首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   12008篇
  免费   815篇
  国内免费   513篇
电工技术   496篇
综合类   627篇
化学工业   2905篇
金属工艺   2596篇
机械仪表   1292篇
建筑科学   82篇
矿业工程   206篇
能源动力   1013篇
轻工业   205篇
水利工程   127篇
石油天然气   121篇
武器工业   96篇
无线电   515篇
一般工业技术   1641篇
冶金工业   1154篇
原子能技术   99篇
自动化技术   161篇
  2024年   11篇
  2023年   228篇
  2022年   333篇
  2021年   387篇
  2020年   427篇
  2019年   314篇
  2018年   259篇
  2017年   368篇
  2016年   334篇
  2015年   361篇
  2014年   598篇
  2013年   505篇
  2012年   768篇
  2011年   836篇
  2010年   611篇
  2009年   668篇
  2008年   538篇
  2007年   770篇
  2006年   707篇
  2005年   526篇
  2004年   481篇
  2003年   442篇
  2002年   434篇
  2001年   411篇
  2000年   342篇
  1999年   274篇
  1998年   229篇
  1997年   190篇
  1996年   159篇
  1995年   182篇
  1994年   115篇
  1993年   85篇
  1992年   88篇
  1991年   95篇
  1990年   114篇
  1989年   90篇
  1988年   25篇
  1987年   9篇
  1986年   5篇
  1985年   1篇
  1984年   4篇
  1983年   2篇
  1982年   1篇
  1981年   2篇
  1980年   1篇
  1978年   1篇
  1977年   1篇
  1976年   2篇
  1975年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
To tackle the dissolution problem of boron carbide particles in silicon infiltration process, carbon-coated boron carbide particles were fabricated for the preparation of the reaction-bonded boron carbide composites. The carbon coating can effectively protect the boron carbide from reacting with liquid Si and their dissolution, thus maintaining the irregular shape of boron carbide particles and preventing the growth of boron carbide particles and reaction formed SiC regions. Furthermore, the nano-SiC particles, originated from the reaction of the carbon coating and the infiltrated Si, uniformly coated on the surfaces of boron carbide particles, thus forming a ceramic skeleton of the nano-SiC particles-coated and -bonded boron carbide particles. The Vickers hardness, flexural strength and fracture toughness of the composites can be increased by 26 %, 45 %, and 37 % respectively, by using carbon-coated boron carbide particles as raw materials.  相似文献   
2.
搭建了鼓泡床碳酸化反应器,研究常温常压下电石渣直接液相碳酸化矿化封存CO2的能力,揭示了重要操作参数表观气速、液固比和CO2浓度对电石渣矿化封存CO2能力和碳酸化效率的影响规律。同时构建响应面模型,分析各参数对电石渣碳酸化效率的影响强度,优化获得最大碳酸化效率及相应操作工况。结果表明,增加气速有利于钙离子溶解和CO2吸收,但反应器中过高气速易导致气相通道效应,不利于气液充分接触。当液固比降低,溶液中钙离子浓度提高,更有利于碳酸化反应,但液固比过低会影响固液间传质。适当增加CO2浓度有利于提高碳酸化效率,但CO2浓度增至到一定值后,对碳酸化效率影响降低。响应面建模分析发现,各因素对碳酸化效率影响顺序为:液固比>CO2浓度>表观气速。优化结果发现碳酸化效率最高为93.58%,工况为表观气速0.07m/s,液固比为8.26mL/g和CO2体积分数为20.91%。研究可知,鼓泡床中常温常压下电石渣直接液相加速碳酸化反应,具有较大的CO2固定量和高的碳酸化效率,实验结果为电石渣加速矿化封存CO2技术的发展提供了基础数据。  相似文献   
3.
