煤炭资源型城市转型模式研究：以徐州贾汪区为例

煤炭资源型城市为我国经济发展提供了重要的资源和能源支持,研究资源型城市转型的经验模式对调整区域经济结构、确保社会稳定和改善生态环境具有重要的实践意义。本文采用文献综述法和实证分析法,研究我国东部煤炭资源枯竭型城市转型所面临的共性难题,并以徐州贾汪区转型探索经历为例,总结城市转型的"徐州贾汪区模式",主要包括放大正向外部效应、长期坚持矿地融合、大力建设矿区社会生态系统恢复力三条路径。研究结果表明,煤炭城市转型发展的共性问题相互联系、相互影响,是一个系统性难题,必须引入系统性思维。我国东部矿区普遍人口密集,农业发达、沉陷积水是最主要的共性特征,煤炭开采产生的社会问题、经济问题、生态问题、环境问题基本相同,转型发展模式值得互鉴。     

2种侧围加强内框总成检具结构对比分析

概述了侧围加强内框总成与周边零件的匹配关系,从检具操作的人机工程出发,描述了侧围加强内框总成检具的2种定位方式和结构设计,对比了2种定位方式对于检测结果的影响,总结了其优点和弊端,结果表明侧围加强内框总成检具采用车内方向朝下的定位方式效果更好。     

Spirobifluorene Dimers: Understanding How The Molecular Assemblies Drive The Electronic Properties

Spirobifluorene (SBF) is one of the most important scaffolds used in the design of organic semi-conductors (OSCs) for electronics. In recent years, among all the structures developed for these applications, SBF dimers have been highlighted due to their great potential in thermally activated delayed fluorescence and in phosphorescent organic light-emitting diodes. Attaching two SBF units generate 10 dimers, each possessing its own structural specificity, which in turn drives its electronic properties. These ten SBF dimers are gathered herein. Understanding how the molecular assembly determines the electronic properties has been one of the pillars of organic electronics. This is the goal of this article. As positional isomerism is a key tool to design OSCs, defining the design guidelines for the SBF scaffold appears of interest for the future of this building block. Herein, the importance of the two main parameters involved in the electrochemical and photophysical properties, namely the nature of the phenyl linkages and the steric congestion between the two SBF units is discussed. The combination of these two parameters drives the electronic properties but their respective weight is different as a function of the regioisomer involved or of the property considered (frontier orbitals energy level, absorption, fluorescence, phosphorescence).     

The influence of mining factors on seismic activity during longwall mining of a coal seam

In this article an attempt to determine the influence of mining factors on the seismic activity during the longwall mining of the upper layer of coal seam no. 405/2 in one of the Polish hard coal mines in the Upper Silesian Coal Basin was conducted. Two longwall panels were mined in analogous geological conditions and based on the same mining system and technology. However, there was significant difference with regards to the mining factors, which was reflected in the observed seismic activity. Some tools used in mining seismology were applied to illustrate the aforementioned influence of mining factors, e.g. the frequency-energy distribution, the frequency-magnitude distribution, the 2 D distribution of released seismic energy, the relationship between released seismic energy and the volume of mined coal, the Benioff strain release, and the Gutenberg-Richter(GR) b coefficient distribution(b is the proportion between high and low energy tremors). Concerning the Benioff strain release, a new solution, based on the slope of a fitted line in a moving time window, is proposed.     

