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1.
An analytical model for gas leakage through contact interface in proton exchange membrane fuel cells
《International Journal of Hydrogen Energy》2022,47(75):32273-32286
Sealing performance between two contacting surfaces is of significant importance to stable operation of proton exchange membrane (PEM) fuel cells. In this work, an analytical micro-scale approach is first established to predict the gas leakage in fuel cells. Gas pressure and uneven pressure distribution at the interface are also included in the model. At first, the micro tortuous leakage path at the interface is constructed by introducing contact modelling and fractal porous structure theory. In order to obtain the leakage at the entire surface, contact pressure distribution is predicted based on bonded elastic layer model. The gas leakage through the discontinuous interface can be obtained with consideration of convection and diffusion. Then, experiments are conducted to validate the numerical model, and good agreement is obtained between them. Finally, influences of surface topology, gasket compression and gasket width on leakage are studied based on the model. The results show that gas leakage would be greatly amplified when the asperity standard deviation of surface roughness exceeds 1.0 μm. Gaskets with larger width and smaller thickness are beneficial to sealing performance. The model is helpful to understand the gas leakage behavior at the interface and guide the gasket design of fuel cells. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(83):35423-35436
The gas diffusion substrate (GDS) is essential in the proton exchange membrane fuel cells. Its fabrication techniques affect the performance significantly and are worthy of investigation. In this study, a manufacturing process of the GDS is proposed to understand the formation process of GDS and promote its structure and performance more pertinently. Different states during the preparation process, raw carbon paper, pre-curing, curing, carbonation, and graphitization, are characterized and measured. Experimental and numerical methods are employed to determine the relationships between microstructure, transport, and mechanical performance variation with the fabricating processes. The results show that its porosity, average pore size, and effective diffusivity decrease first and increase after curing. These parameters after graphitization are lower than that of the carbon paper (CP). The electrical resistivity increases dramatically while pre-curing and decreases gradually after curing, carbonation, and graphitization, and it is much reduced after graphitization. Moreover, mechanical measurement results show that both the picks of tensile strength and flexural modulus occur after curing. Its tensile strength shows little change after graphitization compared to the initial paper's. In contrast, the flexural modulus is improved significantly. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(92):39204-39214
In this work, the SnS2 nanoflowers (SnS2 NFs) were solvothermally prepared in the solvent of ethanol, while SnS2 nanoplates (SnS2 NPs) were obtained through the identical conditions except for the solvent of water. The flowers were assembled with numerous nanosheets with very thin thickness, and the NPs exhibited hexagonal shape. When used as the battery-type electrode material for supercapacitors, the SnS2 NFs delivered a specific capacity of as high as 264.4 C g?1 at 1 A g?1, which was higher than the 201.6 C g?1 of SnS2 NPs. Furthermore, a hybrid supercapacitor (HSC) was assembled with the SnS2 as positive electrode and activated carbon (AC) as negative electrode, respectively. The SnS2 NFs//AC HSC exhibited a high energy density of 28.1 Wh kg?1 at 904.3 W kg?1, which was higher than the 24.2 Wh kg?1 at 844.3 W kg?1 of SnS2 NPs//AC HSC. Especially, when the power density was enhanced to the highest value of 8666.8 W kg?1, the NFs-based device could still hold 20.4 Wh kg?1. In addition, both HSC devices showed an excellent cycling stability after 5000 cycles at 5 A g?1. The present method is simple and can be extended to the preparation of other transition metal sulfides (TMSs)-based electrode materials with brilliant electrochemical performance for supercapacitors. 相似文献
4.
为提高跨临界CO2空气源热泵热水系统运行性能,对不同压缩机频率、电子膨胀阀开度和水流量下的系统及部件运行特性进行了实验研究,并对循环加热模式下的调节方式进行了优化。结果表明:当阀开度减小时,系统性能系数COP和制热量随过热度的增大而减小;压缩机存在最大电效率点,并且电效率极值点会随着运行频率的增大而向低过热度段发生移动;与电子膨胀阀调节方式相比,水流量调节方案下系统COP提升了13.22%;在循环加热模式下不同加热时期的最优阀开度并不相同,根据最优高压理论对其调节方式进行了优化,最大优化率为15.96%。 相似文献
5.
为了研究不可凝气体(non-condensable gases, NCG)对火电与光热发电机组上广泛使用的大扁管空冷凝汽器性能的影响,以工程机组凝汽器上普遍应用的通流面积220 mm×20 mm的大扁管为研究对象,针对汽轮机典型工况下的实际蒸汽流量,基于Lee相变方程、VOF方法以及组分扩散模型,对蒸汽与NCG混合气体管内两相流凝结换热进行数学建模与数值计算。结果表明:由于大扁管的狭窄通流几何结构与高蒸汽流量,NCG对管内蒸汽凝结的抑制效果要远低于预期;当入口空气质量分数按2%增加时,凝结管凝结换热系数仅下降2%左右,这与NCG导致低流量圆管凝结性能急剧下降的结论不同;空气正常泄漏不会导致空冷凝汽器性能下降而影响发电机组效率。 相似文献
6.
为了提高燃气轮机性能数字孪生体求解过程的鲁棒性,提出了一种基于改进广义牛顿法的燃气轮机性能数字孪生体构建方法。首先,选择广义牛顿法作为性能数字孪生体的求解方法;其次,在广义牛顿迭代法的基础上,调整隐式非线性方程对应曲线切线的斜率,改进广义牛顿法的初值设置方法;最后,构建性能数字孪生体,将改进广义牛顿法嵌入性能数字孪生体。通过PGT25+型燃气轮机实测数据验证提出的方法,结果表明:扩大初值范围后,基于改进广义牛顿法的性能数字孪生体的仿真精度仍与原始方法一致,该方法能够提高性能数字孪生体的鲁棒性,扩大性能数字孪生体的适用范围。 相似文献
7.
