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1.
《International Journal of Hydrogen Energy》2022,47(6):3550-3555
Electrocatalytic nitrogen reduction reaction (ENRR) offers a carbon-neutral process to fix nitrogen into ammonia, but its feasibility depends on the development of highly efficient electrocatalysts. Herein, we report that Fe ion grafted on MoO3 nanorods synthesized by an impregnation technique can efficiently enhance the electron harvesting ability and the selectivity of H+ during the NRR process in neutral electrolyte. In 0.1 M Na2SO4 solution, the electrocatalyst exhibited a remarkable NRR activity with an NH3 yield of 9.66 μg h?1 mg?1cat and a Faradaic efficiency (FE) of 13.1%, far outperforming the ungrafted MnO3. Density functional theory calculations revealed that the Fe sites are major activation centers along the alternating pathway. 相似文献
2.
尕斯库勒油田E13油藏已经进入高含水时期,储采失衡加剧,综合含水率达到了80%以上,原油产量下降,经济效益变差。为了提高油藏原油采出程度、改善油藏开发效果,调研了国内外减氧空气驱的机理研究以及现场试验的资料,建立了以油藏真实孔渗饱数据为基础的一维条形地层机理模型,并选取该油藏Y12-27井组进行了减氧空气驱可行性验证。研究表明:纵向顶部减氧空气驱驱油效果优于水驱和氮气驱;驱替压力对原油采出程度影响不大;注水转注气可以提高原油采出程度;对于减氧空气驱,由于低温氧化反应的作用,氧气浓度对原油采出程度有一定影响,但比较微弱,其中,氧气浓度为10%时,驱替结束采出程度最高;尕斯库勒油田E13油藏属于注水开发“双高”油藏,适用于减氧空气驱;对于该油藏Y12-27井组,顶部减氧空气驱驱油效果好于水驱和氮气驱,建议氧气浓度超过10%时采取关井等措施。 相似文献
3.
Yuanyuan Zhang Haiyan Lu Bing Wang Zhuo Zhang Xiaorong Lin Zhongzheng Chen Bin Li 《International Journal of Food Science & Technology》2015,50(6):1397-1404
Removal of imidacloprid and acetamiprid in tea infusions by microfiltration membrane using dead‐end model was investigated in the present study. The results showed that microfiltration significantly promoted the removal of both pesticides (P < 0.05) in tea infusions. Furthermore, the extent of removal was strongly influenced by the pore size of membrane, operational pressure and the concentrations of tea infusions. The initial concentration of imidacloprid and acetamiprid showed no significant effect on their removal rates. The maximum removal rates were 79.7% for imidacloprid and 81.9% acetamiprid. The changes in major chemical components of tea infusions after microfiltration were evaluated. The results indicated that microfiltration caused no considerable changes in total polyphenols and total free amino acids, and small but statistically significant losses (6.3–18.0%) of eight catechins and three methylxanthines when filtration volume reached to 200 mL. The present study validated the application of microfiltration as a potentially feasible and promising method for the removal of imidacloprid and acetamiprid residues from tea infusions. 相似文献
4.
Chitosan (CHT) is a non-toxic and inexpensive compound obtained by deacetylation of chitin, the main component of the exoskeleton of arthropods as well as of the cell walls of many fungi. In agriculture CHT is used to control numerous diseases on various horticultural commodities but, although different mechanisms have been proposed, the exact mode of action of CHT is still unknown. In sycamore (Acer pseudoplatanus L.) cultured cells, CHT induces a set of defense/stress responses that includes production of H2O2 and nitric oxide (NO). We investigated the possible signaling role of these reactive molecules in some CHT-induced responses by means of inhibitors of production and/or scavengers. The results show that both reactive nitrogen and oxygen species are not only a mere symptom of stress conditions but are involved in the responses induced by CHT in sycamore cells. In particular, NO appears to be involved in a cell death form induced by CHT that shows apoptotic features like DNA fragmentation, increase in caspase-3-like activity and release of cytochrome c from the mitochondrion. On the contrary, reactive oxygen species (ROS) appear involved in a cell death form induced by CHT that does not show these apoptotic features but presents increase in lipid peroxidation. 相似文献
5.
