铅基卤素钙钛矿阻变式存储器研究进展

随着数字通信在大数据以及物联网等领域的应用,推动了下一代存储设备的发展。阻变式存储器因其功耗低、尺寸可调、操作速度快等优点被认为是最有前景的信息存储器件之一。近年来,兼具成本低、带隙可调、载流子扩散长度长、离子迁移速率快、载流子迁移率高等优点的铅基卤素钙钛矿,在阻变式存储器领域引起了广泛关注。主要对铅基卤素钙钛矿阻变式存储器最新研究进展进行了概述,就铅基卤素钙钛矿阻变式存储器结构、阻变性能、阻变机理等方面进行了综述。最后,对铅基卤素钙钛矿阻变式存储器当前面临的挑战进行了讨论,并对其未来的发展前景进行了展望。     

IRS辅助的SWIPT系统中基于能效优先的波束成形设计与优化

以智能反射面(intelligent reflecting surface,IRS)辅助的无线携能通信(simultaneous wireless information and power transfer,SWIPT)系统为背景,研究了该系统中基于能效优先的多天线发送端有源波束成形与IRS无源波束成形联合设计与优化方法。以最大化接收端的最小能效为优化目标,构造在发送端功率、接收端能量阈值、IRS相移等多约束下的非线性优化问题,用交替方向乘子法(alternating direction method of multipliers,ADMM)求解。采用Dinkelbach算法转化目标函数,通过奇异值分解(singular value decomposition,SVD)和半定松弛(semi-definite relaxation,SDR)得到发送端有源波束成形向量。采用SDR得到IRS相移矩阵与反射波束成形向量。结果表明,该系统显著降低了系统能量收集(energy harvesting,EH)接收端的能量阈值。当系统总电路功耗为?15 dBm时,所提方案的用户能效为300 KB/J。当IRS反射阵源数与发送天线数均为最大值时,系统可达最大能效。     

An Injectable Hydrogel for Simultaneous Photothermal Therapy and Photodynamic Therapy with Ultrahigh Efficiency Based on Carbon Dots and Modified Cellulose Nanocrystals

The convenience of injectable hydrogels that can provide high loading of diverse phototherapy agents and further long-time retention at the tumor site has attracted tremendous interest in simultaneous photothermal and photodynamic cancer therapies. However, to incorporate the phototherapy agents into hydrogels, complex modifications are generally unavoidable. Moreover, these phototherapy agents usually suffer from low efficiency and work at different irradiation wavelengths outside the near infrared windows. Hence, a method for the fabrication of an injectable hydrogel for simultaneous photothermal therapy and photodynamic therapy, through the Schiff-base reaction between amido modified carbon dots (NCDs) and aldehyde modified cellulose nanocrystals is proposed. The NCDs act as both phototherapy agents and crosslinkers to form hydrogels. Significantly, the NCDs demonstrate an extremely high photothermal conversion efficiency of 77.6% which is among the highest levels for photothermal agents and a high singlet quantum yield of 0.37 under a single 660 nm light-emitting diode irradiation. The hydrogels are examined through in vitro and in vivo animal experiments which show nontoxic and effectively tumor inhibition. Thus, the strategy of direct reaction of phototherapy agents and the matrix not only provides new strategies for injectable hydrogel fabrication but paves a new road for advanced tumor treatment.     

KCl/NaCl/CPI复合盐阳离子聚合物钻井液在南海大斜度井段中的应用

为改善南海东部惠州25-8油田大斜度井因泥岩水化造浆而引起的井壁失稳和钻井液增稠影响携砂的问题,在现有成熟PLUS/KCl钻井液的基础上开展复合盐阳离子聚合物钻井液研究,对钻井液配方进行了优化,评价了优化后钻井液的流变性、抑制性、封堵性和润滑性,并在惠州油田进行了现场应用。结果表明,复合盐阳离子聚合物钻井液配方中,无机盐类抑制剂KCl和NaCl的适宜加量为3%和12%、有机阳离子聚合物抑制剂PF-CPI适宜的加量为2.0%。该钻井液抑制性强,防膨率高达93.32%,钻屑回收率87.56%;受到钻屑侵污后的钻井液流变性能波动小,仍具有较低的黏度和合适的切力,有利于大斜度井携砂;封堵性和润滑性均优于PLUS/KCl钻井液体系。现场应用2口井,钻井液流变性良好,平均起下钻速度提高,钻井过程顺利,无复杂情况发生。复合盐阳离子聚合物钻井液可改善南海大斜度井起下钻阻卡的问题。     

A comparative study on pyrolysis reactivity and gas release characteristics of biomass and coal using TG-MS analysis

Pyrolysis reactivity and gas release characteristics of biomass and coals were comparatively investigated using TG-MS. In addition, chemical compositions and structures of tested samples were determined to correlate pyrolysis gas release characteristic. It was found that pyrolysis reactivity and gaseous product release were hardly varied with pyrolysis heating rate. Furthermore, pyrolysis rates of two biomass samples were greater than those of coals, which were mainly attributed to the chemical compositions and the gaseous product evolution process. The result also showed that gaseous product release during pyrolysis process was related to the presence of different functional groups in samples.     

