全文获取类型
收费全文 | 43922篇 |
免费 | 4566篇 |
国内免费 | 2871篇 |
专业分类
电工技术 | 2786篇 |
技术理论 | 1篇 |
综合类 | 4169篇 |
化学工业 | 6808篇 |
金属工艺 | 3060篇 |
机械仪表 | 1967篇 |
建筑科学 | 2848篇 |
矿业工程 | 1860篇 |
能源动力 | 2007篇 |
轻工业 | 3089篇 |
水利工程 | 1221篇 |
石油天然气 | 2563篇 |
武器工业 | 639篇 |
无线电 | 5273篇 |
一般工业技术 | 4588篇 |
冶金工业 | 2922篇 |
原子能技术 | 1077篇 |
自动化技术 | 4481篇 |
出版年
2024年 | 67篇 |
2023年 | 570篇 |
2022年 | 1104篇 |
2021年 | 1363篇 |
2020年 | 1526篇 |
2019年 | 1251篇 |
2018年 | 1197篇 |
2017年 | 1561篇 |
2016年 | 1652篇 |
2015年 | 1762篇 |
2014年 | 2782篇 |
2013年 | 3030篇 |
2012年 | 3499篇 |
2011年 | 3571篇 |
2010年 | 2643篇 |
2009年 | 2614篇 |
2008年 | 2346篇 |
2007年 | 2903篇 |
2006年 | 2440篇 |
2005年 | 2087篇 |
2004年 | 1772篇 |
2003年 | 1568篇 |
2002年 | 1309篇 |
2001年 | 1142篇 |
2000年 | 960篇 |
1999年 | 784篇 |
1998年 | 670篇 |
1997年 | 552篇 |
1996年 | 525篇 |
1995年 | 454篇 |
1994年 | 333篇 |
1993年 | 275篇 |
1992年 | 234篇 |
1991年 | 181篇 |
1990年 | 156篇 |
1989年 | 116篇 |
1988年 | 74篇 |
1987年 | 46篇 |
1986年 | 43篇 |
1985年 | 40篇 |
1984年 | 32篇 |
1983年 | 19篇 |
1982年 | 16篇 |
1981年 | 15篇 |
1980年 | 18篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1975年 | 9篇 |
1959年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
L.J. Espinoza-Pérez S. Esquivel-Medina E. López-Honorato 《Ceramics International》2021,47(11):15527-15532
The influence of the microstructure on the corrosion rate of three monolithic SiC samples in FLiNaK salt at 900 °C for 250 h was studied. The SiC samples, labeled as SiC-1, SiC-2, and SiC-3, had corrosion rates of 0.137, 0.020, and 0.043 mg/cm2h, respectively. Compared with grain size and the presence of special grain boundaries (i.e., Σ3), the content of high-angle grain boundaries (HAGBs) appeared to have the strongest influence on the corrosion rate of SiC in FLiNaK salt, since the corrosion rate increased six times as the concentration of high-angle grain boundaries increased from 19 to 32% for SiC-2 and SiC-1, respectively. These results stress the importance of controlling the content of HAGBs during the production process of SiC. 相似文献
2.
William M. Pitts Martin Werrel Marco Fernandez Mary A. Long Evan A. Eisenberg James Filliben Cory D. Runyon 《火与材料》2021,45(1):127-154
Fire spread and growth on real‐scale four cushion mock‐ups of residential upholstered furniture (RUF) were investigated with the goal of identifying whether changes in five classes of materials (barrier, flexible polyurethane foam, polyester fiber wrap, upholstery fabric, and sewing thread), referred to as factors, resulted in statistically significant changes in burning behavior. A fractional factorial experimental design plus practical considerations yielded a test matrix with 20 material combinations. Experiments were repeated a minimum of two times. Measurements included fire spread rates derived from video recordings and heat release rates (HRRs). A total of 13 experimental parameters (3 based on the videos and 10 on the HRR results), referred to as responses, characterized the measurements. Statistical analyses based on Main Effects Plots (main effects) and Block Plots (main effects and factor interactions) were used. The results showed that three of the factors resulted in statistically significant effects on varying numbers of the 13 responses. The Barrier and Fabric factors had the strongest main effects with roughly comparable magnitudes. Foam was statistically significant for fewer of the responses and its overall strength was weaker than for Barrier and Fabric. No statistically significant main effects were identified for Wrap or Thread. Multiple two‐term interactions between factors were identified as being statistically significant. The Barrier*Fabric interaction resulted in the highest number of and strongest statistically significant effects. The existence of two‐term interactions means that it will be necessary to consider their effects in approaches designed to predict the burning behavior of RUF. 相似文献
3.
