Chicken nuggets-like core/shell nanosheet arrays as high performance flexible all-solid-state supercapacitor cathode and buckwheat shell as anode

The energy density of a flexible all-solid-state supercapacitor (ASC) requires new electrode material with special structure and morphology as a prerequisite for its secured improvement. In this paper, a new morphological exploration of chicken nuggets-like core/shell NiCo₂O₄/MnO₂ (NCM) nanosheet arrays on Ni foam was employed. The application of this special morphology aims to greatly improve the electrochemical performance of the cathode electrode. Additionally, Buckwheat Biochar (BBC) is utilized as the anode while the PVA/KOH thin film is prepared as the separator. The chicken nuggets-like core/shell NCM nanosheet arrays were obtained by a two-step hydrothermal method. A series of characterization methods were carried out to further support the core/shell's well-designed structure and precise composition. The tests exhibited excellent specific capacitance of 593.3 F g^?1 at 5 mA cm^?2 and outstanding cycling stability with a retention of 90% after 10000 cycles. Furthermore, the assembled NCM//BBC ASC device indicated a high specific capacitance (239 F g^?1 at the current density of 5 mA cm^?2), this is in due part of the unique architecture of NCM nanosheet arrays and interconnected special porous structure of the BBC and the thin film PVA/KOH. Hence, the assembled ASC device exhibited high energy density (an energy density of 58 Wh·kg^?1 at 3263 W kg^?1) and remarkable cycling stability.     

Aligned Co3O4–CoOOH heterostructure nanosheet arrays grown on carbon paper with oxygen vacancies for enhanced and robust oxygen evolution

Developing efficient and stable non-noble metal oxygen evolution reaction (OER) electrocatalysts for sustainable overall water-splitting is extremely desirable but still a great challenge. Herein, we developed a facile strategy to fabricate Co₃O₄–CoOOH heterostructure nanosheet arrays with oxygen vacancies grown on carbon paper (Co₃O₄–CoOOH/CP). Benefiting from the unique 3D architecture, large surface area, synergistic effects between Co₃O₄, CoOOH and oxygen vacancies, the obtained self-supporting Co₃O₄–CoOOH/CP presents excellent electrocatalytic OER activity (low overpotentials of 245 and 390 mV at 10 and 100 mA cm⁻²) and robust long-term stability in alkaline condition. The present strategy provides the opportunities for the future rational design and discovery of high-performance non-noble metal based electrocatalysts for advanced water oxidation and beyond.     

Enhanced photo-electrochemical activity of ZnO/Cu2S nanotube arrays photocathodes

ZnO/Cu₂S nanotube arrays are fabricated firstly by a facile and capping-agent-free method, and the photo-electrochemical performance has been studied systematically. The results show that ZnO/Cu₂S nanotube arrays achieve enhanced photo-electrochemical water splitting performance and the photocurrent densities of ZnO/Cu₂S are 7.9 times than that of ZnO at 0 V versus Ag/AgCl. The performance of the ZnO/Cu₂S nanotube arrays can be adjusted by changing the amount of Cu₂S microcrystals. The results confirm that the enhanced photo-electrochemical performance of ZnO/Cu₂S is due to the significantly improved visible light absorption, effective separation of photo-induced carriers due to the well band energy match and the formed p-n junction between ZnO and Cu₂S.     

Location Privacy in Device-Dependent Location-Based Services: Challenges and Solution

With the evolution of location-based services (LBS), a new type of LBS has already gain a lot of attention and implementation, we name this kind of LBS as the Device-Dependent LBS (DLBS). In DLBS, the service provider (SP) will not only send the information according to the user’s location, more significant, he also provides a service device which will be carried by the user. DLBS has been successfully practised in some of the large cities around the world, for example, the shared bicycle in Beijing and London. In this paper, we, for the first time, blow the whistle of the new location privacy challenges caused by DLBS, since the service device is enabled to perform the localization without the permission of the user. To conquer these threats, we design a service architecture along with a credit system between DLBS provider and the user. The credit system tie together the DLBS device usability with the curious behaviour upon user’s location privacy, DLBS provider has to sacrifice their revenue in order to gain extra location information of their device. We make the simulation of our proposed scheme and the result convince its effectiveness.     

Adaptive neuro-fuzzy algorithm applied to predict and control multi-phase flow rates through wellhead chokes

A Takagi-Sugeno adaptive neuro-fuzzy inference system (TSFIS) model is developed and applied to a dataset of wellhead flow-test data for the Resalat oil field located offshore southern Iran, the objective is to assist in the prediction and control of multi-phase flow rates of oil and gas through the wellhead chokes. For this purpose, 182 test data points (Appendix 1) related to the Resalat field are evaluated. In order to predict production flow rate (Q_L) expressed as stock-tank barrels per day (STB/D), this dataset includes four selected input variables: upstream pressure (Pwh); wellhead choke sizes (D64); gas to liquid ratio (GLR); and, base solids and water including some water-soluble oil emulsion (BS&W). The test data points evaluated include a wide range of oil flow rate conditions and values for the four input variables recorded. The TSFIS algorithm applied involves five data processing steps: a) pre-processing, b) fuzzification, c) rules base and adaptive neuro-fuzzy inference engine, d) defuzzification, and e) post-processing of the fuzzy model. The developed TSFIS model for the Resalat oil field database predicted oil flow rate to a high degree of accuracy (root mean square error = 247 STB/D, correlation coefficient = 0.9987), which improves substantially on the commonly used empirical algorithms used for such predictions. TSFIS can potentially be applied in wellhead choke fuzzy controllers to stabilize flow in specific wells based on real-time input data records.     

Self-supported Ni2P nanotubes coated with FeP nanoparticles electrocatalyst (FeP@Ni2P/NF) for oxygen evolution reaction

Bimetallic phosphides have been widely investigated as electrocatalysts for oxygen evolution reaction (OER) due to their efficient activity and environmental friendliness. While the reasonable design and controllable synthesis of bimetallic phosphide with typical nanostructure is still a great challenge. Hence, we put forward a novel and straightforward way for constructing FeP nanoparticles coated Ni₂P ultrathin nanotube arrays on the surface of Ni foil (FeP@Ni₂P/NF), which is synthesized through two steps of electrodeposition and subsequent in-situ phosphorization process. The obtained FeP@Ni₂P/NF shows excellent electrochemical activity for OER, and it only needs potential of 1.52 V vs. RHE to reach the current density of 50 mA cm⁻² in an alkaline media. The excellent electrocatalytic activity of FeP@Ni₂P/NF mainly benefits from: (i) the synergistic effect between FeP and Ni₂P promoting electron transfer; (ii) the formation of the unique 3D ultrathin nanotube arrays increasing the quantity of active sites and avoiding the agglomeration of catalysts during testing. In addition, the influence of reaction condition on the electrochemical activity for OER has also been investigated through altering the phosphorization temperature of precursor.     

从消费到创造——消费主义挑战下的共享设计探究

与工业时代相比,信息时代消费主义对于设计的影响只增无减,新的商品和服务层出不穷,令人目不暇接。现代设计之父威廉·莫里斯曾提出将消费者与创造者的身份进行结合的解决办法,这种解决办法在工业时代无法实现,却在信息时代背景下的共享设计中重焕生机。