全文获取类型
收费全文 | 3138篇 |
免费 | 534篇 |
国内免费 | 394篇 |
专业分类
电工技术 | 88篇 |
综合类 | 397篇 |
化学工业 | 265篇 |
金属工艺 | 41篇 |
机械仪表 | 54篇 |
建筑科学 | 22篇 |
矿业工程 | 28篇 |
能源动力 | 29篇 |
轻工业 | 31篇 |
水利工程 | 13篇 |
石油天然气 | 19篇 |
武器工业 | 10篇 |
无线电 | 859篇 |
一般工业技术 | 285篇 |
冶金工业 | 42篇 |
原子能技术 | 2篇 |
自动化技术 | 1881篇 |
出版年
2024年 | 8篇 |
2023年 | 54篇 |
2022年 | 61篇 |
2021年 | 67篇 |
2020年 | 83篇 |
2019年 | 82篇 |
2018年 | 68篇 |
2017年 | 110篇 |
2016年 | 106篇 |
2015年 | 125篇 |
2014年 | 166篇 |
2013年 | 202篇 |
2012年 | 243篇 |
2011年 | 304篇 |
2010年 | 268篇 |
2009年 | 290篇 |
2008年 | 334篇 |
2007年 | 341篇 |
2006年 | 260篇 |
2005年 | 267篇 |
2004年 | 215篇 |
2003年 | 140篇 |
2002年 | 95篇 |
2001年 | 66篇 |
2000年 | 38篇 |
1999年 | 13篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 1篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有4066条查询结果,搜索用时 15 毫秒
1.
Dealloyed nanoporous gold (np-Au) has applications as oxygen reduction catalysis in Li-air batteries and fuel cells, or as actuators to convert electricity into mechanical energy. However, it faces the challenges of coarsening-induced structure instability, mechanical weakness due to low relative densities, and slow dealloying rates. Here, monolithic np-Au is dealloyed from a single-phase Au25Ni75 solid-solution at a one-order faster dealloying rate, ultra-low residual Ni content, and importantly, one-third more relative density than np-Au dealloyed from conventional Au25Ag75. The small atomic radius and low dealloying potential of the sacrificing element Ni are intrinsically beneficial to fast produce high relative density np-Au, as predicted by a general model for dealloying of binary alloys and validated by experiments. Stable, durable, and reversible actuation of np-Au takes place under cyclic potential triggering in alkaline and acidic electrolytes with negligible coarsening-induced strain-shift. The thermal and mechanical robustness of bulk np-Au is confirmed by two-order slower ligament coarsening rates during annealing at 300 °C and 45 MPa macroscopic yielding strength distinctive from the typical early onset of plastic yielding. This article opens a rich direction to achieve high relative density np-Au which is essential for porous network connectivity, mechanical strength, and nanostructure robustness for electrochemical functionality. 相似文献
2.
3.
4.
Teh C. Ho 《American Institute of Chemical Engineers》2020,66(6):e16930
Metal sulfide catalysts for ultra-deep hydrodesulfurization of diesel generally lose a fraction of their catalytically active sites during reactor startup. The underlying mechanisms are discussed. A laboratory diagnostic tool consisting of three probe molecules is developed for testing metal sulfide catalysts' start-of-run (SOR) activity maintenance. It is found that a significant fraction of the active sites on a commercial supported catalyst are deactivated permanently, but this is not the case with a bulk metal sulfide catalyst. The SOR deactivation of the bulk catalyst is completely reversible, while that of the supported catalyst is partially reversible. The diagnostic tool may provide a basis for developing a high-throughput approach for evaluating and enhancing catalyst SOR stability, thereby increasing plant productivity. 相似文献
5.
6.
In this paper, we propose a new angle quantization index modulation (AQIM) method, called the difference AQIM (DAQIM) method. The proposed method aims to improve the watermarking performance against gain attacks. Unlike the original AQIM method (Ourique et al., Angle QIM: a novel watermark embedding scheme robust against amplitude scaling distortions, in: Proceedings of IEEE International Conference on Acoustics, Speech, and Signal Processing, vol. 2, 2005, pp. 797–800), the DAQIM method quantizes the difference of the two angles instead of the angles themselves. The main advantage of the DAQIM method is to disperse the interference to the watermark signal from one angle to more angles. Thus, the watermark has a higher ability to resist attacks. We perform a theoretical analysis of the document-to-watermark ratio (DWR) based on our proposed method. We show that our proposed method can obtain a lower embedding distortion compared to the AQIM and the gradient direction watermarking (GDWM) (Nezhadarya et al., IEEE Trans. Inf. Forensics Secur., 6(4), 2011, 1200–1213), methods under the same robustness and payload conditions. The experimental results demonstrate that our proposed method outperforms common existing methods in terms of the robustness against various attacks such as the JPEG quantization noise, additive white Gaussian noise (AWGN), cropping effect and mean filtering. 相似文献
7.
Polymer‐grafted inorganic particles (PGIPs) are attractive building blocks for numerous chemical and material applications. Surface‐initiated controlled radical polymerization (SI‐CRP) is the most feasible method to fabricate PGIPs. However, a conventional in‐batch reaction still suffers from several disadvantages, including time‐consuming purification processes, low grafting efficiency, and possible gelation problems. Herein, a facile method is demonstrated to synthesize block copolymer–grafted inorganic particles, that is, poly(poly(ethylene glycol) methyl ether methacrylate) (PPEGMEMA)‐b‐poly(N‐isopropylacrylamide) (PNIPAM)–grafted silica micro‐particles using continuous flow chemistry in an environmentally friendly aqueous media. Immobilizing the chain transfer agent and subsequent SI‐CRP can be accomplished sequentially in a continuous flow system, avoiding multi‐step purification processes in between. The chain length (MW) of the grafted polymers is tunable by adjusting the flow time or monomer concentration, and the narrower molar mass dispersity (Ð < 1.4) of the grafted polymers reveals the uniform polymer chains on the particles. Moreover, compared with the in‐batch reaction at the same condition, the continuous system also suppresses possible gelation problems. 相似文献
8.
9.
Yasuha Watanabe Prof. Kenzo Fujimoto 《Chembiochem : a European journal of chemical biology》2020,21(22):3244-3248
The regulation of DNAzyme activity is an important problem for its in vivo applications. We achieved photochemical regulation of DNAzyme activity by using reversible DNA photo-crosslinking of 3-cyanovinylcarbazole (CNVK). The ODN containing CNVK photo-crosslinked to a pyrimidine base in the complementary strand after a few seconds of photoirradiation, and its photoadduct was split by photoirradiation of another wavelength. The activity of photo-crosslinked DNAzyme with CNVK was completely inhibited (OFF state). In contrast, after 312 nm irradiation, DNAzyme activity was recovered upon addition of a substrate strand (ON state). In addition, the photo-crosslinked DNAzyme is prone to enzymatic digestion by exonuclease. This photochemical OFF to ON switching with reversible DNA photo-crosslinking was regulated at the desired time and position; therefore, it might be possible to use it for in vivo application. 相似文献
10.