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1.
Yubing Guo Hamed Shahsavan Metin Sitti 《Advanced materials (Deerfield Beach, Fla.)》2020,32(38):2002753
The shape-shifting behavior of liquid crystal networks (LCNs) and elastomers (LCEs) is a result of an interplay between their initial geometrical shape and their molecular alignment. For years, reliance on either one-step in situ or two-step film processing techniques has limited the shape-change transformations from 2D to 3D geometries. The combination of various fabrication techniques, alignment methods, and chemical formulations developed in recent years has introduced new opportunities to achieve 3D-to-3D shape-transformations in large scales, albeit the precise control of local molecular alignment in microscale 3D constructs remains a challenge. Here, the voxel-by-voxel encoding of nematic alignment in 3D microstructures of LCNs produced by two-photon polymerization using high-resolution topographical features is demonstrated. 3D LCN microstructures (suspended films, coils, and rings) with designable 2D and 3D director fields with a resolution of 5 µm are achieved. Different shape transformations of LCN microstructures with the same geometry but dissimilar molecular alignments upon actuation are elicited. This strategy offers higher freedom in the shape-change programming of 3D LCN microstructures and expands their applicability in emerging technologies, such as small-scale soft robots and devices and responsive surfaces. 相似文献
2.
考虑到不同句子对判断文档情感倾向的重要程度不同,因而区分文档的关键句和细节句将有助于提高情感分类的性能。同时,考虑到Title和上下文信息,提出了一种基于Title和加权TextRank抽取关键句的情感分析方法SKTT,实现了高效的情感分析。根据文档Title的情感权重计算Title贡献度,考虑到标点和语义规则对情感倾向的影响;根据加权TextRank算法思想,在文档正文中构建了一个情感句有向图来提取关键句;计算所有关键句的情感倾向进行情感分类。在4个领域上进行实验,实验结果表明,该SKTT方法性能明显优于Baseline,具有高效性。 相似文献
3.
Kangho Park Woo‐Bin Jung Kiok Kwon Oleg D. Lavrentovich Hee‐Tae Jung 《Advanced functional materials》2019,29(26)
Directed self‐assembly (DSA) using soft materials is an important method for producing periodic nanostructures because it is a simple, cost‐effective process for fabricating high‐resolution patterns. Most of the previously reported DSA methods exploit the self‐assembly of block copolymers, which generates a wide range of nanostructures. In this study, cylinders obtained from supramolecular dendrimer films with a high resolution (<5 nm) exhibit planar ordering over a macroscopic area via guiding topographical templates with a high aspect ratio (>10) and high spatial resolution (≈20 nm) of guiding line patterns. Theoretical and experimental studies reveal that this property is related to geometrical anchoring on the meniscus region and physical surface anchoring on the sidewall. Furthermore, this DSA of dendrimer cylinders is demonstrated by the non‐regular geometry of the patterned template. The macroscopic planar alignment of the dendrimer nanostructure reveals an extremely small feature size (≈4.7 nm) on the wafer scale (>16 cm2). This study is expected to open avenues for the production of a large family of supramolecular dendrimers with different phases and feature dimensions oriented by the DSA approach. 相似文献
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《International Journal of Hydrogen Energy》2021,46(80):40014-40021
Perovskite La0.6Sr0.4Co0.2Fe0.8O3+δ (LSCF) as a promising cathode material possessed overwhelming electronic conduction along with certain ionic conductivity. Its strong electron conduction capability hinder the application of pure-phase LSCF as electrolyte in semiconductor membrane fuel cell (SMFC). In order to constrain the electron transport and take advantage of the decent ion conduction of LSCF, a thin layer of γ-Al2O3 with insulating property was added as an electron barrier layer and combine with LSCF to form a two-layer structure electrolyte. Through adjusting the weight ratio of LSCF/γ-Al2O3 to optimize the thickness of double layers, an open circuit voltage of 0.98 V and a maximum power density of 690 mW/cm2 was received at 550 °C. At the same time, SEM, EIS and other characterization technology had proven that the LSCF/γ-Al2O3 bi-layer electrolyte can work efficiently at low temperature. The advantage of this work is the application of double-layer (γ-Al2O3/LSCF) structure electrolyte to instead of mixed material electrolyte in low-temperature solid oxide fuel cells. Structural innovation and the using of insulating materials provided clues for the further development of SMFC. 相似文献
6.
针对金融领域中智能客服的句子相似度计算方法进行了研究。利用基于词性的分词纠正模型减少中文歧义词、金融相关词汇的分词错误;通过词向量方法和循环神经网络分别提取词语级和句子级的语义特征,并且得到句子向量;用融合层计算出句子向量间的差异特征;对差异特征进行降维和归一化得到句子相似度计算结果。实验结果表明,该方法具有较高的准确率和[F1]值。 相似文献
7.
Finding an optimal alignment connecting two end-points in a specified corridor is a complex problem that requires solving three interrelated sub-problems, namely the horizontal alignment, vertical alignment and earthwork optimization problems. In this research, we developed a novel bi-level optimization model combining those three problems. In the outer level of the model, we optimize the horizontal alignment and in the inner level of the model a vertical alignment optimization problem considering earthwork allocation is solved for a fixed horizontal alignment. Derivative-free optimization algorithms are used to solve the outer problem. The result of our model gives an optimal horizontal alignment in the form of a linear-circular curve and an optimal vertical alignment in the form of a quadratic spline. Our model is tested on real-life data. The numerical results show that our approach improves the road alignment designed by civil engineers by 27% on average, resulting in potentially millions of dollars of savings. 相似文献
8.
《International Journal of Hydrogen Energy》2020,45(28):14470-14479
High-temperature operation of solid oxide fuel cells causes several degradation and material issues. Lowering the operating temperature results in reduced fuel cell performance primarily due to the limited ionic conductivity of the electrolyte. Here we introduce the Fe-doped SrTiO3-δ (SFT) pure perovskite material as an electrolyte, which shows good ionic conduction even at lower temperatures, but has low electronic conduction avoiding short-circuiting. Fuel cell fabricated using this electrolyte exhibits a maximum power density of 540 mW/cm2 at 520 °C with Ni-NCAL electrodes. It was found that the Fe-doping into the SrTiO3-δ facilitates the creation of oxygen vacancies enhancing ionic conductivity and transport of oxygen ions. Such high performance can be attributed to band-bending at the interface of electrolyte/electrode, which suppresses electron flow, but enhances ionic flow. 相似文献
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为研究短纤维纱条中纤维的排列状态与纱条截面纤维根数分布不匀的关系,采用几何概率方法建立了等分区间内纤维左头端数分布与纱条截面纤维根数的期望之间的数学模型,并定义了表征纱条中纤维排列状态的参数。运用蒙特卡罗方法模拟了纱条截面根数不匀随排列参数变化的关系曲线。结果表明:短纤维纱条截面纤维根数的CV值与纱条中短纤维排列参数呈负线性关系,与纤维长度分布和模拟区间大小的划分无关;且当排列参数接近1时,即纤维左头端数在所划分区间中为固定值时,纱条截面纤维根数不匀最低,而当排列参数趋向于0时,即纤维左头端数在所划分区间中呈泊松分布时则不匀最大。 相似文献