Tuning of ferrimagnetic nature and hyperfine interaction of Ni2+ doped cobalt ferrite nanoparticles for power transformer applications

Ferrites may contain single domain particles which gets converted into super-paramagnetic state near critical size. To explore the existence of these characteristic feature of ferrites, we have performed magnetization(M-H loop) and Mössbauer spectroscopic studies of Ni²⁺ substitution effect in Co_1-xNi_xFe₂O₄ (where x?=?0, 0.25, 0.5, 0.75 and 1) nanoparticles were fabricated by solution combustion route using mixture of carbamide and glucose as fuels for the first time. As prepared samples exhibit spinel cubic structure with lattice parameters which decreases linearly with increase in Ni²⁺ concentration. The M-H loops reveals that saturation magnetization(M_s), coercive field(H_c) remanence magnetization(M_r) and magnetron number(η_B) decreases significantly with increasing Ni²⁺ substitution. The variation of saturation magnetization has been explained on the basis of Neel's molecular field theory. The coercive field(H_c) is found strongly dependent on the concentration of Ni²⁺ and decrease of coercivity suggests that the particles have single domain and exhibits superparamagnetic behavior. The Mössbauer spectroscopy shows two ferrimagnetically relaxed Zeeman sextets distribution at room temperature. The dependence of Mössbauer parameters such as isomer shift, quadru pole splitting, line width and hyperfine magnetic field on Ni²⁺ concentration have been discussed. Hence our results suggest that synthesized materials are potential candidate for power transformer application.     

Role of Nd-Ni on structural,spectral and dielectric properties of strontium-barium based nano-sized X-type ferrites

The influence of neodymium and nickel substitution on structural and dielectric parameters was investigated in strontium-barium X-type hexagonal ferrites having composition SrBaCu_2?xNi_xNd_yFe_28?yO₄₆ (x = 0, 0.2, 0.4, 0.6, 0.8, 1 and y = 0, 0.02, 0.04, 0.06, 0.08, 0.1). Sol-gel method was employed for synthesizing these hexagonal ferrites. The XRD plots of all studied materials which were annealed at 1250 °C show single phase characteristics. Lattice parameter ‘c’ increased as a consequence of larger radius of rare earth ion (Nd³⁺) as compared to (Fe³⁺), while lattice parameter ‘a’ showed very small variation. The cell volume was obtained in the range 2508.32–2523.75 (ų). The inclusion of Nd-Ni also affected X-ray density, bulk density and porosity. The FTIR spectroscopy indicated the particular absorption peaks of hexagonal ferrites and it was performed in the range of 500–700 cm^?1. On account of Nd-Ni doping, the dielectric constant, dielectric loss and AC-conductivity showed decreasing trend. The occupancy of Nd³⁺ ions at octahedral site impedes the valence alternation of Fe³⁺; therefore there was decrease in dielectric permittivity. Ac conductivity has been decreased from 9.14 to 6.49 (Ω cm)^?1 at frequency of 2.7 GHz. The Cole-Cole plots of synthesized materials noticeably revealed grain boundary contribution. The appearance of single semi-circle in impedance Cole-Cole graphs confirms the exceptional role of grain boundaries in the conduction process. The considerably lower dielectric parameters of investigated nano X-type ferrites propose their feasibility for high-frequency applications (phase shifters, dielectric resonators, stealth technology etc).     

航班恢复问题的迭代局部搜索算法

在恶劣天气和机械故障等原因造成航班不能按照原计划执行时，航空公司需要采取相应的措施对航班进行恢复。本文基于经典的资源指派模型，综合考虑了调整时间、换机、联程拉直、取消航班和调机5种恢复策略，提出一种以最小化加权成本为优化目标的航班恢复模型，并设计一种迭代局部搜索算法。首先用构造-修复启发式方法构造可行解，然后从该初始解出发，在飞机路线对的邻域中进行局部搜索。当陷入局部最优后，对解进行扰动，然后从扰动后的解重新出发进行局部搜索。为了提高搜索效率，同时降低陷入局部最优解的概率，局部搜索过程采用模拟退火算法。实例结果表明，本文提出的模型及算法能够在短时间内对受到影响的大规模航班计划进行恢复。     

Improved magnetic and electromagnetic absorption properties of xSrFe12O19/(1−x)NiFe2O4 composites

