Recycling spent lead acid batteries into aqueous zinc-ion battery material with ultra-flat voltage platforms

The harmless disposal of lead paste in the spent lead-acid batteries (LABs) remains an enormous challenge in traditional pyrometallurgical recycling. Here, we introduced a hydrometallurgical method for the recycling of the spent LABs’ waste to obtain the β-PbO as a novel zinc ion batteries (ZIBs) active material. The obtained β-PbO exhibits ultra-flat charge/discharge voltage platforms (0.21 mV/(mAh g^?1)) and stable specific capacity. During the charge/discharge, the β-PbO spontaneously triggers the formation of (ZnSO₄)[Zn(OH)₂]₃·5H₂O (ZHS) micro-sheets as a surface passivation layer. Moreover, the ex-situ X-ray spectra reveal that the reversible phase transformation occurs between PbSO₄ and Pb with the assistance of ZHS by adjusting the PH value on the electrode-electrolyte interface. The synergistic two-phase-reaction mechanism generates ultra-flat voltage platforms upon the charge/discharge. This “energy-saving and environment-friendly” recycling route eliminates the major source of emission of pollution particulates/gases compared to the traditional pyrometallurgical recycling, while at the same time replacing energy-consuming and environmentally detrimental processes of synthesis of current ZIBs cathodes.     

浅谈机电设备维修保养与修旧利废

随着社会经济的发展和科学技术的不断提高,对煤矿机电设备安全和生产效率的要求也越来越高,机电设备折旧与维修关系到企业的经济效益和正常的生产流程。就设备折旧维修工作中存在的问题展开论述,对煤矿机电设备正确、科学地保养、维修、废物利用进行了研究,以期为日后相关工作的顺利进行提供参考和借鉴。     

废旧毛涤黏混纺面料脱色预处理工艺研究

以废旧毛涤黏混纺面料为研究对象,首先对面料进行清洁与消毒,然后对其组分进行定性、定量分析,最后通过单因素法优化,得出最佳的溶胀工艺为:m_(废旧面料)∶m_(DMSO)=1∶10,溶胀时间40 min,溶胀温度90℃。在该工艺下对织物进行溶胀处理,得到织物的质量损失率为3.06%,K/S值为16.906。     

Plasmonic Oxygen-Deficient TiO2-x Nanocrystals for Dual-Band Electrochromic Smart Windows with Efficient Energy Recycling

Dual-band electrochromic smart windows capable of the spectrally selective modulation of visible (VIS) light and near-infrared (NIR) can regulate solar light and solar heat transmittance to reduce the building energy consumption. The development of these windows is however limited by the number of available dual-band electrochromic materials. Here, plasmonic oxygen-deficient TiO_2-x nanocrystals (NCs) are discovered to be an effective single-component dual-band electrochromic material, and that oxygen-vacancy creation is more effective than aliovalent substitutional doping to introduce dual-band properties to TiO₂ NCs. Oxygen vacancies not only confer good near-infrared (NIR)-selective modulation, but also improve the Li⁺ diffusion in the TiO_2-x host, circumventing the disadvantage of aliovalent substitutional doping with ion diffusion. Consequently optimized TiO_2-x NC films are able to modulate the NIR and visible light transmittance independently and effectively in three distinct modes with high optical modulation (95.5% at 633 nm and 90.5% at 1200 nm), fast switching speed, high bistability, and long cycle life. An impressive dual-band electrochromic performance is also demonstrated in prototype devices. The use of TiO_2-x NCs enables the assembled windows to recycle a large fraction of energy consumed in the coloration process (“energy recycling”) to reduce the energy consumption in a round-trip electrochromic operation.     

