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1.
Jiatong Zhu Xuanyu Meng Ping Zhang Zhuolun Li Jie Xu Michael J. Reece Feng Gao 《Journal of the European Ceramic Society》2021,41(4):2861-2869
A series of rare earth zirconates (RE2Zr2O7) high-entropy ceramics with single- and dual-phase structure were prepared. Compared with La2Zr2O7 and Yb2Zr2O7, the smaller “rattling” ions (Yb3+, Er3+, Y3+) have been incorporated into pyrochlore lattice in (La0.2Nd0.2Y0.2Er0.2Yb0.2)2Zr2O7 (LNYEY) while larger ions (La3+, Nd3+, Sm3+, Eu3+) incorporated into fluorite lattice in (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2Zr2O7 (LNSGY). Due to high-entropy lattice distortion and resonant scattering derived from smaller ions Yb3+, Er3+, and Y3+, LNYEY shows a lower glass-like thermal conductivity (1.62-1.59 W m-1 K-1, 100-600℃) than LNSGY (1.74-1.75 W m-1 K-1, 100-600℃). Moreover, LNYEY and LNSGY exhibit enhanced Vickers’ hardness (LNYEY, Hv = 11.47 ± 0.41 GPa; LNSGY, Hv = 10.96 ± 0.26 GPa) and thermal expansion coefficients (LNYEY, 10.45 × 10-6 K-1, 1000℃; LNSGY, 11.02 × 10-6 K-1, 1000℃). These results indicate that dual-phase rare-earth-zirconate high-entropy ceramics could be desirable for thermal barrier coatings. 相似文献
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通过固液掺杂、等静压压制、中频烧结的方法,制备了不同的氧化镧、氧化钇、氧化锆三元掺杂成分比例的钨电极材料烧结棒材,探究了不同成分配比对样品显微组织、第二相粒子分布以及宏观力学性能的影响。结果表明,氧化镧、氧化钇、氧化锆三元复合添加能够有效改善第二相粒子在钨基体中的分布形态,降低第二相在晶界的过度富集,提高钨电极材料的综合力学性能。并且当添加成分镧、钇、锆质量比为3:1:1时,材料具有最好的综合力学性能,致密度可达96.04%,显微硬度可达549.37HV0.3,抗压强度可达3785MPa,原因是此配比下第二相粒子最为细小均匀,弥散程度最高,对基体晶粒的细化作用最好,该配比下钨基体平均晶粒尺寸达到10.3μm。 相似文献
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Fatemeh Abdi 《Optimization methods & software》2019,34(1):25-36
In this paper, we propose a globally convergent BFGS method to solve Variational Inequality Problems (VIPs). In fact, a globalization technique on the basis of the hyperplane projection method is applied to the BFGS method. The technique, which is independent of any merit function, is applicable for pseudo-monotone problems. The proposed method applies the BFGS direction and tries to reduce the distance of iterates to the solution set. This property, called Fejer monotonicity of iterates with respect to the solution set, is the basis of the convergence analysis. The method applied to pseudo-monotone VIP is globally convergent in the sense that subproblems always have unique solutions, and the sequence of iterates converges to a solution to the problem without any regularity assumption. Finally, some numerical simulations are included to evaluate the efficiency of the proposed algorithm. 相似文献
6.
Traditional Multiple Empirical Kernel Learning (MEKL) expands the expressions of the sample and brings better classification ability by using different empirical kernels to map the original data space into multiple kernel spaces. To make MEKL suit for the imbalanced problems, this paper introduces a weight matrix and a regularization term into MEKL. The weight matrix assigns high misclassification cost to the minority samples to balanced misclassification cost between minority and majority class. The regularization term named Majority Projection (MP) is used to make the classification hyperplane fit the distribution shape of majority samples and enlarge the between-class distance of minority and majority class. The contributions of this work are: (i) assigning high cost to minority samples to deal with imbalanced problems, (ii) introducing a new regularization term to concern the property of data distribution, (iii) and modifying the original PAC-Bayes bound to test the error upper bound of MEKL-MP. Through analyzing the experimental results, the proposed MEKL-MP is well suited to the imbalanced problems and has lower generalization risk in accordance with the value of PAC-Bayes bound. 相似文献
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Nasser Samadzadehaghdam Bahador Makkiabadi Sadegh Masjoodi Mohammad Mohammadi Fahimeh Mohagheghian 《International journal of imaging systems and technology》2019,29(4):686-700
Brain source imaging based on EEG aims to reconstruct the neural activities producing the scalp potentials. This includes solving the forward and inverse problems. The aim of the inverse problem is to estimate the activity of the brain sources based on the measured data and leadfield matrix computed in the forward step. Spatial filtering, also known as beamforming, is an inverse method that reconstructs the time course of the source at a particular location by weighting and linearly combining the sensor data. In this paper, we considered a temporal assumption related to the time course of the source, namely sparsity, in the Linearly Constrained Minimum Variance (LCMV) beamformer. This assumption sounds reasonable since not all brain sources are active all the time such as epileptic spikes and also some experimental protocols such as electrical stimulations of a peripheral nerve can be sparse in time. Developing the sparse beamformer is done by incorporating L1-norm regularization of the beamformer output in the relevant cost function while obtaining the filter weights. We called this new beamformer SParse LCMV (SP-LCMV). We compared the performance of the SP-LCMV with that of LCMV for both superficial and deep sources with different amplitudes using synthetic EEG signals. Also, we compared them in localization and reconstruction of sources underlying electric median nerve stimulation. Results show that the proposed sparse beamformer can enhance reconstruction of sparse sources especially in the case of sources with high amplitude spikes. 相似文献
9.
在进行能量色散X射线荧光光谱(EDXRF)解谱时,如果给定样品的元素构成,采用纯元素谱图剥离的方式会更加合理,但由于每个元素的谱线都不止一条,如果仅仅针对主线对齐做剥离,会导致结果的严重失真,同时剥离次序对解谱结果有较大影响。介绍了一种最优化算法与纯元素谱剥离相结合的EDXRF解谱方法,该方法以多个纯元素谱的强度大小和峰位漂移道数作为变量构建残差方程,并用最优化计算的方法去调整,直至残差达到极小。实验采用强度顺序剥离、能量顺序剥离和最优化算法拟合3种方法分别对谱线重叠较为严重的La-Ce-Pr-Nd混合液样品的L系谱线进行了解析,结果表明最优化计算方法拟合的谱图与原始谱的残差 (1415.0)比另两种方法(166094.0和3192.7)大幅度缩小,拟合谱与原始谱更为吻合,并且方法在实现时对初值不敏感,解谱精度也不依赖于剥离次序。 相似文献
10.
The paper concerns an analysis of an equilibrium problem for 2D elastic body with two semirigid inclusions. It is assumed that inclusions have a joint point, and we investigate a junction problem for these inclusions. The existence of solutions is proved, and different equivalent formulations of the problem are proposed. We investigate a convergence to infinity of a rigidity parameter of the semirigid inclusion. It is proved that in the limit, we obtain an equilibrium problem for the elastic body with a rigid inclusion and a semirigid one. A parameter identification problem is investigated. In particular, the existence of a solution to a suitable optimal control problem is proved. 相似文献