全文获取类型
收费全文 | 822篇 |
免费 | 56篇 |
国内免费 | 23篇 |
专业分类
电工技术 | 9篇 |
技术理论 | 1篇 |
综合类 | 63篇 |
化学工业 | 248篇 |
金属工艺 | 13篇 |
机械仪表 | 94篇 |
建筑科学 | 41篇 |
矿业工程 | 18篇 |
能源动力 | 25篇 |
轻工业 | 145篇 |
水利工程 | 12篇 |
石油天然气 | 9篇 |
武器工业 | 3篇 |
无线电 | 24篇 |
一般工业技术 | 74篇 |
冶金工业 | 68篇 |
原子能技术 | 17篇 |
自动化技术 | 37篇 |
出版年
2024年 | 2篇 |
2023年 | 20篇 |
2022年 | 27篇 |
2021年 | 35篇 |
2020年 | 40篇 |
2019年 | 19篇 |
2018年 | 15篇 |
2017年 | 22篇 |
2016年 | 17篇 |
2015年 | 22篇 |
2014年 | 36篇 |
2013年 | 38篇 |
2012年 | 45篇 |
2011年 | 48篇 |
2010年 | 36篇 |
2009年 | 33篇 |
2008年 | 34篇 |
2007年 | 33篇 |
2006年 | 48篇 |
2005年 | 54篇 |
2004年 | 43篇 |
2003年 | 29篇 |
2002年 | 23篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 15篇 |
1998年 | 14篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 15篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 10篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1958年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有901条查询结果,搜索用时 15 毫秒
1.
《Advanced Powder Technology》2022,33(11):103833
Eliminating the gold preg-robbing effect of carbonaceous matter in carbonaceous gold ores is crucial for gold leaching. In this study, suspension oxidation roasting was proposed to accelerate the decarbonization of carbonaceous gold ore. The characteristics of oxidation reaction process and gas release were analyzed by TG-DTA-FTIR. The phase transformation and microstructure evolution of samples during roasting were analyzed by XRD, SEM and BET. The results show that the gold preg-robbing effect was eliminated after the gasification of carbonaceous matter, and the CaO generated by decomposition of carbonates can effectively capture the SO2. After roasting for 75 min at 650 °C in a 20% O2 atmosphere, the total carbon removal rate reached 99.42%, the distribution of exposed gold increased from 28.85% to 77.10% and the gold leaching efficiency increased from 4.55% to 84.83%. In addition, about 70% sulfur was mainly fixed in the roasted products in the form of sulfate. Therefore, the suspension oxidation roasting process is an efficient and clean pretreatment method for carbonaceous gold ores. 相似文献
2.
《Ceramics International》2022,48(14):20062-20069
Photocatalytic N2 fixation is a promising and sustainable manufacturing process of ammonia (NH3); however, the NH3 production rate by this method is very low, thus severely restricting further application of this sustainable technology. Therefore, developing an efficient photocatalyst for N2 fixation under mild conditions is urgently required. Herein, ferroelectric Bi2WO6 materials with different surface oxygen defects were prepared, and the concentration of corresponding defects was controlled by adjusting the thermal reduction time. The abundant oxygen defects in Bi2WO6 can provide more reactive sites to promote the effective adsorption of N2, and the photogenerated charge carrier can be efficiently separated benefiting from the internal electric field. These would weaken the N2 triple bond and reduce the activation energy barrier for the conversion of N2 to NH3 under mild conditions. In the absence of sacrificial agents and cocatalysts, the optimized Bi2WO6 with oxygen defects shows an indigenous NH3 yield of 132.175 μmol·g-1·L-1·h-1, which is more than two times higher than that of the original Bi2WO6. Surprisingly, the Bi2WO6 with oxygen defects produced more than eight times NH3 (471.13 μmol·g-1·L-1·h-1) than that of the original Bi2WO6 when assisted by an external magnetic field, thus providing a new perspective for further enhancing the N2 fixation performance. 相似文献
3.
4.
