Synthesis,structure, CO oxidation,and H2 production activities of CaCu3−xMnxTi4−xMnxO12 (x = 0, 0.5, and 1.0)

Synthesis of nanocrystalline pristine and Mn-doped calcium copper titanate quadruple perovskites, CaCu_3?xMn_xTi_4?xMn_xO₁₂ (x = 0, 0.5, and 1.0) by modified citrate solution combustion method has been reported. Powder X-ray diffraction patterns attest the phase purity of the perovskite materials. Average particle sizes of all the materials obtained from the Scherrer's formula are in the range of 55–70 nm. The specific surface areas for all the perovskites obtained from BET isotherms are found to be low as expected for the condensed oxide systems and fall in the range of 13–17 m² g^?1. Transmission electron microscopy studies show a reduction in particle size of CaCu₃Ti₄O₁₂ with increase in Mn doping. Ca and Ti are present in +2 and +4 oxidation states in all the materials as demonstrated by X-ray photoelectron spectroscopy analyses. Cu²⁺ gets reduced in CaCu₃Ti₄O₁₂ with higher Mn content. Mn is observed to be present only in +3 oxidation state. All the materials have been examined to be active in CO oxidation as well as H₂ production from methanol steam reforming. CaCu₃Ti₄O₁₂ with ~14 at.% Mn is found to show best catalytic activities among these materials. A comprehensive analysis of the catalytic activities of these perovskites toward CO oxidation and H₂ production from MSR reveal the cooperative activity of copper-manganese in the doped perovskites and it is more effective at lower manganese content.     

瓦斯抽采钻孔水射流协同修护技术研究与应用

瓦斯抽采钻孔普遍存在因变形、煤渣积聚及塌孔等导致钻孔堵塞和抽采效果差的问题。通过分析钻孔塌堵失稳机制,得出煤岩体性质、地质构造及多应力耦合条件是造成钻孔失稳的主要因素,进而推断相应堵孔段情形。利用高压水射流解堵作用,提出了水射流疏通-筛管护孔协同修护技术,并研制出轻型气动钻孔修复装备。应用结果表明,该协同修护技术能有效解决瓦斯抽采钻孔塌堵后无法有效抽采的技术难题,试验钻孔修护深度达到50 m,修护完成后单孔抽采瓦斯浓度和瓦斯纯流量比修复前提高0.57~3.67倍和0.99~5.15倍,抽采效果大幅改善,实现了塌堵钻孔的快速便捷修复进而确保了瓦斯流动通道的畅通。     

一种大型复杂构件加工新模式及新装备探讨

大型复杂构件是航空航天、能源、船舶等领域装备的核心结构件，此类构件通常具有尺寸大、形状复杂、刚性弱等特点。传统“分体离线加工-在线检测”模式存在工艺不稳定、过程复杂、柔性差、周期长等问题，以龙门式多轴数控机床加工为代表的“包容式”加工模式，难以适应大型复杂构件的高效高质量加工制造需求。提出一种基于移动式和吸附式机器人的多机协同原位加工新模式，通过多机器人系统自主寻位、精确定位加工与加工质量原位检测，实现大型复杂构件多安装面并行铣削、制孔与打磨等作业。多机器人系统包括移动式混联机器人、吸附式并联机器人、移动式串联铣削机器人、移动式双臂加工机器人和移动式打磨机器人。构建多机协同原位加工模式，需要揭示多机器人协同原位加工行为与大型弱刚性结构件质量控制的交互机理，面临着本体、测量、工艺和集成四个方面的挑战，需要设计高灵活、高刚度的移动式和吸附式加工机器人，解决移动机器人自主准确寻位和超大结构件原位高精检测难题，攻克加工变形误差在线补偿和振动抑制技术，通过集成实现多机协同高效高精加工，为大型复杂构件的高效高质量制造提供创新技术及装备，并实现此类构件制造核心技术及装备自主可控。     

超声强化过氧化氢-维生素C体系糖汁脱色的研究

研究超声强化过氧化氢-维生素C复合脱色剂体系对糖汁脱色的规律,考察了超声功率、复合脱色剂用量、超声温度和时间对糖汁脱色率的影响。试验结果表明:超声空化强化过氧化氢-维生素C对糖汁具有良好的脱色效果,当处理糖汁量为100 mL,超声功率为260 W,过氧化氢与维生素C的用量均为1.6 mL,空化温度为70℃,超声时间为6 min时,脱色率达到53.4%。通过正交试验分析,得到各个因素对糖汁脱色率影响的主次关系为:超声功率>复合脱色剂用量>超声时间>空化温度。     

基于协同多目标算法的多机器人路径规划

多机器人路径规划是群体机器人协同工作的前提,其特点是在防碰撞与避障的前提下追求多方面资源的最小消耗.针对这一特点,提出协同非支配排序遗传算法,解决具有多个优化目标的多机器人路径规划问题;运用改进的多目标优化算法,克服多目标优化取权值的不足,同时考虑机器人能源与时间两大资源,以多机器人的路径总长度、总平滑度、总耗时为规划目标.同时引入合作型协同算法框架,将难以求解的多变量问题分组求解.每个机器人的路径视为子种群,子种群通过带精英策略的非支配排序遗传算法,进化并筛选出子种群的部分进入协同进化,每次迭代更新外部的精英解集,最终生成一组非支配路径解.仿真结果表明,在栅格地图环境下,本文算法可有效实现多移动机器人的多优化目标路径规划.     

