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1.
Acid–base transport is integral to many important interfacial reactions in various fields of chemistry, but its theoretical foundation is lacked. Herein, a common acid–base transport model is established owing to the success in deriving buffer transport equations. This model is applicable to most buffer systems by flexibly integrating the transport equations in terms of buffer components, and is verified through the model relationships of buffer transport limiting current by using hydrogen evolution reaction experiments. Based on model calculations, two diagram approaches are proposed to depict the dynamic pH response and aid buffer operation optimizations. The model and methods allow us to quantify the rate-limiting effect of acid–base transport on interfacial reactions and to precisely control the effect through medium regulations. Furthermore, the model has laid the foundation of dynamic pH effect on species transformation and process mechanism, which can be of wide interest in the chemistry encompassing interfacial reactions.  相似文献   
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魏菊霞 《矿冶》2018,27(4):100-104
在流程工业生产中,移动物料计量信息的传输普遍采用电台和无线模块。接收电台周围环境严重影响计量信息的传输效果,尤其是钢结构厂房、电磁干扰区内,数据传输过程中的丢包率、误码率相当严重。本文提出一种多节点分布式传输方法,根据各个生产作业区环境条件设置相应的WIFI节点数,实现对作业区的无线信号覆盖。网络覆盖区内无线模块、PDA终端(PDA)、终端查询设备通过节点工作频段和阵列天线自适应调节,实现数据传输最佳化。铜熔炼生产现场测试表明,此种传输方法可以有效消除周围环境的电磁干扰,数据丢包率低于0.1%。  相似文献   
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Crowd movement simulation models are generally based on aggregated speed and flow data collected more than 50 years ago. There appears to be no validated modelling capability to include the impact of recent and future changes in population demographics, resulting from an ageing population and increasing obesity rates. New analytical approaches and data gathering are required to successfully model crowd movement and safety for current and future generations. This study carried out (a) a review of the primary components of crowd movement, demographics and analytical techniques, (b) prototype experiments to investigate age-related aspects of space and potential points of contact and (c) a new predictive model for crowd flow analysis based on pedestrian biomechanics and anthropometric data. The model uses the physical space taken up by the biomechanical walking process and the spatial buffer between points of potential contact with other pedestrians to predict the speed of movement at different levels of congestion. The new analytical model was used to predict single file speeds (for people with different demographics in congested space), which compared well with published experimental data. The next steps for model development for wider “flows” and additional experiments to provide data sets for wider demographics are also proposed.  相似文献   
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ABSTRACT

In recent years, Wireless Sensor Networks (WSNs) are widely placed in real-time monitoring systems like environmental, structural, patient monitoring, etc. The major criterion for WSN includes energy efficiency and network lifetime. Scheduling is used as a large number of data packets focus on the same queue at the same time. Only limited data scheduling schemes have been implemented in WSN to enhance the performance. The existing First Come First Serve (FCFS) and Dynamic Multilevel Priority (DMP) have some technical challenges like delay, packet drop and high energy consumption due to starvation and deadlock. In this paper, we proposed a new algorithm to optimise and rank the incoming data packets based on multi-attributes decision-making methodology named as Packet Rank Based Data Scheduling (PRBDS), the algorithm selects packet priority, deadline, and size as the metrics to rank the incoming data packets. A simulation result shows when compared with existing scheduling, PRBDS not only provides less energy consumption, also significantly reduces the packet drop and increases the lifetime. Thus, the proposed algorithm is most suitable for real-time monitoring system since it combines data ranking method with scheduling algorithm to create accurate and reliable results to evaluate the incoming data packets.  相似文献   
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This article studies the optimal filtering and control for wireless networked control systems (WNCSs). In WNCSs, packets may be lost in both control and feedback channels and user datagram protocol is usually used to improve the performance of the real-time control. Relevant literature indicates that the conventional optimal filtering for such a system cannot be applied in practice due to the complex calculation with Gaussian mixtures. This paper proposes a novel scheme to realize the optimal filtering and the linear quadratic Gaussian control for WNCSs, in which the controlled node performs a local estimation and the remote-control node performs the final estimation and control, and a synchronization of two estimators is guaranteed by a communication mechanism. An optimal filtering algorithm is developed, the stability condition of the filtering error covariance is obtained, optimal finite-horizon and infinite-horizon control are derived, and the stability of the closed-loop control system is proved. Numerical simulations show the validity and feasibility of the theoretical results.  相似文献   
7.
为了减少工作面推采产生的矿压对沿空送巷的影响,采用预留采掘头面之间的安全缓冲区和合理避开矿压应力区,预留缓冲区交替式相向采掘工艺,实现矿井沿空送巷高效安全生产。  相似文献   
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研究同时存在双通道数据包丢失和时变时延的Delta算子网络控制系统(NCSs)故障检测问题.假定数据包丢失发生在控制器到执行器、传感器至控制器的数据传输过程中,并且利用两个相互独立的伯努利随机变量描述是否发生丢包.将上述的NCSs建模为网络切换系统,提出任意切换律下故障检测滤波器的设计方法.利用线性矩阵不等式(LMIs)方法、Lyapunov-Krasovskii泛函和平均驻留时间等得出所考虑的网络切换系统具备指数均方稳定性的充分条件.证明了所用的网络切换系统满足H性能,并推导出了滤波器参数的显式表达.数值仿真结果验证了所提方法的有效性.  相似文献   
9.
Journal of Computer Science and Technology - New non-volatile memory (NVM) technologies are expected to replace main memory DRAM (dynamic random access memory) in the near future. NAND flash...  相似文献   
10.
针对目前化纤纺丝生产中对喷丝板进行自动化铲板的需求,首先,提出一种自动铲板方法并设计了具有串并联弹簧缓冲对刀结构的铲板组件;然后,通过规划铲刀组件的对刀运动参数,建立组件的动力学模型,确定缓冲弹簧的刚度系数;同时对铲刀组件的对刀运动进行Adams仿真,验证运动参数设计和串并联弹簧缓冲对刀结构设计的正确性;最后,搭建了自动化铲板实验平台,开展对刀阶段的接触力测量实验。研究结果表明,实际对刀时的受力趋势与仿真结果一致,铲板组件可有效清洁喷丝板面,且随着铲刀接触力的增大铲板效果越明显,该研究为进一步开展自动化铲板系统的设计提供了技术参考。  相似文献   
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