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1.
The combination of inorganic (e.g., ferrite nanoparticles) and organic (e.g., conducting polymers) materials in the fabrication of heterojunctions or composites is an attractive scheme in the field of photocatalysis. We took the advantage of this phenomenon by fabricating MFerrite (M = Co, Ni, and Zn) @polypyrrole (MFerrite@Ppy) nanocomposites with a varying weight percentage of Ppy for the hydrogen production through photocatalytic water splitting under visible light irradiation. The structural, spectral, morphological, compositional, and optical features of the as-prepared nanocomposites were analyzed in full depth. The average crystallite sizes were estimated to be 30–40 nm from the XRD patterns which were further validated by TEM images from which a core-shell structure of the composites can be inferred. Likewise, the SEM images revealed spherical Ppy particles with a diameter in the range of 100–300 nm. From a photocatalytic viewpoint, CoFerrite@30Ppy is endowed with some peculiar characteristics including but not limited to strong light-harvesting ability (ranging between 300 and 650 nm), narrow optical band gap (as low as 1.6 eV), and higher photoluminescence (PL) lifetime (6.41 ns) which justify why it stands out among all composites in terms of photocatalysis. Under 8 h illumination of simulated visible light and using triethanolamine (TEOA) as a hole scavenger and Eosin-Y (EY) as a dye sensitizer, the photocatalytic hydrogen evolution (HER) amount for CoFerrite@30Ppy was found to be 10.44 mmol g?1, far greater than any other composite catalysts in this study. From the PL spectra, it can be pointed out that sensitization of CoFerrite with 30 wt % Ppy conduces to simultaneous deceleration of the electron-hole recombination process and acceleration of the transference of excitons within the system.  相似文献   
2.
The development of cost-effective bifunctional catalysts with excellent performance and good stability is of great significance for overall water splitting. In this work, NiFe layered double hydroxides (LDHs) nanosheets are prepared on nickel foam by hydrothermal method, and then Ni2P(O)–Fe2P(O)/CeOx nanosheets are in situ synthesized by electrodeposition and phosphating on NiFe LDHs. The obtained self-supporting Ni2P(O)–Fe2P(O)/CeOx exhibit excellent catalytic performances in alkaline solution due to more active sites and fast electron transport. When the current density is 10 mA cm?2, the overpotential of hydrogen evolution reaction and oxygen evolution reaction are 75 mV and 268 mV, respectively. In addition, driven by two Ni2P(O)–Fe2P(O)/CeOx electrodes, the alkaline battery can reach 1.45 V at 10 mA cm?2.  相似文献   
3.
Electrolysis of water for producing hydrogen instead of traditional fossil fuels is one of the most promising methods to alleviate environmental pollution and energy crisis. In this work, Fe and F ion co-doped Ni3S2 nanoarrays grown on Ni foam substrate were prepared by typical hydrothermal and sulfuration processes for the first time. Density functional theory (DFT) calculation demonstrate that the adsorption energy of the material to water is greatly enhanced due to the doping of F and Fe, which is conducive to the formation of intermediate species and the improvement of electrochemical performance of the electrode. The adsorption energy of anions (F and S) and cations (Fe and Ni) to water in each material was also calculated, and the results showed that F ion showed the most optimal adsorption energy of water, which proved that the doping of F and Fe was beneficial to improve the electrochemical performance of the electrode. It is worth noting that the surface of Fe–F–Ni3S2 material will undergo reconstruction during the process of water oxidation reaction and urea oxidation reaction, and amorphous oxides or hydroxides in situ would be formed on the surface of electrode, which are the real active species.  相似文献   
4.
It is extremely desirable to develop high hydrogen evolution activity and stable visible-light-driven photocatalysts. The sluggish oxidation process and holes accumulation are the main obstacles to high catalysis activity and photo-stability. An efficient γ-NiOOH/ZnCdS photocatalyst was prepared by in-situ hydrothermal method. The γ-NiOOH nanosheets distribute on ZnCdS nanospheres surface and accelerate holes transfer. The hydrogen evolution rate is up to 48.60 mmol g?1 h?1 under visible-light illumination (λ = 400–780 nm), about 10.8 times of pure ZnCdS (4.50 mmol g?1 h?1) and 1.8 times of general β-NiOOH modified ZnCdS (27.40 mmol g?1 h?1). And apparent quantum yield of γ-NiOOH/ZCS-100 is up to 18.23% (400 nm). The carrier lifetime extends from 5.50 ns (ZnCdS) to 6.10 ns (γ-NiOOH/ZCS), examined by steady photoluminescence and time-resolved photoluminescence. Moreover, the γ-NiOOH/ZCS photocatalyst has exhibited excellent photo-stability even after one-year of storage. The γ-NiOOH nanosheets can be an excellent co-catalyst on accelerating both holes transfer and oxidation process for high photo-stability and photo-activity.  相似文献   
5.
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production.  相似文献   
6.
