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1.
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light.  相似文献   
2.
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB.  相似文献   
3.
为研究高面板堆石坝的地震易损性,基于增量动力分析(IDA)与支持向量机(SVM)相结合的方法,首先利用拉丁超立方抽样(LHS)方法从人工生成的100条地震动中随机选取30条,选定PGA为地震动强度指标,坝顶竖向位移为性能指标,通过对每条地震动进行等间距调幅,对面板坝进行有限元计算及对结果进行IDA分析,提取各条地震动在所选性能指标不同极限状态下的PGA;然后引入SVM,以代表地震动特性的参数为输入,以PGA为输出,训练并测试SVM模型;最后利用SVM模型做快速预测,在考虑不同地震动数目的条件下,分析面板坝的地震易损性,并绘制地震易损性曲线。研究结果表明,IDA-SVM方法在分析大坝易损性的问题上具有可行性和有效性,且考虑不同地震动数目所得的地震易损性曲线不尽相同。  相似文献   
4.
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production.  相似文献   
5.
针对燃气轮机故障诊断过程中诊断精度不足,卡尔曼滤波易出现“弥散”现象的问题,提出了一种基于滤波阵列的燃气轮机气路故障诊断方法。该方法首先构建了一组基于健康参数调度的平衡流形展开模型阵列,然后结合平方根容积卡尔曼滤波对气路部件健康参数进行了实时估计,最后通过隔离因子实现了对故障部件的检测与隔离。仿真表明:该方法有效解决了卡尔曼滤波在故障诊断过程中出现“弥散”现象的问题,针对燃气轮机气路部件突变故障,能够有效实现故障的检测、隔离与估计。  相似文献   
6.
超前采动影响巷道维护困难,易产生大变形,以干河煤矿2-1261巷为工程背景,提出了超前采动影响围岩控制技术,该技术包括锚网索联合支护和超前采动临时加强支护。监测结果显示,在巷道掘进期间以及超前采动影响时期,其变形均在可控范围内。  相似文献   
7.
为解决矿井大埋深工作面接续及安全生产问题,结合现场地质条件,采用了沿空留巷工艺优化实施方案,提出了关键技术工艺及要求,形成了一套完整的留巷技术方案,缓解了接续,保证了安全生产。  相似文献   
8.
Nonintrusive load monitoring (NILM) is crucial for extracting patterns of electricity consumption of household appliance that can guide users’ behavior in using electricity while their privacy is respected. This study proposes an online method based on the transient behavior of individual appliances as well as system steady-state characteristics to estimate the operating states of the appliances. It determines the number of states for each appliance using the density-based spatial clustering of applications with noise (DBSCAN) method and models the transition relationship among different states. The states of the working appliances are identified from aggregated power signals using the Kalman filtering method in the factorial hidden Markov model (FHMM). Thereafter, the identified states are confirmed by the verification of system states, which are the combination of the working states of individual appliances. The verification step involves comparing the total measured power consumption with the total estimated power consumption. The use of transient features can achieve fast state inference and it is suitable for online load disaggregation. The proposed method was tested on a high-resolution data set such as Labeled hIgh-Frequency daTaset for Electricity Disaggregation (LIFTED) and it outperformed other related methods in the literature.  相似文献   
9.
Nickel selenide electrocatalysts for hydrogen evolution reaction (HER) with a high efficiency and a low-cost have a significant potential in the development of water splitting. However, the inferiority of the high overpotential and poor stability restricts their practical applications. Herein, a composite nanostructure consists of ultrasmall NiSe2 nanocrystals embedded on graphene by microwave reaction is reported. The prepared NiSe2/reduced graphite oxide (rGO) electrocatalyst exhibited a high HER activity with an overpotential of 158 mV at a current density of 10 mA/cm2 and a corresponding moderate Tafel slope of 56 mV/dec in alkaline electrolyte. In addition, a high retention of electrochemical properties (approximately 100%) was demonstrated with an unchangeable microstructure after 100 h of continuous operation.  相似文献   
10.
采用现有方法预测短期变速恒频风力发电系统的风速时,因未分析风力机的运行特性而导致无法准确预测系统的输出无功功率、输出有功功率和短期风速,且预测结果的平均绝对误差和均方误差大,为此提出变速恒频风力发电系统风速的预测方法。首先对风力机的运行特性进行分析,然后采用支持向量机回归算法构建风速预测模型,最后利用风速预测模型完成变速恒频风力发电系统风速的短期预测。实验结果表明,所提方法可准确地预测系统的输出无功功率、输出有功功率和短期风速,且预测结果的平均绝对误差和均方误差小,验证了所提方法的整体有效性。  相似文献   
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