xSrFe₁₂O₁₉/(1−x)NiFe₂O₄ composites (0 ≤ x ≤ 1.0) were synthesized by using a conventional solid-state synthetic route. The results show that magnetic hysteresis loops of the xSrFe₁₂O₁₉/(1−x)NiFe₂O₄ composites are similar to those of individual component ferrites, except for the 0.1SrFe₁₂O₁₉/0.9NiFe₂O₄ and 0.3SrFe₁₂O₁₉/0.7NiFe₂O₄, suggesting that the hard/soft magnetic phases are well exchange-coupled. The saturation magnetization, coercivity, and remanent magnetization of the xSrFe₁₂O₁₉/(1−x)NiFe₂O₄ composites are increased with increasing content of SrFe₁₂O₁₉, with maximal values of 42.1 Am² kg⁻¹, 78.7 kA m⁻¹, 17.2 Am² kg⁻¹, respectively, as the content x is about 0.5. They are higher than those of the individual components, implying that interface coupling is present in the magnetic composites. The coercivity and remanent magnetization of the composites are increased initially with increasing sintering temperature and then show a downward tendency. For the component SrFe₁₂O₁₉ and NiFe₂O₄, the minimum reflection losses are −12.5 dB and −18.3 dB at match thicknesses of 2.5 mm and 2 mm, respectively. Compared with those of the component SrFe₁₂O₁₉ and NiFe₂O₄, the microwave absorption performances of the xSrFe₁₂O₁₉/(1−x)NiFe₂O₄ composites are improved remarkably, especially for the samples of x = 0.3 and x = 0.9. The minimum reflection losses values of the 0.3SrFe₁₂O₁₉/0.7NiFe₂O₄ composite are −31.6 dB (12.7 GHz) and −20.2 dB (13 GHz), while those of the 0.9SrFe₁₂O₁₉/0.1NiFe₂O₄ composites are −23.7 dB (16.3 GHz) and −33.5 dB (15.8 GHz), as the matching thicknesses are 2.5 mm and 2 mm, respectively. Therefore, the xSrFe₁₂O₁₉/(1−x)NiFe₂O₄ composites could be used as potential microwave absorption materials.     

南水北调中线水源区浮游植物群落结构 及其生物多样性

为探究南水北调中线水源区丹江口水库浮游植物群落结构变化及其生物多样性，于 2014—2015 年对丹江 口水库进行为期 1 年的调查和分析。发现浮游植物共 8 门 76 属 101 种，其中，绿藻门、蓝藻门及硅藻门占总种数 90.10%，绿藻门种类数最多（45 种），其次是蓝藻门（26 种）和硅藻门（20 种）。浮游植物群落结构随季节变化有所 不同：夏秋季节生物量明显高于冬春季节；优势种在冬季以颗粒直链藻、颗粒直链藻极狭变种、铜绿微囊藻和小 环藻为主，春季以球衣藻、薄甲藻属及小环藻为主，夏季以简单颤藻、单胞衣藻原变种和球衣藻为主，秋季以类颤 藻鱼腥藻、简单颤藻、球衣藻和小环藻为主。应用 Shannon-Wiener 多样性指数 H′、Pielou 均匀度指数 J′、Margalef 丰富度指数 Dm评价水质结果表明：丹江口水库夏秋季水体营养化程度更高。典型对应分析表明：水温、透明度、 总氮、总磷等是影响浮游植物群落结构的主要环境因子，夏秋季受温度影响蓝藻、绿藻数量逐渐增多，一定程度 上增加了受水区生态变化风险。本研究可为南水北调中线水源区丹江口水库生态环境变化及生物迁移风险提供 数据支持。     

进路式分层崩落采矿系统的设计与实现

首先,简单介绍了分层崩落采矿法的基本思想;然后,根据进路式分层崩落采矿法的特点和工艺流程,给出进路式分层崩落采矿系统的设计思路和实现方法。     

电弧喷涂快速制模技术研究与发展现状

电弧喷涂快速制模技术因其制模周期短、成本低等优点,成为当前模具快速制造技术重要发展方向之一。文章介绍了电弧喷涂快速制模技术的基本原理,各工艺参数对电弧喷涂制模的影响,电弧喷涂快速制模的工艺路线及其技术特点,综述了电弧喷涂快速制模发展现状,最后对电弧喷涂快速制模发展方向进行了展望。     

基于共享单车大数据的城市型自行车绿道选线规划途径研究

城市型自行车绿道对于鼓励居民慢行出行,缓解城市交通拥堵具有非常重要的价值。从共享单车社会行为大数据和绿地空间利用潜力分析两方面内容入手,构建了一个基于实际使用需求和城区可建设空间的城市型自行车绿道选线规划途径,并以北京海淀区为例开展实证探索。选线规划途径主要包括:利用共享单车起点—终点数据,并运用熵值法建立评价指标体系进行绿地节点利用潜力分析,确定关键连接节点;通过共享单车轨迹数据得到自行车使用的道路热度,提取现状线性绿地廊道,生成自行车绿道连接的土地适宜性成本栅格;利用连接节点和成本栅格计算最低成本路径,划定绿道选线。该选线途径将随着城市大数据的进一步丰富和准确而得到完善,具有很好的未来应用前景。     

采用GPS进行城市规划区送电线路测量的方法

本文介绍采用RTK GPS进行线路测量方法,分析影响直线精度因素及具体作业。     

上海轨道明珠线北延伸线友谊路以北走向探讨

通过明珠线一期工程北延伸线友谊路以北线路走向的研究 ,探讨如何尽量减少轨道交通对周围环境及景观的影响 ,以及轨道交通与地区规划、其它市政工程的协调发展等若干问题