《Ceramics International》2021,47(23):33353-33362
High thermal conductivity Si3N4 ceramics were fabricated using a one-step method consisting of reaction-bonded Si3N4 (RBSN) and post-sintering. The influence of Si content on nitridation rate, β/(α+β) phase rate, thermal conductivity and mechanical properties was investigated in this work. It is of special interest to note that the thermal conductivity showed a tendency to increase first and then decrease with increasing Si content. This experimental result shows that the optimal thermal conductivity and fracture toughness were obtained to be 66 W (m K)-1 and 12.0 MPa m1/2, respectively. As a comparison, the nitridation rate and β/(α+β) phase rate in a static pressure nitriding system, i.e., 97% (MS10), 97% (MS15), 97% (MS20) and 8.3% (MS10), 8.3% (MS15), 8.9% (MS20), respectively, have obvious advantages over those in a flowing nitriding system, i.e., 91% (MS10), 91% (MS15), 93% (MS20) and 3.1% (MS10), 3.3% (MS15), 3.3% (MS20), respectively. Moreover, high lattice integrity of the β-Si3N4 phase was observed, which can effectively confine O atoms into the β-Si3N4 lattice using MgO as a sintering additive. This result indicates that one-step sintering can provide a new route to prepare Si3N4 ceramics with a good combination of thermal conductivity and mechanical properties. 相似文献
4.
Wire arc additive manufacturing(WAAM)has been investigated to deposit large-scale metal parts due to its high deposition efficiency and low material cost.However,in the process of automatically manufacturing the high-quality metal parts by WAAM,several problems about the heat build-up,the deposit-path optimization,and the stability of the process parameters need to be well addressed.To overcome these issues,a new WAAM method based on the double electrode micro plasma arc welding(DE-MPAW)was designed.The circuit principles of different metal-transfer models in the DE-MPAW deposition process were analyzed theoretically.The effects between the parameters,wire feed rate and torch stand-off distance,in the process of WAAM were investigated experimentally.In addition,a real-time DE-MPAW control system was developed to optimize and stabilize the deposition process by self-adaptively changing the wire feed rate and torch stand-off distance.Finally,a series of tests were performed to evaluate the con-trol system's performance.The results show that the capability against interferences in the process of WAAM has been enhanced by this self-adaptive adjustment system.Further,the deposition paths about the metal part's layer heights in WAAM are simplified.Finally,the appearance of the WAAM-deposited metal layers is also improved with the use of the control system. 相似文献
5.
针对现有基于视频监控的人流量统计方案成本高、算法复杂且不利于个人隐私保护的局限性,利用毫米波雷达体积小、成本低、分辨率高的特点,提出了一种基于双时间点检测的人流量监测方法。该方法先获取人体目标散射点位置和多普勒频移信息来构成点云数据,然后根据多普勒频移正负来判断人体的运动方向,并筛选具有高多普勒频移值的点云数据以降低干扰点对聚类结果的影响;在双时间点对特定区域内人员数量进行统计,并根据双时间点之间所获取的点云数据聚类结果对所统计人员数据进行修正。实验结果表明,该方法能够用匿名的方式以较高的正确率统计人员进出。 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(54):22981-22992
In this study, a three-dimensional model was established using the lattice Boltzmann method (LBM) to study the internal ice melting process of the gas diffusion layer (GDL) of the proton exchange membrane fuel cell (PEMFC). The single-point second-order curved boundary condition was adopted. The effects of GDL carbon fiber number, growth slope of the number of carbon fibers and carbon fiber diameter on ice melting were studied. The results were revealed that the temperature in the middle and lower part of the gradient distribution GDL is significantly higher than that of the no-gradient GDL. With the increase of the growth slope of the number of carbon fiber, the temperature and melting rate gradually increase, and the position of the solid-liquid interface gradually decreases. The decrease in the number of carbon fibers has a similar effect as the increase in the growth slope of the number of carbon fibers. In addition, as the diameter of the carbon fiber increases, the position of the solid-liquid interface gradually decreases first and then increases. 相似文献
7.
