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1.
基于分形几何理论,考虑微凸体因应变硬化而造成弹塑性变形阶段硬度随变形量变化而变化,建立结合面第一、第二弹塑性变形阶段单次加载刚度分形模型。推导出在计入硬度变化的情况下,单个微凸体在弹塑性变形阶段法向接触刚度与接触面积之间的关系式,进而得出结合面在弹塑性变形阶段法向接触刚度与接触面积、接触载荷之间量纲为一的关系式,并通过仿真分析得出相关参数对结合面法向接触刚度的影响。仿真结果显示:考虑硬度变化时,结合面量纲一法向接触刚度的值与法向实际接触载荷、实际接触面积之间存在关系;结合面法向接触刚度随着分形维数D的增大而增大;分形维数一定时,结合面法向接触刚度随表面长度尺度参数G值增大而增大。 相似文献
2.
目的 提高缓蚀剂在酸溶液中的缓蚀性能.方法 构建含有2-巯基苯并噻唑(MBT)以及不同浓度Cl–的Fe表面溶液模型,并进行分子动力学计算.观察缓蚀剂分子在Fe表面的吸附构型,考察不同Cl–值下缓蚀剂膜的致密化行为.提取缓蚀剂分子的均方位移(MSD)曲线,评价缓蚀剂膜的稳定性.计算水分子的密度分布和扩散系数,考察不同Cl–值下MBT缓蚀剂膜的驱水能力和水分子的迁移能力.结果 当Cl–值从0增加到25时,MBT膜的厚度(0.42~1.51 nm)和致密度(占有面积0.33~1.31 nm2)增加,缓蚀剂分子的自扩散系数减小(从1.25×10–9 m2/s到接近0),水分子的吸附峰强度(相对密度为72.3~33.9 nm–3)和扩散系数(1.495×10–9~0.627×10–9 m2/s)降低.当Cl–值从25增加到36时,则出现了相反的趋势.结论 缓蚀剂分子与Cl–之间存在协同作用,适当浓度的KCl可以提高MBT缓蚀剂在H2SO4溶液中的缓蚀性能.Cl–值为25时,MBT缓蚀效率最高. 相似文献
3.
Yuelong Ma Le Zhang Tianyuan Zhou Bingheng Sun Chen Hou Shunshun Yang Jin Huang Rui Wang Farida A. Selim Zhongying Wang Ming Li Hao Chen Yun Wang 《Journal of the European Ceramic Society》2021,41(4):2834-2846
Ce:Y3Al5O12 transparent ceramics (TCs) with appropriate emission light proportion and high thermal stability are significant to construct white light emitting diode devices with excellent chromaticity parameters. In this work, strategies of controlling crystal-field splitting around Ce3+ ion and doping orange-red emitting ion, were adopted to fabricate Ce:(Y,Tb)3(Al,Mn)5O12 TCs via vacuum sintering technique. Notably, 85.4 % of the room-temperature luminescence intensity of the TC was retained at 150 °C, and the color rendering index was as high as 79.8. Furthermore, a 12 nm red shift and a 16.2 % increase of full width at half maximum were achieved owing to the synergistic effects of Tb3+ and Mn2+ ions. By combining TCs with a 460 nm blue chip, a warm white light with a low correlated color temperature of 4155 K was acquired. Meanwhile, the action mechanism of Tb3+ ion and the energy transfer between Ce3+ and Mn2+ ions were verified in prepared TCs. 相似文献
4.
Haiyue Xu Ji Zou Weimin Wang Hao Wang Wei Ji Zhengyi Fu 《Journal of the European Ceramic Society》2021,41(1):635-645
Fully dense ceramics with retarded grain growth can be attained effectively at relatively low temperatures using a high-pressure sintering method. However, there is a paucity of in-depth research on the densification mechanism, grain growth process, grain boundary characterization, and residual stress. Using a strong, reliable die made from a carbon-fiber-reinforced carbon (Cf/C) composite for spark plasma sintering, two kinds of commercially pure α-Al2O3 powders, with average particle sizes of 220 nm and 3 μm, were sintered at relatively low temperatures and under high pressures of up to 200 MPa. The sintering densification temperature and the starting threshold temperature of grain growth (Tsg) were determined by the applied pressure and the surface energy relative to grain size, as they were both observed to increase with grain size and to decrease with applied pressure. Densification with limited grain coarsening occurred under an applied pressure of 200 MPa at 1050 °C for the 220 nm Al2O3 powder and 1400 °C for the 3 μm Al2O3 powder. The grain boundary energy, residual stress, and dislocation density of the ceramics sintered under high pressure and low temperature were higher than those of the samples sintered without additional pressure. Plastic deformation occurring at the contact area of the adjacent particles was proved to be the dominant mechanism for sintering under high pressure, and a mathematical model based on the plasticity mechanics and close packing of equal spheres was established. Based on the mathematical model, the predicted relative density of an Al2O3 compact can reach ~80 % via the plastic deformation mechanism, which fits well with experimental observations. The densification kinetics were investigated from the sintering parameters, i.e., the holding temperature, dwell time, and applied pressure. Diffusion, grain boundary sliding, and dislocation motion were assistant mechanisms in the final stage of sintering, as indicated by the stress exponent and the microstructural evolution. During the sintering of the 220 nm alumina at 1125 °C and 100 MPa, the deformation tends to increase defects and vacancies generation, both of which accelerate lattice diffusion and thus enhance grain growth. 相似文献
5.
