冷低压分离器油相系统铵盐垢下腐蚀风险的模拟预测

为探究某加氢装置高压换热器管束腐蚀泄漏原因，利用Aspen Plus工艺模拟软件计算了冷低压分离器油相（简称冷低分油）中水质量分数分别为1%,2%,3%时，冷低分油系统的露点温度、氯化铵结晶温度、氯化铵潮解点温度和相对湿度。结果表明：相较于经验的露点温度预测方法，通过引入潮解点、划分系统“湿环境”温度范围判断氯化铵垢下腐蚀风险区域的方法与实际腐蚀案例更为切合；在3种油相含水条件下，换热器管束存在氯化铵垢下腐蚀的“湿环境”温度范围分别为：50~103 ℃,50~161 ℃,50~176 ℃；随着油相中含水量的提高，“湿环境”腐蚀区域逐渐向高温部位迁移，预计铵盐导致的垢下腐蚀将会愈加严重。     

Designing amorphous formulations of polyphenols with naringin by spray-drying for enhanced solubility and permeability

Naringin (NAR), a major flavanone (FVA) glycoside, is a component of food mainly obtained from grapefruit. We used NAR as a food additive to improve the solubility and permeability of hydrophobic polyphenols used as supplements in the food industry. The spray-dried particles (SDPs) of NAR alone show an amorphous state with a glass transition temperature (T_g) at 93.2 °C. SDPs of hydrophobic polyphenols, such as flavone (FVO), quercetin (QCT), naringenin (NRG), and resveratrol (RVT) were prepared by adding varying amounts of NAR. All SDPs of hydrophobic polyphenols with added NAR were in an amorphous state with a single T_g, but SDPs of hydrophobic polyphenols without added NAR showed diffraction peaks derived from each crystal. The SDPs with NAR could keep an amorphous state after storage at a high humidity condition for one month, except for SDPs of RVT/NAR. SDPs with NAR enhanced the solubility of hydrophobic polyphenols, especially NRG solubility, which was enhanced more than 9 times compared to NRG crystal. The enhanced solubility resulted in the increased membrane permeability of NRG. The antioxidant effect of the hydrophobic NRG was also enhanced by the synergetic effect of NAR. The findings demonstrated that NAR could be used as a food additive to enhance the solubility and membrane permeability of hydrophobic polyphenols.     

Comparison of γ-aminobutyric acid accumulation capability in different mung bean (Vigna radiata L.) varieties under heat and relative humidity treatment,and its correlation with endogenous amino acids and polyamines

In this study, the accumulation of GABA and its inherent factors across different varieties of mung bean (Vigna radiata L.) in response to heat and relative humidity (HRH) were investigated. Results showed the average GABA content in mung bean varieties was increased 7.52 times following HRH treatment, and the black mung bean variety (A8) exhibited the highest GABA accumulation capability (1.76–84.57 mg per 100 g DW). From the perspective of GABA shunt metabolites, the free glutamic acid content of mung beans significantly decreased (P < 0.05) after HRH treatment and presented a significant correlation (P < 0.05) with GABA content. In polyamine degradation pathway, although the average levels of spermine and spermidine of mung bean varieties significantly decreased (P < 0.05) after HRH treatment, no significant correlation with GABA content was identified. Hence, the GABA accumulation was predominantly attributed to GABA shunt. Besides, free amino acids including glutamic acid, serine, ornithine, arginine and glycine in mung beans showed a significant positive correlation (P < 0.05) with GABA content and increment following HRH treatment, which suggested that mung beans enriched in these free amino acids might accumulate higher amounts of GABA after HRH treatment and be useful for industrial applications.     

相对湿度和开孔对纸蜂窝芯层抗压强度的影响

对无孔、开孔蜂窝芯纸条和5种纸蜂窝芯层进行静态压缩实验,研究了相对湿度和开孔(圆孔直径、圆孔数量)对蜂窝芯纸条纵向和横向环压强度以及纸蜂窝芯层抗压强度的影响规律,采用多元线性回归分析法和SPSS软件评估了相对湿度和圆孔直径对蜂窝芯纸条纵向和横向环压强度的影响,探讨了长度缺陷率与环压强度系数之间的经验关系。实验结果表明,无孔和开孔蜂窝芯纸条的纵向环压强度是横向环压强度的1.4~1.5倍;蜂窝芯纸条纵向和横向环压强度以及纸蜂窝芯层的抗压强度都随着相对湿度、圆孔直径和圆孔数量的增加而降低,且双孔蜂窝芯纸条的纵向环压强度和双孔纸蜂窝芯层的抗压强度更易受相对湿度的影响;在相对湿度和开孔的综合影响下,纸蜂窝芯层适合开圆孔直径为2 mm或3 mm的单孔。     

翅片结构对单向开缝翅片管换热器传热与阻力性能的影响

通过对不同开缝数量、不同相对开缝高度的单向开缝翅片管换热器进行模拟,分析开缝数量、相对开缝高度对单向开缝翅片管换热器传热与阻力性能的影响规律。结果表明:在开缝数量为3～7片时,翅片侧Nu和f因子随着开缝数量的增加而增大,但Nu增幅逐渐减小;将开缝的数量取为5片能得到最好的综合性能;在相对开缝高度为0.3～0.7时,翅片侧Nu和f因子随着相对开缝高度的增加而增大,但当相对开缝高度在0.5～0.7范围内,翅片侧Nu的增幅减小;将相对开缝高度取为0.5能得到最好的综合性能。     