Compositional analysis of boron carbide on nanometer length scales to examine or interpret atomic mechanisms, for example, solid-state amorphization or grain-boundary segregation, is challenging. This work reviews advancements in high-resolution microanalysis to characterize multiple generations of boron carbide. First, ζ-factor microanalysis will be introduced as a powerful (scanning) transmission electron microscopy ((S)TEM) analytical framework to accurately characterize boron carbide. Three case studies involving the application of ζ-factor microanalysis will then be presented: (1) accurate stoichiometry determination of B-doped boron carbide using ζ-factor microanalysis and electron energy loss spectroscopy, (2) normalized quantification of silicon grain-boundary segregation in Si-doped boron carbide, and (3) calibration of a scanning electron microscope X-ray energy-dispersive spectroscopy (XEDS) system to measure compositional homogeneity differences of B/Si-doped arc-melted boron carbides in the as-melted and annealed conditions. Overall, the improvement and application of advanced analytical tools have helped better understand processing–microstructure–property relationships and successfully manufacture high-performance ceramics.  相似文献   
4.
Using spark plasma sintering (SPS), >98.5 % dense boron carbide (B4C) samples were made from commercially available and lab-synthesised powders made via a low temperature synthesis (LTS) process. The work showed that the LTS powder can be produced in batches of tens to hundreds of grams whilst maintaining a high purity material with lower levels of residual free carbon (20.6–21.3 wt.% C) than commercially available samples (22.4 wt.% C). The LTS material was seen to exhibit higher hardness values (37.8 GPa) than the commercial grade material (32.5 GPa) despite featuring a coarser average grain size (10.8 μm and 2.4 μm respectively). This is largely thought to be due to the influence of ZrO2 and AlB2 impurities introduced to the material during micronising milling of the powder after synthesis, as opposed to the influence of the materials lower carbon content.  相似文献   
5.
In this study, silicon carbide (SiC) composites reinforced with pitch-based carbon fibers and composed of heat transfer channels were fabricated by combining chemical vapor infiltration and reactive melting infiltration method. It was observed that the internal heat conduction skeleton of pitch-based carbon fibers was sequentially formed. The thermal conductivities from room temperature to 500 °C along through-thickness direction and in-plane direction were investigated. The results showed that Cpf/SiC composites with heat transfer channels possessed excellent thermal conductvity in two directions, and the thermal conductivity increased with increasing volume content of heat transfer channels. The thermal conductivity in through-thickness direction reached 38.89 W/(m·K), and that for in-plane direction reached 112.42 W/(m·K). Theoretical calculations were empolyed to study the temperature dependence of the Cpf/SiC composites. The variations in slope A′ and intercept B′ values of fitted curves were in good agreement with the experimental results. To verify the reliablilty of the theoretical model, the Cpf/SiC composites were heated at 1650 °C for 2 h and the thermal conductivity exhibited further improvement due to the formation of more perfect crystalline structure. Thermal conductivity through thickness direction improved to 43.49 W/(m·K), and that in in-plane direction improved to 142.49 W/(m·K), which could be identified by the theoretical model. Finally, the leading edge model was established by using ABAQUS finite element analysis software to evaluate the potential application of the composites. Owing to the outstanding thermal conductivity, the leading edge obtained by using Cpf/SiC composites in this study exhibited lower temperature gradient and a more uniform temperature distribution. Moreover, less thermal stress and displacement were generated during heating process.  相似文献   
6.
杨剑  张明珠  李伟 《柴油机》2022,44(5):51-55
针对现有双螺杆压缩机转子加工用成形盘铣刀刀片排布方式不合理、容易发生磨损的问题,基于图形仿真法研制一款螺杆转子可转位成形盘铣刀。研制工作主要围绕刀片在刀体圆周上的排布、容屑槽和螺钉孔在刀体圆周上的排布、可转位成形盘铣刀刀体三维造型等3方面展开,通过转位成形盘铣刀切削试验,验证新设计的可转位成形盘铣刀有刀体利用率高、加工效率高、加工效果好等优点,尤其适用于批量加工部件。  相似文献   
7.
