated using the simulation model. Results showed that the effectiveness of the sampling plan is influenced by the sampling strategy. With expected low contamination levels the SS strategy performs better than the two other strategies. At higher expected contaminated levels, the STRS strategy is preferred. 相似文献
6.
Software updates are an important topic for increasingly software dependent and automated automotive systems. Besides ongoing technical developments, there are also regulatory requirements in development for such systems. We present here an overview of the automotive domain and the particular requirements on update systems, identify potentially suitable update frameworks and evaluate them based on automotive requirements. A focus is on a holistic view of requirements, considering safety, security, and availability. 相似文献
7.
A tubular platinum reactor with a perforated annular array enables fuel/air mixtures to exchange sides, thus sustaining flames and preventing heat loss. Consequently, the combustion efficiency and operational range can be enhanced. A hydrogen/air mixture was introduced into inner and outer chambers at different equivalence ratios and flow velocities to chemically and physically investigate the interplay between the chambers. The benefits of hydrogen include a high gravimetric heating value, flame speed, and diffusion capacity and short chemical reaction time. The coexistence of heterogeneous (surface) and homogeneous (gas) reactions in the micro TPV reactor was examined and elucidated in terms of aerodynamics, mass and heat transfer, and chemical reactivity. Furthermore, a TPV reactor with TPV cell arrays was assembled, and the corresponding radiant efficiency of the emitter and the overall efficiency of the proposed micro TPV system were determined in this study. 相似文献
8.
9.
Rene M. Ripken Jeffery A. Wood Johannes G. E. Gardeniers Sverine Le Gac 《化学工程与技术》2019,42(10):2179-2186
In heterogeneous catalysis, the creation of gaseous products as bubbles in a liquid phase on the catalytic surface is associated with slip phenomena. In a microreactor, the slip length at the gas‐liquid interface is in the same order of magnitude as the reactor dimensions, which can affect fluid dynamics and transport phenomena. Here, the interplay of momentum, heat and mass transfer in a microreactor, when bubbles form on the catalytic surface, was investigated using two‐dimensional simulations. The effect of bubbles on the endothermic process of aqueous‐phase reforming of a glycerol solution was evaluated in terms of conversion and conversion and temperature in the reactor. Altogether, this study highlights the impact of bubbles, not only on the transport phenomena but also on the reactor performance. 相似文献
10.
堆芯中子学计算是反应堆设计分析的基础,为提高堆芯中子学计算的模拟分辨率与计算精度,开发了反应堆堆芯先进中子学模拟软件(SCAP-N)。该程序首先根据轴向特征对堆芯进行分层,并逐层进行二维堆芯非均匀输运计算,再采用超级均匀化方法(SPH)获得栅元等效均匀化截面,最后进行三维堆芯逐棒(pin-by-pin)输运计算,获得堆芯有效增殖因子与精细棒功率分布。为提高程序计算效率,采用分布式/共享式(MPI/OPENMP)混合并行方式对程序进行了并行化开发。利用虚拟反应堆(VERA)系列基准例题及美国先进非能动压水堆(AP1000)启动物理试验实测数据对程序进行了测试验证。结果表明,相比于商用核设计程序系统,SCAP-N程序采用的逐棒输运技术能够提高堆芯中子学的计算精度。与同类型高精度中子学程序相比,SCAP-N具有更高的计算效率,可进一步提高核电厂的经济性及运行灵活性。 相似文献