中国是一个钢铁生产大国,也是一个油气资源相对不足、煤炭资源相对丰富的国家。基于中国能源结构的实际情况,结合钢铁行业和化工行业的发展现状,讨论了钢铁生产各个工序煤气的发生与使用情况,并对钢铁流程副产煤气合成化工产品的现状与潜力进行了分析,指出了存在的问题。结合分析结果,提出了未来可再生能源廉价制氢发展达到一定阶段,钢铁联合企业可以通过“以氢固碳”实现钢铁生产大规模减少CO2排放的目标,提升其清洁能源转化与高附加值化工产品生产的社会功能。最后,对未来中国钢化联产的发展提出了建议。 相似文献
5.
《International Journal of Hydrogen Energy》2021,46(67):33409-33419
Developing efficient catalysis for dinitrogen (N2) fixation is a very important and challenging issue in chemistry. Herein, by means of density functional theory (DFT) computations, we reported that the potential of single-atom Rhenium (Re) supported on the graphyne (Re-GY) for activating N2 and reducing it into ammonia (NH3). It is found that the adsorption energies of N2 on Re-GY for end-on/side-on configuration are −1.05/-0.56 eV, together with the N–N bond length are stretched to 1.14/1.21 Å, respectively. The hydrazine intermediate is difficult to release with adsorption energies of −1.71/1.49 eV on Re-GY for different pathways, which ensures it is sequentially hydrogenated and eventually form NH3. All the mechanisms considered are energetically favorable and the most favorable pathway is the mixed mechanism. It is worth noting that there are relatively rare researches on Re-based catalysts for N2 fixation, our findings provide a new option for the design and synthesis of catalysts for N2 reduction reaction. 相似文献
6.
7.
生物质能源是一种环境友好的可再生能源,但也存在能量密度低、含水率高、碱金属含量高等缺点,导致其在热利用的过程中存在易结渣、堵灰及腐蚀、热效率不高等问题。本文结合生物质气化、炉内碱金属/硫固定、两级焦油裂解、蓄热式燃烧,以及冷凝热回收等多项先进技术,设计并搭建了连续蓄热式生物质气化/燃烧供热系统。以海洋贝壳类废弃物作为生物质成型燃料的添加剂和生物质焦油裂解过程的催化剂,在实现海洋废弃资源高值化利用的同时,克服了生物质热利用过程中的多项障碍,能够显著提高生物质能热利用效率,同时大幅度降低当前工业及民用供热过程中CO2、SOx、NOx及烟尘的排放,具有良好的经济性与环保性。 相似文献
8.
A salience computation approach based on perceptual distinctness is proposed in this paper that predicts human eye fixation locations in images. The approach uses a novel representation of pattern in a patch around a pixel such that discrimination between patterns is in compliance with distinctness between them in-terms of a few well-known perceptual cues. Image patches of different sizes (resolutions) are considered. The representations of the value at and pattern around a pixel in different features such as lightness, color and orientation are discriminated from all those in the rest of the image to compute salience at that pixel. The effectiveness of the proposed salience computation approach in generating salience maps closer to human eye fixation density maps is demonstrated by comparing it both qualitatively and quantitatively to other existing state-of-the-art salience computation approaches. Several synthetic images and psychological patterns, and real-life images from five well-known datasets are considered for this purpose. 相似文献
9.
10.
Di Suo Zhen Fang Yang-Yang Yu Yang-Chun Yong 《American Institute of Chemical Engineers》2020,66(4):e16897
Microbial electrocatalysis systems (MES) provide a cutting-edge solution to global problems associated with the environment and energy, but practical applications are hindered by the expensive electrode materials. Although stainless steel (SS) has been proposed as a promising inexpensive candidate, poor cell/SS interaction results in a low performance for MES. Here, a new synthetic biology approach was established for reinforcing the cell/SS interaction. Hybridized curli nanofibers fused with a metal-binding domain were heterogeneously expressed onto the cell surface, which realized efficient cell binding with the SS electrode. Consequently, it enabled a ~420-fold improvement of the anodic power output and a substantial enhancement of the cathodic Coulombic efficiency (from 0.6 to 4% to over 80%) with an SS electrode. This work demonstrates low-cost MES with an SS electrode and introduces a new avenue to engineer the cell/electrode interaction, which is promising for future practical applications of MES. 相似文献