Understanding silica-supported metal catalysts: Pd/silica as a case study

Supported metal catalysts, particularly noble metals supported on SiO₂, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO₂/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO₂ films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon.     

Innovation in construction: a sociology of technology approach

An alternative approach to understanding innovation is made using two intersecting ideas. The first is that successful innovation requires consideration of the social and organizational contexts in which it is located. The complex context of construction work is characterized by inter-organizational collaboration, a project-based approach and power distributed amongst collaborating organizations. The second is that innovations can be divided into two modes: 'bounded', where the implications of innovation are restricted within a single, coherent sphere of influence, and 'unbounded', where the effects of implementation spill over beyond this. Bounded innovations are adequately explained within the construction literature. However, less discussed are unbounded innovations, where many firms' collaboration is required for successful implementation, even though many innovations can be considered unbounded within construction's inter-organizational context. It is argued that unbounded innovations require an approach to understand and facilitate the interactions both within a range of actors and between the actors and technological artefacts. The insights from a sociology of technology approach can be applied to the multiplicity of negotiations and alignments that constitute the implementation of unbounded innovation. The utility of concepts from the sociology of technology, including 'system building' and 'heterogeneous engineering', is demonstrated by applying them to an empirical study of an unbounded innovation on a major construction project (the new terminal at Heathrow Airport, London, UK). This study suggests that 'system building' contains outcomes that are not only transformations of practices, processes and systems, but also the potential transformation of technologies themselves.     

Ultrasonic study of molecular association of poly(vinyl chloride) solution in tetrahydrofuran

Ultrasonic absorption, velocity, adiabatic compressibility, relaxation time and relaxation amplitude measurements are reported on poly(vinyl chloride) (PVC) solution in tetrahydrofuran (THF) using pulsed ultrasonic apparatus operating at 2 MHz and 313 K. Results show a linear increase of velocity. density, viscosity, absorption coefficient, relaxation time and relaxation amplitude values with the increase of PVC concentration in THF. In contrast the compressibility decreases with increasing PVC concentration. This suggests interaction between PVC and THF molecules.     

Guayule seedling response to nitrogen fertilizers

Slow growth and high seedling mortality limit direct seeding establishment of guayule (Parthenium argentatum G.). This study was conducted to assess seedling growth enhancement by the addition of different rates and forms of N fertilizers and Ca salts. Experiments were conducted in a greenhouse with cultivar 593 under both surface and subirrigated conditions using water low in salts (salinity of 0.8 dSm^–1, SAR of 5.0 and 10 mg Ca L^–1). Under surface-irrigated conditions, seedling height and fresh plant weight increased with N application to the irrigation water to 70 mg L^–1. The best seedling growth was observed when (NH₄)₂SO₄ was added in combination with CaCl₂ or CaSO₄. Progressively less growth was observed by addition of (NH₄)₂SO₄ alone, CO(NH₂)₂ plus CaSO₄, CO(NH₂)₂ alone and Ca(NO₃)₂. When seedlings were subirrigated, however, the best growth was observed with Ca(NO₃)₂. Intermediate growth was obtained with (NH₄)₂SO₄ plus CaSO₄ and lowest growth rates with (NH₄)₂SO₄ alone. These differential responses may be explained by the differences in leaching and volatile characteristics of the N forms. Growth enhancement from N and Ca additions increased with time with significant increases 45 days after seeding. Nitrogen application with Ca may be effective amendment in promoting subsequent growth of direct seeded guayule.     

Polymer/surfactant interaction—Its relevance to detergent systems

The field of polymer/surfactant interaction is reviewed in this work. Results from two investigative methods,viz., dialysis and surface tension, are discussed, illustrating the main behavioral patterns and outlining the principles of the interactions. Next, aspects of the interaction phenomena that appear to have relevance to detergent formulation are presented. These include solution rheology, solubility control and surface conditioning. Lastly, the importance of surface activity of the polymer itself is stressed, culminating in a discussion of the properties of hydrophobically modified water-soluble polymers (“polymeric surfactants”), both alone and in the presence of conventional surfactants. Based on the Samuel Rosen Memorial Award lecture, given at the AOCS Annual Meeting, Anaheim, CA, April 1993.     

A social interaction system based on cloud computing for mobile video telephony

As the use of smartphones become popular,people heavily depend on smartphone applications to deal with their social activities.For this reason,traditional message texting between mobile applications does not fulfill the versatile requirements of social networking.Many mobile applications use multimodality to deliver multimedia messages including sticker,voice and photo message,video call,and snap movie to enhance the communicative capability.However,without face-to-face interaction,people may fail to detect the other side’s non-verbal social behavior such as fine-grain facial expressions,body movements,or hand gesture.During social interaction,non-verbal behavior conveys information about the involved individuals and help the speakers express their social emotion in an implicit way.It is so important for real-world face-to-face interaction but is often blocked on the mobile telephony.To cope with this problem,we propose an afective computing model to assist the representation of social emotion and then help the progress of social interaction on the mobile telephony.In this model,for the purpose of real-time afective analysis,we delegate the computing loading to the cloud side service and enhance the system’s scalability and availability.The result of this experiment approves the feasibility of our system design for the applications of social intelligent.Also,the system provides a research framework of the social intelligent system on the mobile telephony.     

Influence of ions on the critical behavior of a binary mixture near the consolute point

The lower critical point of stratification of a 3-methylpyridine (MP)+heavy water (D₂O) mixture in the presence of Na⁺ and CI^– ions has been studied by the Toepler shadow method. Addition of 0.3% ions lowered the critical temperature and reduced the equilibration time and the gradient of the refractive index (compressibillity). The analysis of the form of the near-critical isotherm demonstrated the ionic mixture to be described by the index = 3.05 ± 0.15. which corresponds to the classical mean-field theory. The results obtained provide evidence that even small admixtures of charged particles result in a substantial suppression of fluctuations near the critical point by the long-range Coulomb interaction.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A.     

Vehicle Teleoperation Interfaces

Despite advances in autonomy, there will always be a need for human involvement in vehicle teleoperation. In particular, tasks such as exploration, reconnaissance and surveillance will continue to require human supervision, if not guidance and direct control. Thus, it is critical that the operator interface be as efficient and as capable as possible. In this paper, we provide an overview of vehicle teleoperation and present a summary of interfaces currently in use.     

Process control and risky decision-making: moderation by general mental ability and need for cognition

Human factors and ergonomics research could benefit from focusing more strongly on individual differences – especially trait variables. The present study suggests the analysis of moderator effects as a promising way to enhance understanding of trait variables and process control performance. Process control performance was studied by analysing moderator effects of general mental ability (GMA) and need for cognition (NC) on risky decision-making (RDM) and performance. Fifty engineering students were trained on a process control task using a computer-based simulation for three hours and tested twice thereafter. Risky decision-making was measured using a computerised gambling task while GMA and NC were assessed with questionnaires. Risky decision-making in interaction with each GMA and NC explained variance in performance over and above variance explained by the single effects. In conclusion, the analysis of moderator effects between individual difference variables and process control performance seems promising.

Practitioner Summary: Individual difference variables affect learning and performance, but have often not been studied to any great extent in human factors research. This article suggests a promising approach to studying individual differences – moderator analyses – and illustrates how such differences can lead to a better understanding of what determines process control performance.     

网络环境下的蓄电池智能监测系统设计

介绍了一种新型智能蓄电池监测系统的设计方案，并进一步研究了网络环境下蓄电池监控数据的加工处理，以实现蓄电池监测软计算模型的动态进化。