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1.
城市发展与新能源渗透导致电力系统运行难度增大、电网荷源联合调峰控制消耗增加,为此,提出基于灵活性裕度的电网荷源联合调峰节能降耗控制方法,减少污染排放,达到节能降耗目的。以电力系统的上调和下调灵活性裕度指标为基础,以最大抽蓄调峰效益、最大风电消纳电量、降低发电机组能耗为目标,结合气电功率平衡、火电机组、水电站等约束条件,建立荷源联合调峰协调滚动节能降耗控制模型;将模型分为水电、气电、火电3个调度层实施分层求解,实现电网荷源联合调峰节能降耗控制。实验结果表明,该方法通过灵活性资源配置可避免切负荷情况出现,全额消纳风电资源,最大限度地利用电网能源;同时该方法应用后可减少火电开机机组台数,可减少341 t污染物排放,减排率达到4.3%,节能降耗效果显著。 相似文献
2.
相邻工作面开采会导致复杂的漏风情况,浮煤易自燃,增大防火工作的难度。为明确相邻采空区自燃“三带”分布特征及确定最佳注氮防灭火参数,以贵州某矿4244工作面为背景,结合现场实测,应用Fluent流场分析软件,模拟研究不同注氮方案下采空区氧气浓度场分布规律。结果表明,实测结果与模拟相吻合,验证了模拟的可靠性;当注氮位置为X=50 m,注氮流量为100 m3/h时,采空区进、回风巷侧氧化带宽度分别为7 m和38 m,能明显减少本采空区氧化带面积,且能防止氧化带距工作面太近;此工作面进风侧注氮对相邻采空区氧化带影响范围较小,这要求在回采过程中需要对煤柱进行加固,降低孔隙率,控制漏风,减少氧气进入相邻采空区,降低煤自燃风险。模拟结果为相邻采空区灾害防治工作提供了的理论指导。 相似文献
3.
为解决魏家地煤矿工作面煤层透气性系数低,采空区瓦斯治理难的安全生产问题,以该矿北1103工作面为工程背景,采用数值模拟和现场实践等方法,对地面钻孔瓦斯抽采后,采空区自燃“三带”的变化规律进行了分析研究,并给出了相关自然发火对应防治措施。结果表明,北1103工作面经地面钻孔抽采瓦斯后,采空区散热带宽度由56 m增加至61 m;氧化带宽度由29 m增加至39 m;窒息带宽度由315 m减少至300 m。本次研究有效解决了北1103采空区瓦斯涌出量大与自然发火隐患问题。研究结果适用于魏家地煤矿采取综合立体瓦斯抽采治理模式的工作面,极大地保护了工作面安全回采,对落实矿井的安全高效生产及经济价值效益具有良好的工程示范意义。 相似文献
4.
《Advanced Powder Technology》2022,33(6):103595
Ceria (CeO2) particles are prevalent polishing abrasive materials. Trivalent lanthanide ions are the popular category of dopants for enriched surface defects and thus improved physicochemical properties, since they are highly compatible with CeO2 lattices. Herein, a series of dendritic-like mesoporous silica (D-mSiO2)-supported samarium (Sm)-doped CeO2 nanocrystals were synthesized via a facile chemical precipitation method. The relation of the structural characteristics and chemical mechanical polishing (CMP) performances were investigated to explore the effect of Sm-doping amounts on the D-mSiO2/SmxCe1?xO2?δ (x = 0–1) composite abrasives. The involved low-modulus D-mSiO2 cores aimed to eliminate surface scratch and damage, resulting from the optimized contact behavior between abrasives and surfaces. The trivalent cerium (Ce3+) and oxygen vacancy (VO) at CeO2 surfaces were expected to be reactive sites for the material removal process over SiO2 films. The optimal oxide-CMP performances in terms of removal efficiency and surface quality were achieved by the 40% Sm-doped composite abrasives. It might be attributed to the high Ce3+ and VO concentrations and the enhancement of tribochemical reactivity between CeO2SiO2 interfaces. Furthermore, the relationship between the surface chemistry, polishing performance as well as the actual role in oxide-CMP of the D-mSiO2/SmxCe1?xO2?δ abrasives were also discussed. 相似文献
5.
6.