8.
《International Journal of Hydrogen Energy》2022,47(72):30950-30958
Waste-to-hydrogen processes are a way to produce hydrogen from waste and reduce the amount of landfill/incineration of wastes simultaneously through the gasification of waste. The water-gas shift (WGS) reaction is a key step in this waste-to-hydrogen process by removing the CO and producing additional H2. A nanofiber-structured CoFe2O4 catalyst was synthesized by the electrospinning method, and the catalytic performance in WGS using waste-derived synthesis gas was compared with that of catalysts prepared by sol-gel, hydrothermal, and co-precipitation methods. The CoFe2O4 catalyst synthesized by the electrospinning method showed a clear nanofiber structure and revealed a superior redox property. This superior redox property, which has a large relation with the high oxygen storage capacity of the catalyst, induced the formation of an active phase (Co0 and Fe3O4) in CoFe2O4. As a result, the nanofiber structured oxygen defective CoFe2O4-x prepared by the electrospinning method showed the best catalytic activity in this study. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(4):2723-2734
To investigate the evaluation method of hydrogen compatibility of A286 superalloy in high pressure hydrogen gas, SSRT tests of hydrogen-charged specimens were conducted at ambient temperature at various strain rates. The relative reduction in area (RRA), one of the ductility parameters, was determined. The hydrogen content in the hydrogen-charged specimen was the same as the equilibrium hydrogen content on the specimen surface at 150 °C in 70 MPa hydrogen gas. The strain rate dependence of RRA was smaller than that of RRA obtained in 70 MPa hydrogen gas at 150 °C. All the hydrogen-charged specimens showed slip-plane fractures in the grains in their cores. However, the specimens in 70 MPa hydrogen gas at 150 °C showed fracture surfaces morphology ranging from dimples to quasi-cleavages and intergranular fractures with decreasing strain rate. These dissimilarities are expected to arise from differences in the hydrogen concentration behaviors of the specimens during the deformation process. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(69):29771-29780
Conjugated polymers have emerged as a promising class of organic photocatalysts for photocatalytic hydrogen evolution from water splitting due to their adjustable chemical structures and electronic properties. However, developing highly efficient organic polymer photocatalysts with high photocatalytic activity for hydrogen evolution remains a significant challenge. Herein, we present an efficient approach to enhance the photocatalytic performance of linear conjugated polymers by modifying the surface chemistry via introducing a hydrophilic adenine group into the side chain. The adenine unit with five nitrogen atoms could enhance the interaction between the surface of polymer photocatalyst and water molecules through the formation of hydrogen bonding, which improves the hydrophilicity and dispersity of the resulting polymer photocatalyst in the photocatalytic reaction solution. In addition, the strong electron-donating ability of adenine group with plentiful nitrogen atoms could promote the separation of light-induced electrons and holes. As a result, the adenine-functionalized conjugated polymer PF6A-DBTO2 shows a high photocatalytic activity with a hydrogen evolution rate (HER) of 25.21 mmol g?1 h?1 under UV-Vis light irradiation, which is much higher than that of its counterpart polymer PF6-DBTO2 without the adenine group (6.53 mmol g?1 h?1). More importantly, PF6A-DBTO2 without addition of a Pt co-catalyst also exhibits an impressive HER of 21.93 mmol g?1 h?1 under visible light (λ > 420 nm). This work highlights that it is an efficient strategy to improve the photocatalytic activity of conjugated polymer photocatalysts by the modification of surface chemistry. 相似文献