In the present work, the heating performance of a new system combined with a new modified baseboard radiator and fan coil is investigated. Using longitudinal fins with special geometry and also forced airflow at the end of the system causes that at the lower inlet water temperature compared with the conventional models, higher heat output rate be obtained. The heat output rate of the new modified system is obtained by experimental metrology based on the European Standard No. EN-442. Temperature and velocity distribution in the room space is done by simulation of the modified system in the Flovent software. Computational fluid dynamics (CFD) results are validated against experimental results and there is a good agreement between them. Also, the energy consumption of the system during the winter season is calculated in TRANSYS software. Experimental results show that the heat output rate of a new modified heating system with inlet water temperature in the range of 45–55°C is on average 4.17 times higher compared with the conventional model. CFD simulation also showed that the combined system provides good thermal comfort conditions. Energy consumption of the new system reduced about 13% compared with conventional models. 相似文献
8.
为改善H型垂直轴风力机(VAWT)的气动特性,文章研究了6种翼型型线改变后的翼型对H型VAWT气动特性的影响,并进行了数值模拟计算和风洞试验。风洞试验验证了模拟计算的结果,证明了型线改变后的风力机对提高气动性有积极的作用。试验结果表明:1波浪型风机和Dimple型风机均可在一定叶尖速比(λ)范围内提高风力机的风能利用率,其中1波浪型风力机在低λ下最高可提高风能利用率13.76%,其单叶片切向力在下游区明显增大;Dimple型风力机在高λ下最高可提高风能利用率14.6%,其单叶片切向力在上游区明显增大。两种改型后的翼型均可改善流动分离,并提高VAWT的气动性能。 相似文献
9.
《Journal of dairy science》2022,105(5):4171-4188
Based on modeling studies, a 1-yr calving interval for dairy cows is generally considered optimal from an economic point of view. Recently some dairy farmers are deliberately extending the voluntary waiting period for insemination (VWP) to extend the calving interval. Reasons to extend the VWP are to reduce the frequency of transitions such as dry-off and calving to improve health, to reduce labor associated with these transitions, and to reduce the number of surplus calves. This study aimed to evaluate yearly revenues, yearly costs, and yearly net partial cash flow (NPCF) for individual cows with a VWP of 50, 125, or 200 d based on data from a randomized control trial. The NPCF included revenues and costs for milk yield, calves born, inseminations, concentrate supply, partial mixed ration (PMR) supply, veterinary treatments, discarded milk due to veterinary treatments, culling, and labor (for milking, calving cows, inseminations, and veterinary treatments). Holstein-Friesian dairy cows (n = 153) within one herd were blocked for parity, calving season, and expected (primiparous cows) or previous (multiparous cows) 305-d milk yield. Cows were randomly assigned within the blocks to 1 of 3 VWP (VWP50, VWP125, or VWP200) in wk 6 after calving, and monitored from wk 6 after calving until wk 6 after the next calving or until culling. Revenues and costs were calculated per individual cow and expressed per cow per year. Revenues from milk and costs for PMR and concentrate contributed most to the yearly NPCF. Total yearly revenues were greater in VWP50 compared with VWP200 (€3,169 vs. €2,832), mainly because of €334 greater milk revenues. Total yearly costs were also greater in VWP50 compared with VWP200 (€1,964 vs. €1,729), mainly because of €102 greater concentrate costs. The VWP was not significantly associated with the NPCF per cow per year. A change in milk, feed, or calf price, or a change in labor costs for calving cows or for inseminations had a greater effect on the yearly NPCF of cows in VWP50 compared with cows in VWP200. To investigate variation in NPCF, cows were grouped for yearly NPCF and categorized into 3 economic classes (EC): EC1 (<€1,100/yr), EC2 (€1,100–€1,400/yr), and EC3 (>€1,400/yr). Cows in EC3 had greatest lactation production per day in the experiment (i.e., kg of milk, protein, fat, lactose), and lowest number of veterinary treatments during the experiment. 相似文献
10.
《Soils and Foundations》2022,62(3):101150
The circular helicoid pile (CH pile) is a new type of special-shaped pile that has been developed in Japan and South Korea in the past decade and has been widely used in the fields of construction, transportation, natural energy and agriculture due to its excellent compressive and pullout bearing performances. Consequently, this new type of pile has good engineering application prospects. However, as an innovative engineering structure, the CH pile is not widely known by geotechnical engineers worldwide. The geometric structure of the CH pile is similar to a circular helicoid in differential geometry. Therefore, the pile-soil interaction problem cannot be reduced to a plane strain problem or an axisymmetric problem in theoretical research. In view of this, dry silica sand was used as the model foundation in this study, and a model test device and method that can effectively reflect the installation process and loading-bearing service state of CH piles were developed. Under different installation methods, pile structures and foundation soil conditions, 90 model tests were carried out to evaluate the engineering performances of CH piles during the whole process of installation and bearing, including the installation performances during the installation process, the compressive bearing performances under axial compressive loading and the pullout bearing performances under axial pullout loading. Compared with steel sheet piles and steel pipe piles, CH piles have better engineering performance and more economic benefits from the aspects of installation, construction, recycling, timeliness of engineering application, and the relative relationship between bearing capacity and pile mass. 相似文献