不同细颗粒含量甲烷水合物沉积物三轴剪切试验研究

海域试开采区域含水合物沉积物的粒度分析结果表明水合物沉积物骨架由粗、细颗粒混合构成,通过开展多组低温、高压三轴排水剪切试验研究细颗粒含量和密度对含甲烷水合物沉积物和无水合物沉积物的强度和变形特性的影响。试验结果表明,含水合物沉积物抗剪强度及剪胀性都随细粒含量提高而显著增强。这是由于细颗粒含量增加改变了颗粒间水合物的样貌和分布特征,形成了由水合物包裹着粗颗粒-细颗粒的团簇状集合体。然而,细颗粒含量对无水合物沉积物的强度和变形特性的影响却表现出相反趋势。另外,含水合物沉积物的剪胀关系可以使用修正剑桥模型中的剪胀关系式进行描述。结果表明,剪胀关系的拟合曲线依赖于水合物饱和度的大小。通过对比研究发现,天然水合物和实验室合成水合物试样在较高饱和度时的峰值摩擦角大小及其伴随水合物饱和度的增长趋势存在差异,这种差异主要来源于水合物在沉积物骨架颗粒孔隙中不同的赋存模式及分布特征。     

InSAR技术在矿区地表变形监测中的应用

以禹州市梁北矿为研究区，利用2018年11月—2020年6月间35景5 m×20 m分辨率Sentinel-1A数据，采用InSAR技术，利用SBAS（短基线集InSAR）雷达干涉测量方法对梁北矿进行地面沉降信息提取解译，并通过实地调查成果认为，采用InSAR技术适合在矿区开展地表变形监测。     

Enhanced electrocatalytic oxygen reduction reaction from organic-inorganic heterostructure

Herein, molybdenum disulfide nanoflakes decorated copper phthalocyanine microrods (CuPc-MoS₂) are synthesized via two step simple hydrothermal method. The as synthesized hybrid along with pure molybdenum disulfide (MoS₂) nanoflower and pure copper phthalocyanine (CuPc) microrods are well characterized by various techniques that confirm phase, morphology, elemental compositions etc. Next, electrocatalytic oxygen reduction reaction towards fuel cell is investigated in alkaline medium and obtained results proclaim that our CuPc-MoS₂ heterostructure outperforms the other two constituent materials. Efficient oxygen reduction is achieved following four electron pathway by CuPc-MoS₂ whereas partial reduction is done through two electron process by CuPc and MoS₂ separately. Long-time durability test reveals almost 97.6% retention after 8000s that eventually dictate us that CuPc-MoS₂ heterostructure can be the efficient cathode electrocatalyst for future generation fuel cell.     

基于多媒体技术的思想政治教育课程资源整合系统

为解决资源种类划分结果异常,设计基于多媒体技术的思想政治教育课程资源整合系统。选用CYUSB3014芯片作为此次设计系统的主控芯片,并设定信息处理芯片以及外围电路。在此基础上,对思政课程信息进行分类,建立了课程资源库。优化资源整合模块,设定多媒体资源整合流程,并添加DataSet与.NET Framework数据处理程序,实现对多媒体数据的高效处理。构建系统测试环节显示,此系统资源种类划分结果较为合理且系统承载率较高。由此可知,此系统在应用中具有较高的综合性能。     

乌兰矿采矿现状及技术应对方案

本文分析了乌兰矿投产前期采矿现状及存在的主要问题,针对该矿所处蒙古国经济落后、投资风险大的现实状况,为避免生产中断、规避投资风险,早日回收前期投资考虑,采取了双斜坡道开拓、全尾胶结充填、高端壁空场嗣后充填采矿、多中段组合式连续开采等系列技术应对方案。大大降低了一次性投资规模及投资风险,前期投资得以快速回笼的同时,矿山产能也充分释放,确保了矿山的持续稳定,取得了较好的经济和社会效益。为海外地下近地表矿体开采矿山规避投资风险提供了很好的技术方案借鉴。     

煤峪口矿81010工作面煤层底板裂隙发育特征及防治

针对煤炭开采过程中出现的突水事故,采用RFPA数值模拟软件建立采动模型,对底板裂隙破断过程和声发射进行模拟,研究煤层底板采动裂隙扩展突水通道,结果表明:离断层越近,断层内水压导升高度越高,断层出现活化,裂隙扩展发育,最终贯通形成导水通道,在进行注浆改造后,单个钻孔的最大涌水量为8 m³/h,说明注浆加固防治水效果较好,能确保工作面的安全回采。