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排序方式: 共有4427条查询结果,搜索用时 15 毫秒
1.
Chenhui Ding Marion Breunig Jana Timm Roland Marschall Jürgen Senker Seema Agarwal 《Advanced functional materials》2021,31(49):2106507
Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m2 g−1), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future. 相似文献
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《Ceramics International》2022,48(17):24383-24392
We propose a novel approach for manufacturing dual-scale porosity alumina structures by UV curing-assisted 3D plotting of a specially formulated alumina feedstock using a thermo-regulated phase separable, photocurable camphene/triethylene glycol dimethacrylate (TEGDMA) vehicle. In particular, 3D plotting process was conducted at - 5 °C, and thus an alumina suspension prepared using liquid camphene/TEGDMA at room temperature could undergo phase separation, resulting in camphene crystals surrounded by walls comprised of liquid photopolymer enclosing alumina particles. To enhance the shape retention ability of extruded filaments, polystyrene (PS) polymer was used as the tackifier. The phase-separated feedrod could be extruded favorably through a nozzle and rapidly photopolymerized by UV light during the 3D plotting process. Three-dimensionally interconnected macropores were tightly constructed, which were separated by microporous alumina filaments, where micropores were created by the removal of camphene crystals via freeze-dying. The macroporosity of porous alumina ceramics was controlled by adjusting the distance between deposited filaments, while their microporosity was kept constant, leading to tightly tailored overall porosity and mechanical properties. 相似文献
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《Ceramics International》2021,47(19):26991-27001
Hydroxyapatite (HA) scaffolds were fabricated using the space holder method with a pressureless sintering process in a systematically developed manner at different fabrication stages to increase the strength of the scaffold at high porosity. Polyvinyl alcohol (PVA) and Polymethyl methacrylate (PMMA) were used as binders and space holder agents, respectively. The physical properties of the HA scaffolds were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), linear shrinkage test, and porosity measurements. The mechanical properties of the HA scaffolds were analyzed using compressive strength measurements. The results revealed that the HA scaffold met the expected quality requirements with a compressive strength of 2.2 MPa at a porosity of 65.6% with pore sizes distributed in the range of 126–385 μm. The shrinkage of the scaffold diameter occurred by 20.27%, this diameter shrinkage predominantly to the shrinkage of the HA scaffold caused by sintering. Besides, suspect that a higher PMMA concentration causes pore size shrinkage upon sintering. The formation of pore interconnections was evidenced by SEM observations and the ‘translucent light method’ developed in this study. The results of the scaffold phase test using XRD showed that the final scaffold consisted only of the HA phase, as the PVA and PMMA phases burned out during the sintering process. 相似文献
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准确的横波测井速度是影响地震叠前属性分析及反演质量的重要参数,在缺乏偶极横波测井情况下需要用Krief、Pride等数学模型预测横波,近年来临界孔隙度模型在计算骨架的弹性模量中应用效果较好。在前人研究的临界孔隙度模型的基础上,发展出了可变临界孔隙度的Nur模型,并将遗传算法应用于可变临界孔隙度的计算,最终估算得到了页岩气层的横波速度。实例应用表明,遗传算法可以计算得到沿井眼不同深度的临界孔隙度,而且预测得到的横波与偶极横波测井(DSI)一致性好,证明该方法应用于页岩气的横波估算中是可行的。 相似文献
7.
Vinod Kumar 《Particulate Science and Technology》2019,37(6):766-776
The effects of SiC, Al2O3, and ZrO2 particles on the characteristics of Al/SiC, Al/Al2O3, and Al/ZrO2 metal matrix composites (MMCs) have been studied in the present research work. The comparison of machining characteristics has been done to analyze the behavior of various reinforced particles with the variation of laser machining variables. The output characteristics such as dross height and kerf deviation have been investigated and compared with each MMCs. SEM and XRD have been used for the investigation of morphological changes in the structure and agglomeration of reinforced particles. The crack and recast layer formation has been examined in the specimens of higher quantity of reinforced particles. It was observed that the MMC material reinforced with SiC particles has shown different behavior as compared to other MMC materials. 相似文献
8.
鄂尔多斯盆地马家沟组碳酸盐岩储层成岩相测井识别评价 总被引:5,自引:3,他引:2
基于岩心分析、常规测井和成像测井等资料,对鄂尔多斯盆地马家沟组五段5亚段-10亚段储层的储集空间类型、成岩作用类型和强度、成岩矿物组合特征等进行了研究。马家沟组五段5亚段-10亚段储层的岩性以粉晶、细晶白云岩为主,储集空间以晶间孔、晶间溶孔和溶孔为主,偶尔伴生成岩裂缝。根据成岩作用、成岩矿物和储层物性,马家沟组五段5亚段-10亚段可划分出晶间孔相、溶蚀相、成岩微裂缝相、压实压溶相、钙质胶结相和膏质充填相6种成岩相。结合成岩相在常规测井曲线上的响应特征,引入成像测井孔隙度谱分析方法,实现了单井成岩相的测井识别,分析结果与试气资料吻合较好。成像测井孔隙度谱的定性分析与常规测井相结合可揭示孔隙的发育状况和分布,判别测井成岩相,为储层评价和预测提供理论指导和方法支持。 相似文献
9.
David P. Serrano Juan A. Melero Gabriel Morales Jose Iglesias Patricia Pizarro 《Catalysis Reviews》2018,60(1):1-70
This article reviews the recent advances in the development of zeolite catalysts for biomass valorization processes to produce both biofuels and/or bio-based chemicals, which is an emerging and fast expanding field. The work deals with different types of feedstocks, including vegetable oils, lignocellulose and sugars, as well as with a number of relevant intermediates and platform molecules. Transformation of biomass into valuable products is hindered by a number of factors, mainly related to its complex composition, as biomass typically consists of bulky molecules with high oxygen content. Accordingly, biomass processing usually requires the combination of multiple steps and severe conditions, hence concepts like atom efficiency, product selectivity, and catalyst deactivation become of special relevance. A great progress has been achieved in the past years engineering the properties of zeolites for being adapted to the challenges associated to biomass valorization. The possibility of tailoring the main physicochemical properties of zeolites has become now a reality, being the major reason that explains the success achieved by this class of materials in a growing variety of biomass conversion pathways, as those described in this work: catalytic cracking and pyrolysis, hydrotreatments, with special relevance for hydrodeoxygenation processes, as well as in a high number of condensation, isomerization, and dehydration reactions. Thus, the development of hierarchical zeolites, exhibiting enhanced accessibility, and the possibility of introducing and combining in a controlled way different types of active sites (Brønsted and Lewis acid centers, basic sites, and metal phases) are the main basis of the excellent performance of zeolites in numerous biomass conversion routes. 相似文献
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