A volume element model (VEM) for energy systems engineering

This work presents a simplified modeling and simulation approach for energy systems engineering that is capable of providing quick and accurate responses during system design. For that, the laws of conservation are combined with available empirical and theoretical correlations to quantify the diverse types of flows that cross the system and produce a simplified tridimensional mathematical model, namely a volume element model (VEM). The physical domain of interest is discretized in space, thus producing a system of algebraic and ODEs with respect to time, whose solution delivers the project variables spatial distribution and dynamic response. In order to illustrate the application of the VEM in energy systems engineering, three example problems are considered: (i) a regenerative heat exchanger; (ii) a power electronic building block (PEBB); and (iii) a notional all‐electric ship. The same mathematical model was used to analyze problems (ii) and (iii), that is, the thermal management of heat‐generating equipment packaging. In the examples, the converged mesh had a total of 20, 2000, and 7725 volume elements. The third problem led to the largest simulation, which for steady‐state cases took between 5 and 10 min of computational time to reach convergence and for the ship dynamic response 50 min (i.e., 80,000 s of real time). The regenerative heat exchanger model demonstrated how VEM allowed for the coexistence of different phases (subsystems) within the same volume element. The thermal management model was adjusted and experimentally validated for the PEBB system, and it was possible to perform a parametric and dynamic analysis of the PEBB and of the notional all‐electric ship. Therefore, because of the observed combination of accuracy and low computational time, it is expected that the model could be used as an efficient tool for design, control, and optimization in energy systems engineering. Copyright © 2014 John Wiley & Sons, Ltd.     

A Straightforward Direct Traction Boundary Integral Method for Two-Dimensional Crack Problems Simulation of Linear Elastic Materials

This paper presents a direct traction boundary integral equation method (DTBIEM) for two-dimensional crack problems of materials. The traction boundary integral equation was collocated on both the external boundary and either side of the crack surfaces. The displacements and tractions were used as unknowns on the external boundary, while the relative crack opening displacement (RCOD) was chosen as unknowns on either side of crack surfaces to keep the single-domain merit. Only one side of the crack surfaces was concerned and needed to be discretized, thus the proposed method resulted in a smaller system of algebraic equations compared with the dual boundary element method (DBEM). A new set of crack-tip shape functions was constructed to represent the strain field singularity exactly, and the SIFs were evaluated by the extrapolation of the RCOD. Numerical examples for both straight and curved cracks are given to validate the accuracy and efficiency of the presented method.     

低觉醒脑电识别与唤醒的可穿戴系统研究

为智能化地识别警戒作业人员出现的低觉醒、注意力下降的生理状态，本文介绍了一种基于FPGA和脑电信号处理的低觉醒状态检测与唤醒系统，系统通过传感器从大脑头皮采集脑电信号，转换为数字信号，经傅里叶变换获取了脑电信号的θ相对能量、α相对能量、重心频率、谱熵等4个特征量，由4个特征量表征低觉醒状态并运用支持向量机对低警戒状态进行识别，当识别出低觉醒状态时采用声音报警模块发出声音，唤醒警戒作业人员。设计系统能够较好地识别出低觉醒状态，识别率达90.8%，可为提高警戒作业工作绩效提供一种可穿戴的智能装备。     

A Pyropheophorbide Analogue Containing a Fused Methoxy Cyclohexenone Ring System Shows Promising Cancer-Imaging Ability

Herein we report the synthesis, photophysical properties, positron emission tomography (PET) imaging and photodynamic therapy (PDT) efficacy of methyl 3-(1′-m-iodobenzyloxy)ethyl-3-devinyl-verdin 4 (with or without the ¹²⁴I isotope). The PET imaging ability and ex vivo biodistribution of [¹²⁴I] 4 were compared with the well-studied methyl [3-(¹²⁴1′-m-iodobenzyloxy)ethyl]-3-devinyl-pyropheophorbide-a methyl ester (PET-ONCO or [¹²⁴I] 2 ) and [¹⁸F]fluorodeoxyglucose ([¹⁸F]FDG) in BALB/c mice bearing colon-26 tumors. Whole-body PET images of [¹²⁴I] 4 containing a fused methoxy cyclohexenone ring system showed excellent tumor contrast with time (72>48>24 h post-injection). Ex vivo biodistribution results indicate that relative to the current clinical standard [¹⁸F]FDG and [¹²⁴I] 2 in 2 % ethanol formulation, [¹²⁴I] 4 , at the same radioactive dose (25 μCi per mouse), showed higher tumor uptake at 24 h post-injection and longer tumor retention. In biological environments, compound 4 showed lower fluorescence and lower singlet oxygen yield than 2 , which is possibly due to higher aggregation caused by the presence of a fused cyclohexenone ring system, resulting in limited in vitro/in vivo PDT efficacy. Therefore, the chlorophyll-a analogue [¹²⁴I] 4 provides easy access to a novel PET imaging agent (with no skin phototoxicity) to image cancer types—brain, renal carcinomas, pancreas—in which [¹⁸F]FDG shows limitations.