A chromium carbide (Cr-C) coating in-situ formed on the C/C substrate is successfully prepared by a novel reactive wetting strategy. The interfacial microstructure and oxidation resistance of coated C/C composites are investigated in detail. The as-prepared coating mainly consists of Cr23C6 and Cr7C3, forming a tight joining with the C/C substrate. Compared to uncoated samples, the oxidation weight loss of coated C/C composites is substantially reduced at high temperatures. Furthermore, the hardness of coated C/C composites is significantly increased, enhancing their ability to resist external damage. This reactive wetting strategy can also be used to prepare uniform coatings on C/C composites with complex grooved structure or large size. Surprisingly, coated C/C composites possess a low weight gain of 3.7% due to thin coating (< 10 µm), which can maintain their advantage of low density.  相似文献   
8.
张蕾  陈宁娜  许超 《冶金分析》2022,42(6):51-56
含碳化硅耐火材料已广泛地应用于冶金炉料中,目前对含碳化硅耐火材料测定常采用湿法分析,然而这些方法繁琐耗时,不适合大批量检测要求。实验采用聚酯(PET)薄膜包裹粉末压片法制样,以微晶纤维素为粘结剂,选取与待测试样粒度一致、基体相似、各成分含量有梯度的铝硅系耐火材料标准样品和碳化硅标准样品,按照不同的比例,配制成各组分含量从低到高具有一定梯度含碳化硅铝质耐火材料校准样品,对其拟合校准曲线,建立了X射线荧光光谱法(XRF)同时测定含碳化硅铝质耐火材料中TSi、Fe2O3、Al2O3、CaO、MgO、TiO2、P2O5、K2O含量的快速分析方法。采用PET薄膜包裹压片不仅减少粉尘污染,把对仪器损坏的几率降到了最低,而且可以防止压片暴露在空气中,增加压片保存时间。对含碳化硅铝质耐火材料试样进行了精密度考察,各组分测定结果的相对标准偏差(RSD,n=10)为0.08%~3.7%。采用实验方法对合成含碳化硅铝质耐火材料校准样品(未用于校准曲线绘制)和实际样品进行测定,结果与参考值或国标方法的分析值相吻合。  相似文献   
9.
摘要:利用SEM、TEM、XRD、EPMA等手段,研究了水冷、空冷和炉冷对奥氏体基FeMnAlC钢微观组织和力学性能的影响。研究结果表明,3种冷却工艺都获得了以奥氏体为基体的微观组织,均含有大量孪晶,随冷却速度的降低,沿晶界析出的铁素体和κ碳化物逐渐增多,微观结构呈现出从以位错为主到调制结构再到矩形畴界的转变过程,组织演变受合金元素的配分行为控制。与水冷样品相比,κ碳化物的析出导致炉冷和空冷样品的强度提升约200MPa,铁素体和κ碳化物的晶界析出行为导致冲击吸收能量降低约100J。  相似文献   
10.
碳化硅结势垒肖特基二极管(SiC JBS)是新一代航天器电推进系统的关键部件,但高能粒子辐射严重威胁其可靠性与稳定性。为揭示其辐射损伤机理,为其抗辐射加固设计与考核评估储备数据,本研究基于加速器开展了先进商用SiC JBS 10~20 MeV中能质子地面辐照实验,并提取器件辐照前后的正向伏安特性、反向伏安特性、电容电压等电学参数及缺陷特性。系统分析器件关键特性随辐照条件的改变规律。结果显示,质子辐照引起了器件肖特基势垒升高、载流子浓度降低,且10 MeV较低能质子导致的位移损伤退化更严重。分析认为,PN结界面缺陷导致高性能商用SiC JBS反向电学性能对中能质子的辐照更加敏感,正向特性相对稳定,辐照生碳缺陷造成载流子去除效应是引起SiC JBS性能退化的主要机制。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号