A resilient buffer allocation scheme in active queue management: a stochastic cooperative game theoretic approach

During the last decade, a plentiful number of active queue management schemes have been proposed, but their main objectives are simply allocating the buffer resource to all flows evenly, or protecting responsive flows from being degraded by unresponsive flows. However, the sending rates of the responsive flows can be determined diversely, and not all unresponsive flows have aggressively high sending rates. Furthermore, it is rational to reserve a portion of the buffer resource for certain privileged traffic. Grounded by these evidences, in this paper, we present a resilient active queue management algorithm, named Prior‐Core‐based Buffer Allocation considering diverse congestion control algorithms, fair‐unresponsive flows, and some privileged traffic. Our approach is based on stochastic cooperative game theory, where the payoffs yielded by cooperation are described by random variables, and the core is defined only over the distribution of these random payoffs; the core in this situation is called the prior‐core. As a result, it is shown that our buffer allocation, yielded by the prior‐core, achieves completely fair allocation for those flows whose requirement does not exceed the fair‐share regardless of the responsiveness, whereas aggressive flows are restricted according to availability of the buffer; all these are verified through ns‐2 simulation experiments. Copyright © 2014 John Wiley & Sons, Ltd.     

Nash equilibrium cooperative transmission strategy considering competition

In cooperative communications, employing the idle relay node for forwarding data can effectively improve the transmission rate and performance of the wireless networks. Therefore, various relay node selection algorithms are proposed. However, most of the existing algorithms just focus on the benefit caused by relay nodes, while ignoring the negative effect of the backoff duration time which does not exist in direct transmission, when more than one flow compete for the same relay node. To this end, considering both advantage and adverse impact caused by the relay node, we adopt the game-theoretic approach and propose a cooperative transmission strategy based on the Nash equilibrium, named the Nash Equilibrium Cooperative Transmission Strategy (NECTS). The NECTS can not only guarantee the gain of each flow, but also maximize the system performance, and improve the system throughput effectively. Simulation results show that the NECTS can take the advantage of cooperative communications. Meanwhile, it can avoid the unnecessary competition, and its performance outperforms that of the existing methods.     

考虑交叉销售的O2O供应链合作广告策略研究

基于网络零售平台与制造商的合作广告实践，运用Stackelberg博弈理论研究了平台交叉销售效应及合作广告引导作用对O2O供应链合作广告决策的影响，并通过数值算例对参与合作广告计划前后渠道成员的决策变量均衡结果和利润进行对比分析，研究发现平台交叉销售效应是影响网络零售平台合作广告计划制定和实施的关键因素，只有当其达到一定水平时，制造商才拥有参与网络零售平台合作广告计划的资格；在一定条件时，合作广告计划能够实现制造商和网络零售平台利润的提升；当平台交叉销售效应较大时，网络零售平台获得的利润大于制造商。     

我国现状能源与水纽带关系定量识别

以省级行政区为研究对象,以2017年为研究时段,分析我国社会水循环过程耗能及电力生产耗水。结果显示:2017年我国社会水循环过程耗电总量为10 828.1亿kW·h,占当年我国全社会用电总量的17.2%,终端用水是最大的耗能环节;2017年我国电力生产过程耗水量为65.7亿m~3,占当年全社会耗水总量的2%;火电是我国最耗水的电源,其耗水量占全国电力开发耗水总量的78%。基于计算结果,提出了实现能源-水协同安全的相关建议。     

政府和社会资本间信任对PPP项目绩效的影响——合作行为的中介作用

为解释以往关于信任对项目绩效正向或负向影响的研究分歧，以 PPP 项目为背景，构建以信任（能力信任和善意信任）为自变量、项目绩效为因变量、合作行为（角色内行为和角色外行为）作为中介变量的理论模型。通过结构方程模型分析 286 份有效问卷，结果表明:能力信任和善意信任对 PPP 项目绩效起正向促进作用，角色内行为和角色外行为对 PPP项目绩效起正向促进作用。同时，角色内行为和角色外行为在能力信任、善意信任与 PPP 项目绩效间均发挥部分中介作用。研究结果有助于深入理解中国 PPP 情境下不同维度信任对项目绩效的影响，也为 PPP 项目实践中面临的绩效低下问题提供了管理建议。