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1.
目的 建立使用八级杆碰撞/反应池电感耦合等离子体质谱法测定大米中痕量铬和硒元素含量的方法,比较普通模式和ORS模式对2种元素测定结果的差异。方法 ORS模式采用屏蔽矩技术结合氦气碰撞反应池消除40Ar12C+ 对52Cr、39Ar39Ar+和40Ar38Ar+对78Se的干扰,选用丰度较高的同位素52Cr、78Se测定。普通模式通过在线加入内标校正基体干扰,选择同量异位素干扰较少的同位素53Cr、82Se测定。结果 普通模式铬和硒元素的检出限为0.059μg/L和0.023μg/L,而ORS模式铬和硒的检出限为0.027μg/L和0.012μg/L,铬、硒元素的含量在0 ~ 100μg/L范围内,线性相关系数优于0.9998。结论 普通模式用于大米中含量较高的铬和硒的测定也是可行的,应用ORS模式在痕量样品分析时测定结果更准确可靠,研究结果为同类样品的测定提供了参考  相似文献   
2.
为了探究典型长寿区大米有机硒的赋存形态与人体硒营养水平的关系,本文分析了江西典型长寿区大米中有机硒、谷蛋白硒、硒代蛋氨酸(Selenomethionine, SeMet)等的组成特征,并运用胃肠体外模拟法对大米硒的生物可利用度及其与各有机硒组分之间的相关关系进行了研究。结果表明,大米中的硒主要以有机形式(78.67 ± 13.52%)赋存,其中,53.73 ± 8.27%的有机硒为谷蛋白硒,且65%以上的谷蛋白硒可酶解消化为SeMet。大米硒的生物可利用度为55.58 ± 10.53%。大米谷蛋白中SeMet比例相对较高且易于被人体吸收利用,这可能与当地居民的健康长寿关系密切。不过,SeMet与大米可利用硒的相关系数仅为0.55。因此,未来有必要对大米中不同硒蛋白的代谢产物(如SeMet)进行研究。  相似文献   
3.
Based on the ab-initio calculations the thermodynamics of the Sb2Se3 intermediate phase was modeled and used in the calculations of the Sb–Se phase diagram together with the thermodynamic properties of liquid phase elaborated by the association model. The modeled heat capacity of Sb2Se3 phase shows excellent agreement with the experiment data available in the literature in the wide temperature range. The calculated equilibrium lines of the Sb–Se phase diagram good correlate with the experimental ones. The determined thermodynamic parameters can be applied in future calculations of the high-ordered systems and for determination of the Sb2Se3 thermoelectric properties.  相似文献   
4.
In this report MoSe2 nanosheets were fabricated using new precursors of MoCl5 and Na2SeO3 and a very simple chemical procedure without using inert atmosphere and complex methods for preparing Se ion source. The structural properties of fabricated nanosheets were examined by means of XRD, field emission scanning electron microscopy (FESEM), elemental mapping of energy dispersive x-ray spectroscopy (EDS), transmission electron microscopy (TEM), atomic force microscopy (AFM), Raman spectroscopy and isotherm gas adsorption-desorption technique. The results showed the nanosheets are mixed phase metallic-semiconductor 1T-2H with thicknesses about 3.6–6.1 nm and are stable for several months. The effective surface area is obtained 28 m2 g−1 and mean pore size of 6–8 nm for MoSe2 nanosheets. Electro-impedance spectroscopy showed low resistivity of nanosheets due to presence of metallic phase of MoSe2. HER activity of nanosheets obtains a Tafel slope of 60 mV.dec−1 and high current density values up to 150 mA cm−2 and the value of over potential at 10 mA cm−2 is 155 mV.  相似文献   
5.