杨耀红  刘盈  代静 《资源与产业》2022,24(3):114-125
流域是由干流和多个、多级支流组成的相互影响的复杂系统,为了解决流域水污染和水生态环境问题,需要干流和支流各地区的共同治理。然而,现有的研究大多关注上下游水污染治理机制的研究,对于干流与多个支流间治污协作机制的研究较少,因此水污染协同治理机制很难在全流域实施。论文为系统性解决流域跨界水污染问题,形成覆盖整个流域的水污染治理机制,将上下游跨界水污染治理研究拓展到干流和两个支流,研究干流政府和两支流政府决策行为的变化规律和影响因素。基于演化博弈模型,通过构建三方政府博弈收益矩阵并求解复制动态方程,探讨补偿赔偿奖励融合机制下三方政府策略选择的演化稳定路径,并讨论了博弈均衡点策略演化的稳定条件。基于数值仿真分析了污染转移系数、干流政府对支流政府的奖励以及初始治污意愿等参数对三方策略选择的影响规律。研究结果表明:1)支流政府之间的主要影响因素是污染转移系数和初始治污意愿,某一支流污染转移系数越大,其他支流治理意愿越低,当污染转移系数超过某一临界值时,其他支流会选择不治理的策略,同时支流政府的初始治污意愿越高,其稳定于治理策略的速度越快,污染转移系数的临界值越大;2)干支流政府之间的主要影响因素是干流政府对支流政府的补偿和奖励以及支流政府对干流政府的生态赔偿,干流政府对支流政府额外治污减排的奖励越多,越能激励支流政府治污减排。研究结论可为干流和多个支流间形成生态补偿、赔偿和奖励机制以达到治污减排目标提供参考。  相似文献   
7.
Nickel selenide electrocatalysts for hydrogen evolution reaction (HER) with a high efficiency and a low-cost have a significant potential in the development of water splitting. However, the inferiority of the high overpotential and poor stability restricts their practical applications. Herein, a composite nanostructure consists of ultrasmall NiSe2 nanocrystals embedded on graphene by microwave reaction is reported. The prepared NiSe2/reduced graphite oxide (rGO) electrocatalyst exhibited a high HER activity with an overpotential of 158 mV at a current density of 10 mA/cm2 and a corresponding moderate Tafel slope of 56 mV/dec in alkaline electrolyte. In addition, a high retention of electrochemical properties (approximately 100%) was demonstrated with an unchangeable microstructure after 100 h of continuous operation.  相似文献   
8.
该研究从24份浓酱兼香型白酒二轮次出池酒醅筛选出正丙醇含量高、中、低酒醅样品,对其理化指标进行分析,采用高通量测序技术分析其微生物群落结构,基于冗余分析(RDA)探讨正丙醇产量与理化因子、微生物群落相关性。结果表明,3份酒醅样品水分、总酸、还原糖以及氨基酸态氮含量差异显著(P<0.05);共检出16个微生物属(3个细菌属,13个真菌属),其中,共有优势细菌属为乳杆菌属(Lactobacillus)(相对丰度>1%),共有优势真菌属为曲霉属(Aspergillus)、伊萨酵母属(Issatchenkia)(相对丰度>1%)。RDA结果表明,酒醅的水分、氨基酸态氮、总酸、乳杆菌属、曲霉属、伊萨酵母属、嗜热子囊菌属(Thermoascus)、毕赤酵母属(Pichia)与正丙醇产出呈负相关,还原糖、毛孢子菌属(Trichosporon)、枝芽孢杆菌属(Virgibacillus)、克罗彭斯特菌属(Kroppenstedtia)与正丙醇产出呈正相关。  相似文献   
9.
《Soils and Foundations》2022,62(1):101099
With the interests to see specimen thickness (hsp) effect on apparent swelling pressure (ps) of compacted bentonite and capture characteristics of ps development during wetting bentonite specimens (ps evolution, hereafter), a series of tests to measure ps of compacted bentonite specimens with a dry density (ρd) range of 0.99–1.76 Mg/m3 and a specimen thickness (hsp) range of 2–10 mm were conducted. Test results suggest: (1) ps evolution generally has common characteristics with four feature points chronologically: peak (tp, pp), valley (tv, pv), initial equilibrium (tei, pei) and an equilibrium (teq, peq), where, tp, tv, tei and teq represent time (t) and pp, pv, pei, and peq denote ps of the four feature points, respectively; (2) within the tested range, hsp effect is generally minor on ps at feature points, and pp, pv, pei, and peq have well correlations with specimen final dry density (ρdf); (3) time scale for specimens with different hsp can be well unified by a time coefficient χsp (=hsp/√t).  相似文献   
10.
为了使污水处理厂出水中的氮、磷浓度进一步降低,制备出了一种石灰石改性硫磺材料,通过批次实验和生物滤池实验探究其脱氮除磷性能。结果表明,硫磺/石灰石体积比为3∶1的改性材料脱氮除磷效果最佳,发泡可以提高改性材料脱氮除磷性能,改性材料对HRT有较好的适应性。当HRT=1 h,进水NO3--N、PO43--P分别为20、1 mg/L时,生物滤池NO3--N、PO43--P去除率分别高于89%、65%。微生物群落分析显示,生物滤池中硫自养反硝化菌丰度大于79%。  相似文献   
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