Deconvoluting Energy Transport Mechanisms in Metal Halide Perovskites Using CsPbBr3 Nanowires as a Model System

Understanding energy transport in metal halide perovskites is essential to effectively guide further optimization of materials and device designs. However, difficulties to disentangle charge carrier diffusion, photon recycling, and photon transport have led to contradicting reports and uncertainty regarding which mechanism dominates. In this study, monocrystalline CsPbBr₃ nanowires serve as 1D model systems to help unravel the respective contribution of energy transport processes in metal-halide perovskites. Spatially, temporally, and spectrally resolved photoluminescence (PL) microscopy reveals characteristic signatures of each transport mechanism from which a robust model describing the PL signal accounting for carrier diffusion, photon propagation, and photon recycling is developed. For the investigated CsPbBr₃ nanowires, an ambipolar carrier mobility of μ = 35 cm² V⁻¹ s⁻¹ is determined, and is found that charge carrier diffusion dominates the energy transport process over photon recycling. Moreover, the general applicability of the developed model is demonstrated on different perovskite compounds by applying it to data provided in previous related reports, from which clarity is gained as to why conflicting reports exist. These findings, therefore, serve as a useful tool to assist future studies aimed at characterizing energy transport mechanisms in semiconductor nanowires using PL.     

关于构建塑料包装废弃物的分类、收集与管理体系的思考

简介了我国塑料包装行业发展状况和塑料包装废弃物治理的有关政策与法规；阐述了为解决塑料包装废弃物等对环境造成的污染不同主体应承担与落实的责任，包括政府部门、企业和消费者等；提出了为高值（质）化回收利用塑料包装废弃物构建细化分类、收集与管理体系的一些设想。     

Chemical Recycling of Carbon Fiber Reinforced Epoxy Composites Using Mild Conditions

The increased use of carbon fiber reinforced thermosets generates more waste and end-of-life products. However, an efficient recycling method for the expensive carbon fibers has not yet been developed. The selective decomposition of amine-cured epoxy resin under mild conditions is presented. A two-step method was investigated to decompose the epoxy resin. The optimum parameters were initially determined using a model compound. By analysis of the reaction products, a cleavage of the C–N bond according to the Cope elimination could be proven. Therefore, the Cope elimination is suggested as the main step of the decomposition of amine-cured epoxy resins in presence of hydrogen peroxide. By dissolving the resin, it is possible to recover resin-free fibers with unimpaired mechanical properties.     

Plastic-containing materials as alternative reductants for base metal production

Shredder residue materials are produced after the removal of ferrous and non-ferrous fractions from end-of-life electronic equipment. Despite the high plastic content and metal value in the ash, high percentages of these materials are currently sent to landfills. In this study, the potential of utilising shredder residue material and other plastic-containing materials as reducing agents was studied. Plastic-containing materials were co-injected with coal into a zinc-fuming furnace in Boliden-Rönnskär smelter. The data obtained from the trial, such as the data from the chemical analysis of the slag and the steam production, are discussed. The observations indicate that plastic-containing material can replace up to 1?ton?h^?1 of coal without a significant decrease in the zinc reduction rate.     

澜湄环境利益共同体模式的评价与选择研究

推进澜湄合作是构建周边命运共同体的具体实践，以“同饮一江水，命运紧相连”为主题的澜湄合作机制也为构建澜湄国家命运共同体提供了推进方向。环境问题是澜湄流域最为核心的问题之一，面向澜湄合作中的环境利益问题，文章结合共同体的理念，基于霍尔三维结构理论，总结出合作伙伴环境利益共同体模式、合作联盟环境利益共同体模式与一体化环境利益共同体模式的三种环境利益共同体模式，通过建立环境利益共同体模式的评价指标体系，利用网络层次分析法对澜湄环境利益共同体模式进行评价，选择适合澜沧江-湄公河的环境利益共同体模式。结果表明，在当前的澜湄现状下，以“澜湄六国通过开发流域资源发展本国经济而同时受到其他主体监督以保证不破坏澜沧江-湄公河的生态环境”为主要内容的合作联盟环境利益共同体模式更适合澜湄流域各国，这一模式可以有效解决流域各国经济与环境“两难重”的困境。