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1.
The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v(C?C) = 2108–2128 cm?1 and v(C?C) = 1505–1532 cm?1 were calculated after extrapolation. Similarly sp-C13C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.  相似文献   
2.
In shape memory materials,that have been trained to have a two way shape memory effect(TWSM),themartensitic variants are classified into two groups,i.e.,preferentially oriented variants and self-accommodatingvariants.Applied stress may promote or constrain the transition of preferentially oriented variants and so changetransformation temperatures but has no essential effect on self-accommodating variants.According to the pointof view mentioned above,some experimental phenomena during thermocycling of a TWSM device may be ex-plained,such as the absence of synchronization between the plot of resistance change.temperature and the plotof memory strain vs.temperature.  相似文献   
3.
Robert Rodošek 《Constraints》2001,6(2-3):257-269
This paper presents an hybrid algorithm for deriving 3-D structures of cyclic polypeptides. The algorithm combines constraint-based techniques with the most widely used methods for non-cyclic polypeptides. The empirical results demonstrate that the proposed hybrid algorithm outperforms traditional methods especially with respect to running times.  相似文献   
4.
We consider discrete event systems (DES) involving tasks with real-time constraints and seek to control processing times so as to minimize a cost function subject to each task meeting its own constraint. When tasks are processed over a single stage, it has been shown that there are structural properties of the optimal sample path that lead to very efficient solutions of such problems. When tasks are processed over multiple stages and are subject to end-to-end real-time constraints, these properties no longer hold and no obvious extensions are known. We consider a two-stage problem with homogeneous cost functions over all tasks at each stage and derive several new optimality properties. These properties lead to the idea of introducing “virtual” deadlines at the first stage, thus partially decoupling the stages so that the known efficient solutions for single-stage problems can be used. We prove that the solution obtained by an iterative virtual deadline algorithm (VDA) converges to the global optimal solution of the two-stage problem and illustrate the efficiency of the VDA through numerical examples.
Christos G. CassandrasEmail:
  相似文献   
5.
The calculations of the elastic scattering properties of ultra-cold francium isotopes are reported in detail. A parametric model potential for the triplet molecular states of the Fr2 is represented, and the scattering lengths at and the effective range re are calculated using WKB and Numerov methods for Fr--Fr in the triplet state. The convergence of these scattering properties depending on a K0 parameter and core radius is also investigated using two methods: Quantum Defect Theory and analytical formula of Symskoviski.  相似文献   
6.
A semicircle control chart can be used in detecting both increases and decreases in the mean and/or variance. In this paper, we propose two modified semicircle charts for detecting a reduction in the process variance, a.k.a. process improvement. Each of these modified semicircle charts, namely, SC1 and SC2 has two limits, defined by the inner and outer semicircles. A process improvement is detected by the SC1 scheme if a point is plotted inside the smallest semicircle, or if two successive points are plotted between the inner and outer semicircles and by the SC2 scheme if a point plots inside the smallest semicircle or if two of three successive points plot between the inner and outer semicircles. It will be shown that the two modified semicircle charts have superior average run length (ARL) performances to the basic semicircle chart in the detection of process improvement. The ARL study is conducted by means of a simulation.  相似文献   
7.
This paper introduces a high precision 7m laser measuring instrument developedby the anthors and its operating principle,and systematically analyses the errors havinginfluence on the performance of the measuring instrument.Error analysis and actualverification indicate that all the characteristics reached or exceeded the original designspecifications.  相似文献   
8.
用有限元法计算了有一个紧固件孔的半无限平板在紧固件力作用下的孔周应力.在紧固件与孔之间的接触区域的结点间加无长刚杆元.用反复计算的方法确定接触范围;计算出孔周应力等,并与文献[1]的实验结果进行了比较.  相似文献   
9.
基于Jack的虚拟环境中一种防止穿越的实现   总被引:1,自引:0,他引:1  
在虚拟环境下虚拟人手和虚拟物体的交互中,会发生穿越现象。为了解决穿越问题,在人体模型系统Jack的虚拟环境中,根据约束Constraint对象的特点,利用Constraint对象来模拟物体对人手阻挡作用,并利用约束队列实现了对场景中Constraint对象的管理,达到防穿越的效果。  相似文献   
10.
In this paper, we identify two cases in which the proposition for calculating time window penalties presented in Nagata, Y., Bräysy, O. and Dullaert, W. A penalty-based edge assembly memetic algorithm for the vehicle routing problem with time windows, Computers & Operations Research 2010;37(4): 724–37 yields incorrect results. We derive the corrected proposition and use numerical studies to show that a significant proportion of the evaluations performed by a Tabu Search for VRPTW falls under the two incorrect cases. Moreover, we demonstrate that the incorrect time window handling has a significant negative impact on the solution quality of the Tabu Search.  相似文献   
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