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1.
采用γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)对聚乙烯醇(PVA1799)进行接枝改性,制备了交联型聚乙烯醇表面施胶剂(PVA-KH560);通过傅里叶变换红外光谱、氢核磁共振谱及稳定性测试等对PVA-KH560结构及稳定性进行分析,并对PVA-KH560与PVA1799复配施胶前后纸张的物理性能进行了分析。结果表明,KH560中的环氧基团在PVA-KH560中消失,含硅支链成功接枝到PVA1799长链中;当m(PVA1799)∶m(KH560)=9∶1.5时,PVA-KH560稳定且粒径最小(122.2 nm),分散性指数为0.291;和原纸相比,复配施胶纸张耐折度、抗张指数、挺度、撕裂指数、耐破指数分别提高了436.0%、60.1%、116.4%、89.9%、80.5%,接触角增大了57.7%,综合性能优于单独使用PVA1799的施胶纸。 相似文献
2.
Joanna Skrzyde Dorota Borowska-Wykrt Dorota Kwiatkowska 《International journal of molecular sciences》2021,22(8)
This review is devoted to the structure, assembly and function of cuticle. The topics are discussed from the mechanical perspective and whenever the data are available a special attention is paid to the cuticle of perianth organs, i.e., sepals, petals or tepals. The cuticle covering these organs is special in both its structure and function and some of these peculiarities are related to the cuticle mechanics. In particular, strengthening of the perianth surface is often provided by a folded cuticle that functionally resembles profiled plates, while on the surface of the petal epidermis of some plants, the cuticle is the only integral continuous layer. The perianth cuticle is distinguished also by those aspects of its mechanics and development that need further studies. In particular, more investigations are needed to explain the formation and maintenance of cuticle folding, which is typical for the perianth epidermis, and also to elucidate the mechanical properties and behavior of the perianth cuticle in situ. Gaps in our knowledge are partly due to technical problems caused by very small thicknesses of the perianth cuticle but modern tools may help to overcome these obstacles. 相似文献
3.
Birgit Köhn Prof. Dr. Michael Kovermann 《Chembiochem : a European journal of chemical biology》2019,20(6):759-763
In all intracellular processes, protein structure and dynamics are subject to the influence of macromolecular crowding (MC). Here, the impact of MC agents of different types and sizes on the model protein Bacillus subtilis Cold shock protein B (BsCspB) during both thermal and chemical denaturation have been comprehensively investigated. We consistently reveal a distinct stabilization of BsCspB in a manner dependent on the MC concentration but not on viscosity, polarity, or size of the MC agent used. This general stabilization has been decoded by use of NMR spectroscopy, through monitoring of chemical shift (CS) perturbations and the intramolecular hydrogen-bonding networks, as well as local protection of amide protons against exchange with solvent protons. Whereas CSs and hydrogen-bonding networks are not systematically affected in the presence of MC, we detected a pronounced reduction in exchange in loop regions of BsCspB. We conclude that this reduced accessibility of solvent protons is a key parameter for the increases in protein stability seen under MC. 相似文献
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以N-乙烯基吡咯烷酮(VP)、丙烯酸丁酯(BA)、甲基丙烯酸-2-羧乙酯(CA)为单体,通过溶液聚合,制得高分子表面活性剂P(VP-co-BA-co-CA)。以P(VP-co-BA-co-CA)乳化分散1,6-己二异氰酸酯(HDI)三聚体,制得水可分散型HDI三聚体(WD-HDIT),考察了BA质量分数、CA质量分数和HDI三聚体质量分数对乳液粒径和施胶性能的影响。探讨了WD-HDIT乳液对纸张表面的施胶性能。结果表明,当w(VP)=5.0%,w(BA)=3.4%,w(CA)=1.3%,w(HDI三聚体)=60.0%时,施胶剂乳液WD-HDIT具有良好的稳定性和优异的施胶特性。以WD-HDIT质量分数为10%的施胶剂乳液进行表面施胶,纸张施胶度达29 s,纸张与水接触角达119.49°,耐折度达67次,抗张指数达55.8 N?m/g,抗弯挺度指数为2.003 N·m7/kg3,环压强度指数为5.1468 N·m/g。 相似文献
6.