不同含量低污染水对人工湿地中细菌的影响研究 总被引:1,自引:0,他引:1
探究水平流人工湿地(HFCW)系统处理低污染水过程中,相同COD/ρ(TN)下不同碳氮含量对细菌群落结构的影响。结果表明,进水为较高碳氮含量的HFCW(HF1)和进水为较低碳氮含量的HFCW(HF2)对COD和TN的去除效率具有一定的差异,HF1和HF2对COD的去除效率分别为48.26%和28.89%,对TN的去除率分别为79.06%和81.87%。HF1中细菌的丰富度和多样性均高于HF2,HF1中富集的优势细菌为Chloroflexaceae、Comamonadaceae和Rhodocyclaceae,均具有异养反硝化功能,HF2中富集的优势细菌为Xanthomonadaceae和Rhodocyclaceae,其中Xanthomonadaceae具有自养反硝化功能。COD、NH4^+-N和NO3^--N对HF1中细菌群落的影响大于对HF2中细菌群落的影响,HF1中COD对细菌群落的影响大于NH4^+-N和NO3^--N。 相似文献
6.
7.
采用“溶胀-嵌入-收缩”方法改性聚酰胺反渗透膜,制备了一种高脱硼反渗透膜。通过甲醇溶胀增加了高分子链之间的距离,为疏水性癸酸分子的嵌入提供了场所,然后在压力和浓差极化共同作用下,改性分子选择性嵌入聚酰胺膜的孔内;当甲醇分子离开后,聚酰胺膜收缩将癸酸分子固定在高分子网络中。实验借助溶胀和分子嵌入以及溶胀后的收缩调节聚酰胺膜的孔径大小;利用脂肪酸的疏水性降低聚酰胺膜的极性,从而实现增加空间位阻和减少氢键结合位点数量的目的。实验结果显示,改性膜的脱硼率和截盐率均明显升高,截盐率从90.36%增加到96.46%,脱硼率从未改性膜的47.85%增加到77.32%,渗透液的硼含量达到WTO的使用标准。虽然水和硼的渗透性均下降,但是水和硼的渗透选择性增加,证明该方法有利于提高水硼选择性。 相似文献
8.
新汶矿业集团经过探索和实践,研究运用了差异互补式全掩护支护技术、掩护支架自牵引联动装置工艺、矿车运输、滑移运输多用轨道、自动找正装车平台、液控调整装置等新技术、新工艺,做到了液压支架综合流程快速回撤,实现了高效化、连贯化安全回撤,取得了良好的经济效益。 相似文献
9.
Syafikah Huda Paiman Mukhlis A Rahman Khairul Hamimah Abas Azian Abd Aziz Ahmad Fauzi Ismail Mohd Hafiz Dzarfan Othman Juhana Jaafar Mohammad Noorul Anam Mohd Norddin 《化学工程与技术》2019,42(6):1321-1329
Removal by absorptive ceramic membranes can simultaneously absorb and separate metal ions from water. Alumina/yttria‐stabilized zirconia (Al2O3/YSZ) hollow‐fiber membranes, fabricated using phase inversion and sintering process, were deposited with iron oxide by an in‐situ hydrothermal process. The results showed that α‐Fe2O3 was produced and incorporated across the membranes. A reduction in flux was recorded with the deposition of α‐Fe2O3. However, it improved the adsorption capacity for heavy metal adsorption. The adsorption‐separation test demonstrated that the optimized membrane is able to completely remove Pb(II) ions after two hours. 相似文献
10.
The fourth-order partial differential equations have good performance on noise smoothing and edge preservation without creating blocky effects on smooth regions. However, for low signal-to-noise ratio images, the discrimination between edges and noise is a challenging problem. A novel kernel-based fourth-order diffusion is proposed in this paper. It introduces a kernelized gradient operator in the fourth-order diffusion process, which leads to more effective noise removal capability. Experiment results show that this method outperforms several previous anisotropic diffusion methods for noise removal and edge preservation. 相似文献