The wetness impregnation method was used to synthesize 0.1% CdSe/TiO2 photocatalysts with different atomic molar ratios (90–10, 70–30, 50–50, and 30–70). These catalysts were characterized by XRD, SEM-EDX and mapping, TEM-EDS, UV–VIS spectroscopy, fluorescence spectroscopy, XPS, TPR, TPO, and TPD analyses. Cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses were performed to examine the photocatalytic activity for photocatalytic fuel cells (PFCs) in glucose solution in the dark and under UV illumination. The characterization analyses revealed that anatase TiO2 formed the catalyst and electronic structure and surface properties changed when doped with metal. The photocatalytic glucose electrooxidation (PGE) results demonstrate that the 0.1% CdSe(50-50)/TiO2 catalyst has higher photocatalytic activity, stability, and resistance than other catalysts both in the dark (2.71 mA cm?2) and under UV illumination (7.20 mA cm?2). These results offer a promising new type of photocatalyst for PFC applications.  相似文献   
6.
Betalains are hydrophilic colorants containing chromophore betalamic acid. Owing to poor stability, its usage is limited to low acidic short shelf-life, and frozen foods. In this report, effect of metals (inorganic Se4+, Zn2+, and Cu2+) on stability of betalains in Rivina humilis L. berry juice (RBJ) was studied in presence of 10 and 40 μg metal/mL with/without ascorbic acid (AA; 0.25 and 0.5 g/100 mL). Se bleached RBJ betacyanins mildly, whereas Zn, and Cu bleached the pigments significantly. AA protected the pigments from metal-induced bleaching, and stabilizing effect of 0.25 g AA/100 mL was higher (P < 0.05) than 0.5 g AA/100 mL. AA (0.25 g/100 mL) + Se (40 μg/mL) enhanced (five-fold) the half-life time of betacyanins. RBJ betacyanins degraded up to 95% and 96% on treatment for 36 min at 90 °C and storage for 48 days at 25 °C, respectively, whereas only 15% pigment was lost on storage (5 °C, 90 days). AA (0.25 g/100 mL) + Se (40 μg/mL) regenerated the pigments on storage at 5 °C after thermal degradation. Color values of AA (0.25 g/100 mL) + Se (40 μg/mL) containing samples indicated an orange tinge, whereas other samples turned brown yellow after thermal treatment.  相似文献   
7.
转基因大豆对硒的富集作用和形态分布研究   总被引:1,自引:1,他引:0  
目的研究转基因大豆对硒的富集作用以及富集前后转基因大豆中硒的形态分布和形态转化。方法 采用电感耦合等离子体质谱分析转基因大豆富集前后硒的总量,采用蛋白酶提取,高效液相色谱-电感耦合等离子体质谱(high performance liquid chromatography-inductively coupled plasma-mass spectrometry,HPLC-ICP-MS)联用技术分析转基因大豆中的硒酸盐(selenate,Se VI)、亚硒酸盐(selenite,Se IV)、硒代蛋氨酸(selenomethionine,Se Met)和硒代胱氨酸(selenocystine,Se Cys)等几种硒化合物。盆栽种植试验研究转基因大豆对硒的富集作用。通过对照试验,考察大豆植株不同部位总硒含量变化和形态分布的转化情况。结果转基因大豆对硒有较好的富集作用,吸收的亚硒酸盐在大豆植株中部分转化成了硒代蛋氨酸和硒代胱氨酸。结论 了解了转基因大豆的形态分布和转化情况,可以更好地评估转基因大豆的食用安全风险并进行生物利用开发。  相似文献   
8.
9.
The antibacterial properties of Se NPs were investigated against four foodborne pathogens (Escherichia coli O157:H7, Staphylococcus aureus, Salmonella, and Listeria monocytogenes). The cytotoxicity of Se NPs was also studied using the Caco-2 cell line. Se NPs at concentrations of 10 μg/mL or higher exhibited dose-dependent antimicrobial properties against S. aureus, but not on the other three pathogens. Se NPs also exhibited various degrees of toxicity on Caco-2 cells after 24 h of exposure. Cellular shrinkage and irregular shapes of treated bacterial cells indicated that the antimicrobial effects of Se NPs are bacteriostatic, not bactericidal. This is the first study to investigate the antimicrobial activity of Se NPs against important foodborne pathogens. The results of this study demonstrate that Se NPs can be used as an antimicrobial agent to inhibit the growth of S. aureus and can be potentially used for food safety applications.  相似文献   
10.
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