基于流体体积法和k-ε湍流模型对液化天然气单液滴在气流中的变形破碎情况进行模拟研究。研究不同We对液滴形态和破碎模式的影响,分析液滴形态变化过程中速度、加速度和阻力系数随时间的变化趋势,并研究不同流场下液滴变形破碎情况。结果表明,不同的We下,液滴呈现出不同的破碎模式,液滴发生剪切破碎的临界We为80左右,同一We下不同直径的液滴临界破碎时间有所不同;随着气液相对速度的We的增大,液滴的无量纲变形时间先递减后趋向于平缓;液滴变形破碎过程中,速度随着时间的延长而增加,加速度和阻力系数随着时间的延长先增后减;与普通流场相比,带挡板的流场中液滴变形破碎时间明显缩短。 相似文献
6.
针对传统雷达差分干涉测量技术(DInSAR)无法利用相位信息识别矿区大量级沉降区域地表活动信息的问题,本文采用时序振幅分析方法,对16景Sentinel-1A的振幅数据进行多时相处理,提取了2017年5月13日至2018年2月25日开采沉陷区地表后向散射系数。通过建立研究区后向散射系数分析模型,分析了开采活动过程中地表后向散射系数时序变化特征,发现地表后向散射系数由工作面外边缘至工作面中心逐渐增大,在工作面中心区域变化剧烈;通过对比分析工作面走向和倾向地表特征观测点的沉降速率与后向散射系数的关系,发现两者在开采沉陷过程中平均相关系数r大于0.8,具有较强的相关性。实验结果表明,利用沉陷区地表后向散射系数能较好地分析地表动态沉降速率规律,是识别大量级沉降区域地表活动剧烈程度的指标,为矿区地表变形提供了新的分析手段,具有良好的应用前景。 相似文献
7.
低透气性突出煤层顺层钻孔预抽回采工作面瓦斯具有工程量大,抽采效率低等特点,为此,采用顺煤层分段水力压裂实现煤储层增透。寺家庄矿15#煤层属于低透气性突出煤层,在15301工作面开展了顺煤层分段水力压裂强化抽采试验,利用自主研发的拖动式双封隔器分段封孔装备及工艺,满足压裂孔稳定、快速封隔,可实现全孔段分三段及以上逐级开展压裂。对比压裂区和非压裂顺层钻孔瓦斯抽采效果,压裂区平均浓度为35.1%,非压裂区为6.0%,压裂区浓度是非压裂区的5.9倍;压裂区百孔纯量为3.6 m3/min,非压裂区为0.3 m3/min,压裂区百孔纯量是非压裂区的11.2倍。 相似文献
8.
为了探索10%龙灯·喜乐龙与20%噻虫胺对甘蔗螟虫及蓟马、蚜虫的防治效果及用量,2019年在云南省陇川县蔗区进行试验。试验结果表明,龙灯·喜乐龙与噻虫胺对甘蔗螟虫具有较好的防治效果,10%龙灯·喜乐龙SC+20%噻虫胺(13500+1350 g/hm2、1800+1800 g/hm2、2250+2250 g/hm2)对甘蔗螟虫防治效果显著,与空白对照比,对螟害株的防治效果分别达到了100%、97.56%、96.34%,对螟害节的防治效果分别达到了100%、98.98%、98.48%。 相似文献
9.
Dr. Thomas Le Bihan Dr. Cathryn H. S. Driver Dr. Thomas Ebenhan Dr. Nathalie Le Bris Dr. Jan Rijn Zeevaart Prof. Dr. Raphaël Tripier 《ChemMedChem》2021,16(5):809-821
An improved glucose-chelator-albumin bioconjugate (GluCAB) derivative, GluCAB-2Mal, has been synthesized and studied for in vivo 64Cu-PET/CT imaging in breast cancer mice models together with its first-generation analogue GluCAB-1Mal. The radioligand works on the principle of tumor targeting through the enhanced permeability and retention (EPR) effect with a supportive role played by glucose metabolism. [64Cu]Cu-GluCAB-2Mal (99 % RCP) exhibited high serum stability with immediate binding to serum proteins. In vivo experiments for comparison between tumor targeting of [64Cu]Cu-GluCAB-2Mal and previous-generation [64Cu]Cu-GluCAB-1Mal encompassed microPET/CT imaging and biodistribution analysis in an allograft E0771 breast cancer mouse model. Tumor uptake of [64Cu]Cu-GluCAB-2Mal was clearly evident with twice as much accumulation as compared to its predecessor and a tumor/muscle ratio of up to 5 after 24 h. Further comparison indicated a decrease in liver accumulation for [64Cu]Cu-Glu-CAB-2Mal. 相似文献
10.
Optimization of room-temperature TCR of polycrystalline La0.9-xSrxK0.1MnO3 ceramics by Sr adjustment
Hongjiang Li Kaili Chu Xingrui Pu Xiaohan Yu Xiaoli Guan Shuaizhao Jin Xiang Liu 《Ceramics International》2021,47(1):94-101
High-density La0.9-xSrxK0.1MnO3 ceramics (LSKMO, A-site = La, Sr and K, 0 ≤ x ≤ 0.25) are successfully fabricated by using facile sol-gel method. Electrical properties are performed by using combination of phenomenological percolation (PP) model, double exchange (DE) mechanism, and Jahn-Teller (JT) effect. Moreover, X-ray diffraction and scanning electron microscopy are employed to analyze the structure and morphology of LSKMO ceramics. Valence states and ionic stoichiometry are assessed by using X-ray photoemission spectrometry. Results reveal that Sr2+ ions, substituting La3+ ions, significantly influenced DE mechanism and JT effect. In addition, Sr-doping plays essential role in improving electrical properties of LSKMO ceramics. At optimal doping content of x = 0.09, peak temperature coefficient of resistance (TCR) of the resistivity is found to be 11.56% K?1 at 297.15 K, which is optimal TCR for A-site K-occupied perovskite manganese oxides. These results confirm that polycrystalline LSKMO ceramics render high room-temperature TCR values due to Sr-doping. 相似文献