论携号转网行为的私法规制

以电信用户入网协议为切入点,电信用户的携号转网行为应受到《合同法》《消费者权益保护法》等私法规范的保护与限制。该行为引起的格式条款解释、合同终止、违约责任、损失赔偿等问题,不能仅靠《电信条例》等公法规范来调整。应当积极引导广大消费者用户以私法领域相关规定为依据,转变争议解决思维,拓宽纠纷处理途径,合理选择维权手段,以保护自身合法民事权益,与行业监管部门共同推动电信行业有序发展。     

密文策略属性加密中的撤销控制方案

在云环境下使用数据共享功能时，由于云环境的复杂性，需要对数据进行安全保护和访问控制，这就要求使用加密机制。基于密文策略属性的加密（CP-ABE）是当前广泛使用的加密机制，它可以根据用户的属性来设置访问权限，任何具有合格访问权限的用户都可以访问数据。然而云是一个动态环境，有时可能只允许具有访问权限用户中的一部分用户访问数据，这就需要用户权限的撤销机制。然而，在CP-ABE中，访问权撤销或用户撤销是一个冗长且代价高昂的事件。所提出方案根据对CP-ABE流程的改进，在原密文中嵌入了可灵活控制的用户个人秘密，使得用户权限撤销时既不要求使用新访问策略的用户撤销数据，也不要求对数据进行重新加密，大幅减少撤销时的计算成本。与知名CP-ABE撤销方案对比，所提出方案的计算成本更低且具有良好的安全性。     

基于LBT-SA的LoRaWAN信道接入方法研究

标准LoRaWAN协议中定义的纯ALOHA信道接入方法在网络负载较大时会造成大量碰撞，使LoRa网络的可扩展性和可靠性受到极大挑战。为此提出了一种将先听后说与模拟退火相结合（Listen Before Talk combined with Simulated Annealing，LBT-SA）的LoRa信道接入方法。该方法通过在设备发送之前先监听信道，降低信道被同时接入的概率，并以成功传输所需退避时间为初始值，搜索更小的退避时间。仿真结果表明，LBT-SA和基于二元指数退避算法的先听后说（Listen Before Talk，LBT）方法在包成功传输率方面保持了高度的一致，并且LBT-SA在周期传输过程中逐渐减少了不必要的退避时间，从而减少了时延。在多达10 000个终端接入单个网关的场景中，该算法的平均退避时间至少降低了16.38%。     

来流马赫数影响高负荷扇形扩压叶栅气动性能的研究

为研究亚音速高负荷扇形扩压叶栅NACA0065-K48的变工况性能,采用数值方法研究了来流马赫数对叶栅气动性能和流场结构的影响,来流马赫数的取值范围为0.3～0.8。计算结果表明:随着来流马赫数的增大,叶栅静压比不断提高,但总压损失先减后增,马赫数在0.5～0.7范围内叶栅具有较好的综合气动性能。扇形叶栅下角区分离程度大于上角区的不平衡流动现象会随着马赫数的增大而加剧,通道涡则是这一发展趋势的主导,且马赫数达到0.7之后,下角区通道涡与集中脱落涡趋于融合。此外,下端壁分离螺旋点的形成与发展是控制下角区分离程度和损失大小的关键。     

Study and comparison of the unique selling propositions (USPs) of free-to-use multinational patent search systems

The article analyses and compares some free-to-use patent search services which are not managed by patent authorities but which may offer unique selling propositions (USPs) beyond the expected, standard, search functions. Those services selected for this study are Google Patents, Lens, Patent Inspiration, Free Patents Online, SureChEMBL and Octimine. For this comparative study a total set of 66 criteria were analysed for each of the six search services. Furthermore the USPs and perceived advantages and disadvantages were identified. The study concluded that some of these search services are better suited for general prior art searches or patent analysis while others are applicable for patent searches in specific fields like biotechnology or pharmaceuticals.