Chemical Synthesis of A Pore‐Forming Antimicrobial Protein,Caenopore‐5, by Using Native Chemical Ligation at a Glu‐Cys Site 下载免费PDF全文
Karima Medini Dr. Paul W. R. Harris Kiel Hards Dr. Andrew J. Dingley Gregory M. Cook Prof. Margaret A. Brimble 《Chembiochem : a European journal of chemical biology》2015,16(2):328-336
The 2014 report from the World Health Organization (WHO) on antimicrobial resistance revealed an alarming rise in antibiotic resistance all around the world. Unlike classical antibiotics, with the exception of a few species, no acquired resistance towards antimicrobial peptides (AMPs) has been reported. Therefore, AMPs represent leads for the development of novel antibiotics. Caenopore‐5 is constitutively expressed in the intestine of the nematode Caenorhabditis elegans and is a pore‐forming AMP. The protein (82 amino acids) was successfully synthesised by using Boc solid‐phase peptide synthesis and native chemical ligation. No γ‐linked by‐product was observed despite the use of a C‐terminal Glu‐thioester. The folding of the synthetic protein was confirmed by 1H NMR spectroscopy and circular dichroism and compared with data recorded for recombinant caenopore‐5. The permeabilisation activities of the protein and of shortened analogues were evaluated. 相似文献
7.
Applying γ‐Substituted Prolines in the Foldon Peptide: Polarity Contradicts Preorganization 下载免费PDF全文
Dennis Dietz Dr. Vladimir Kubyshkin Prof. Dr. Nediljko Budisa 《Chembiochem : a European journal of chemical biology》2015,16(3):403-406
Rational choice of chemical modifications to proline residues allows the preorganization principle to be exploited for more stable assembly of the foldon domain as a tag for trimerization. With systematic knowledge of how chemical and steric variations of the ring substituents affect the relative stabilities of exo and endo puckers, the preorganization principle should then be usable in biotechnologically synthesized foldon mutants and applicable for protein tagging elsewhere. 相似文献
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云端融合计算(Cloud-P2P)融合了云计算与对等计算环境的所有节点资源,实现了最大范围的协作与资源共享。数据销毁机制是保障用户数据的安全性和可控性的重要措施之一,然而云端计算环境本身的特性也给数据的有效销毁带来了困难。针对云端数据存储系统对数据的主动销毁、定时销毁和自销毁等复合需求,提出一种基于移动Agent的数据复合销毁机制,该方法不依赖第三方,利用移动Agent技术实现对过期、废弃型数据及时、有效、灵活的销毁,并在恶意主体对数据实施攻击时主动实施防御性数据销毁,有效增强了用户数据的安全性。针对节点上数据的具体销毁,还提出一种新颖的“数据折叠”的数据覆写方法,它充分利用数据本身进行销毁,有效降低了系统的开销。 相似文献
10.
服务因其灵活的应用机制,逐渐成为软件开发过程中的主要载体.面对网络中涌现出的大量功能相同或相似而QoS(quality of service)不同的服务群体,如何快速、准确地定位到所需要的服务个体,仍是一项十分具有挑战性的工作.基于服务对功能的封装特性,提出一种基于服务功能规约的服务选择方法,将功能相关的抽象服务规约为一个粒度更大的服务级的抽象服务;然后,针对规约后的大粒度抽象服务完成服务发现和组合优化的过程.由于规约操作能够有效减少参与服务组合优化的抽象服务的个数以及相应的候选服务的个数,从而使算法的执行效率得到有效提升.实验结果表明:该算法与传统的启发式算法相比执行效率更高,并且对服务组合规模及候选服务规模表现出更好的扩展性. 相似文献