首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   219134篇
  免费   31055篇
  国内免费   25421篇
电工技术   21583篇
技术理论   9篇
综合类   17878篇
化学工业   38026篇
金属工艺   8706篇
机械仪表   14375篇
建筑科学   9598篇
矿业工程   2946篇
能源动力   6421篇
轻工业   14086篇
水利工程   3127篇
石油天然气   6343篇
武器工业   2418篇
无线电   34826篇
一般工业技术   23423篇
冶金工业   5076篇
原子能技术   3374篇
自动化技术   63395篇
  2024年   261篇
  2023年   3584篇
  2022年   6285篇
  2021年   7777篇
  2020年   7961篇
  2019年   6870篇
  2018年   6195篇
  2017年   8312篇
  2016年   8643篇
  2015年   10437篇
  2014年   11029篇
  2013年   14113篇
  2012年   17085篇
  2011年   19179篇
  2010年   13849篇
  2009年   13907篇
  2008年   15314篇
  2007年   17316篇
  2006年   16207篇
  2005年   13893篇
  2004年   11725篇
  2003年   9363篇
  2002年   7101篇
  2001年   5402篇
  2000年   4304篇
  1999年   3562篇
  1998年   2918篇
  1997年   2311篇
  1996年   1926篇
  1995年   1663篇
  1994年   1433篇
  1993年   1049篇
  1992年   851篇
  1991年   676篇
  1990年   590篇
  1989年   432篇
  1988年   311篇
  1987年   194篇
  1986年   190篇
  1985年   261篇
  1984年   223篇
  1983年   168篇
  1982年   212篇
  1981年   114篇
  1980年   108篇
  1979年   40篇
  1978年   26篇
  1977年   34篇
  1959年   21篇
  1957年   24篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light.  相似文献   
2.
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB.  相似文献   
3.
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production.  相似文献   
4.
针对燃气轮机故障诊断过程中诊断精度不足,卡尔曼滤波易出现“弥散”现象的问题,提出了一种基于滤波阵列的燃气轮机气路故障诊断方法。该方法首先构建了一组基于健康参数调度的平衡流形展开模型阵列,然后结合平方根容积卡尔曼滤波对气路部件健康参数进行了实时估计,最后通过隔离因子实现了对故障部件的检测与隔离。仿真表明:该方法有效解决了卡尔曼滤波在故障诊断过程中出现“弥散”现象的问题,针对燃气轮机气路部件突变故障,能够有效实现故障的检测、隔离与估计。  相似文献   
5.
Nonintrusive load monitoring (NILM) is crucial for extracting patterns of electricity consumption of household appliance that can guide users’ behavior in using electricity while their privacy is respected. This study proposes an online method based on the transient behavior of individual appliances as well as system steady-state characteristics to estimate the operating states of the appliances. It determines the number of states for each appliance using the density-based spatial clustering of applications with noise (DBSCAN) method and models the transition relationship among different states. The states of the working appliances are identified from aggregated power signals using the Kalman filtering method in the factorial hidden Markov model (FHMM). Thereafter, the identified states are confirmed by the verification of system states, which are the combination of the working states of individual appliances. The verification step involves comparing the total measured power consumption with the total estimated power consumption. The use of transient features can achieve fast state inference and it is suitable for online load disaggregation. The proposed method was tested on a high-resolution data set such as Labeled hIgh-Frequency daTaset for Electricity Disaggregation (LIFTED) and it outperformed other related methods in the literature.  相似文献   
6.
Nickel selenide electrocatalysts for hydrogen evolution reaction (HER) with a high efficiency and a low-cost have a significant potential in the development of water splitting. However, the inferiority of the high overpotential and poor stability restricts their practical applications. Herein, a composite nanostructure consists of ultrasmall NiSe2 nanocrystals embedded on graphene by microwave reaction is reported. The prepared NiSe2/reduced graphite oxide (rGO) electrocatalyst exhibited a high HER activity with an overpotential of 158 mV at a current density of 10 mA/cm2 and a corresponding moderate Tafel slope of 56 mV/dec in alkaline electrolyte. In addition, a high retention of electrochemical properties (approximately 100%) was demonstrated with an unchangeable microstructure after 100 h of continuous operation.  相似文献   
7.
Sorption selective catalytic reduction of nitrogen oxides (NOx) (sorption-SCR) has ever been proposed for replacing commercial urea selective catalytic reduction of NOx (urea-SCR), while only the single-stage sorption cycle is hitherto adopted for sorption-SCR. Herein, various multi-stage ammonia production cycles is built to solve the problem of relative high starting temperature with ammonia transfer (AT) unit and help detect the remaining ammonia in ammonia storage and delivery system (ASDS) with ammonia warning (AW) unit. Except for the single-stage ammonia production cycle with MnCl2, other sorption-SCR strategies all present overwhelming advantages over urea-SCR considering the much higher NOx conversion driven by the heat source lower than 100°C and better matching characteristics with low-temperature catalysts. Furthermore, the required mass of sorbent for each type of sorption-SCR is less than half of the mass of AdBlue for urea-SCR. Therefore, the multifunctional multi-stage sorption-SCR can realize compact and renewable ammonia storage and delivery with low thermal energy consumption and high NOx conversion, which brings a bright potential for efficient commercial de-NOx technology.  相似文献   
8.
As a form of hybrid multi-energy systems, the integrated energy system contains different forms of energy such as power, thermal, and gas which meet the load of various energy forms. Focusing mainly on model building and optimal operation of the integrated energy system, in this paper, the dist-flow method is applied to quickly calculate the power flow and the gas system model is built by the analogy of the power system model. In addition, the piecewise linearization method is applied to solve the quadratic Weymouth gas flow equation, and the alternating direction method of multipliers (ADMM) method is applied to narrow the optimal results of each subsystem at the coupling point. The entire system reaches its optimal operation through multiple iterations. The power-thermal-gas integrated energy system used in the case study includes an IEEE-33 bus power system, a Belgian 20 node natural gas system, and a six node thermal system. Simulation-based calculations and comparison of the results under different scenarios prove that the power-thermal-gas integrated energy system enhances the flexibility and stability of the system as well as reducing system operating costs to some extent.  相似文献   
9.
土体参数具有空间变异性是被广泛接受的,而这种变异性对岩土中结构性能有着重要的影响。随机场理论是一种常用的用来模拟土体参数空间变异性的方法。基于随机场理论,以土体弹性模量的空间变异性为切入点,采用蒙特卡罗方法和有限差分模拟计算相结合的方法,开展隧道水平收敛的随机分析。在大量蒙特卡罗计算基础上,提出了3种简单易用的简化考虑空间变异性的方法,分别为参数折减法、放大系数法和可靠度分项系数标定法。经过对计算结果的统计分析,给出了在土体弹性模量的水平、竖向相关距离及其变异系数的不同组合下3种简化考虑方法的建议值。提出的简化方法可以为空间变异性研究应用到实际工程提供一定的参考。  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号