An analytical model for gas leakage through contact interface in proton exchange membrane fuel cells
《International Journal of Hydrogen Energy》2022,47(75):32273-32286
Sealing performance between two contacting surfaces is of significant importance to stable operation of proton exchange membrane (PEM) fuel cells. In this work, an analytical micro-scale approach is first established to predict the gas leakage in fuel cells. Gas pressure and uneven pressure distribution at the interface are also included in the model. At first, the micro tortuous leakage path at the interface is constructed by introducing contact modelling and fractal porous structure theory. In order to obtain the leakage at the entire surface, contact pressure distribution is predicted based on bonded elastic layer model. The gas leakage through the discontinuous interface can be obtained with consideration of convection and diffusion. Then, experiments are conducted to validate the numerical model, and good agreement is obtained between them. Finally, influences of surface topology, gasket compression and gasket width on leakage are studied based on the model. The results show that gas leakage would be greatly amplified when the asperity standard deviation of surface roughness exceeds 1.0 μm. Gaskets with larger width and smaller thickness are beneficial to sealing performance. The model is helpful to understand the gas leakage behavior at the interface and guide the gasket design of fuel cells. 相似文献
7.
《International Journal of Hydrogen Energy》2022,47(83):35423-35436
The gas diffusion substrate (GDS) is essential in the proton exchange membrane fuel cells. Its fabrication techniques affect the performance significantly and are worthy of investigation. In this study, a manufacturing process of the GDS is proposed to understand the formation process of GDS and promote its structure and performance more pertinently. Different states during the preparation process, raw carbon paper, pre-curing, curing, carbonation, and graphitization, are characterized and measured. Experimental and numerical methods are employed to determine the relationships between microstructure, transport, and mechanical performance variation with the fabricating processes. The results show that its porosity, average pore size, and effective diffusivity decrease first and increase after curing. These parameters after graphitization are lower than that of the carbon paper (CP). The electrical resistivity increases dramatically while pre-curing and decreases gradually after curing, carbonation, and graphitization, and it is much reduced after graphitization. Moreover, mechanical measurement results show that both the picks of tensile strength and flexural modulus occur after curing. Its tensile strength shows little change after graphitization compared to the initial paper's. In contrast, the flexural modulus is improved significantly. 相似文献
8.
通过耦合零维等离子动力学求解器和燃烧动力学求解器,建立了交流放电等离子体助燃模型,研究了交流放电非平衡等离子体对C2H4/空气的助燃路径,并与自燃过程进行了对比。该模型使用电子能量分布函数计算电子碰撞反应速率,并得到贫燃条件下连续放电过程中温度、组分浓度、放热速率、关键组分的生成/消耗速率随时间的变化。研究表明,等离子体助燃增加了新的反应路径,生成了更多的自由基和激发态组分,缩短滞燃期近两个数量级。氧气、氮气激发态的弛豫和淬熄过程促使电能—化学能—热能的转化,放电结束后的总放热量增加,最高燃烧温度比自燃条件下高约400 K。同时,电子碰撞O2、N2激发态与O2的退激反应、单态氧原子O(1D)的弛豫等过程促进了氧原子的生成。此外,H原子的生成间接提高了O原子的物质的量分数(主要通过H+O2———→OH+O),加速C2H4氧化生成HCO、CO等,缩短了点火延迟时间,有助于燃烧效率的提高。 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(65):28152-28164
The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NOx emission analysis demonstrates that 60% methanol addition results in the highest NOx emissions. The most important reactions dominating the NOx consumption and production are identified in this study. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(92):39204-39214
In this work, the SnS2 nanoflowers (SnS2 NFs) were solvothermally prepared in the solvent of ethanol, while SnS2 nanoplates (SnS2 NPs) were obtained through the identical conditions except for the solvent of water. The flowers were assembled with numerous nanosheets with very thin thickness, and the NPs exhibited hexagonal shape. When used as the battery-type electrode material for supercapacitors, the SnS2 NFs delivered a specific capacity of as high as 264.4 C g?1 at 1 A g?1, which was higher than the 201.6 C g?1 of SnS2 NPs. Furthermore, a hybrid supercapacitor (HSC) was assembled with the SnS2 as positive electrode and activated carbon (AC) as negative electrode, respectively. The SnS2 NFs//AC HSC exhibited a high energy density of 28.1 Wh kg?1 at 904.3 W kg?1, which was higher than the 24.2 Wh kg?1 at 844.3 W kg?1 of SnS2 NPs//AC HSC. Especially, when the power density was enhanced to the highest value of 8666.8 W kg?1, the NFs-based device could still hold 20.4 Wh kg?1. In addition, both HSC devices showed an excellent cycling stability after 5000 cycles at 5 A g?1. The present method is simple and can be extended to the preparation of other transition metal sulfides (TMSs)-based electrode materials with brilliant electrochemical performance for supercapacitors. 相似文献