非常规气藏储层改造体积评价方法研究

为精确描述非常规气藏压裂后的复杂流动特征及定量评价储层改造体积（SRV），利用自主研发的缝网重构算法“破裂树生长法”建立压后缝网模型，并以此为基础提出了使用拟稳态流动时特定的压力等值线来确定SRV范围的定量评价方法，最后以长宁201井区为例进行了矿场实例分析。该方法根据微地震监测点的位置，重构出微裂缝网的连通关系。在复杂微裂缝网的基础上建立离散裂缝地质模型并进行生产数值模拟，根据数值模拟结果的压力分布精确划定SRV的范围。利用该方法计算出长宁201井区的SRV体积为0.052 1 km3，以该缝网模型的数值模拟产量预测结果符合实际生产规律，方法实用性较好。     

基于改进残差特征蒸馏的轻量级超分辨率网络

基于深度学习的图像超分辨率算法通常采用递归的方式或参数共享的策略来减少网络参数，这将增加网络的深度，使得运行网络花费大量的时间，从而很难将模型部署到现实生活中。为了解决上述问题，本文设计一种轻量级超分辨率网络，对中间特征的关联性及重要性进行学习，且在重建部分结合高分辨率图像的特征信息。首先，引入层间注意力模块，通过考虑层与层之间的相关性，自适应地分配重要层次特征的权重。其次，使用增强重建模块提取高分辨率图像中更精细的特征信息，以此得到更加清晰的重建图片。通过大量的对比实验表明，本文设计的网络与其他轻量级模型相比，有更小的网络参数量，并且在重建精度和视觉效果上都有一定的提升。     

Effect of support and reduction temperature in the hydrogenation of CO2 over the Cu–Pd bimetallic catalyst with high Cu/Pd ratio

Metal-support interaction and catalyst pretreatment are important for industrial catalysis. This work investigated the effect of supports (SiO₂, CeO₂, TiO₂ and ZrO₂) for Cu–Pd catalyst with high Cu/Pd ratio (Cu/Pd = 33.5) regarding catalyst cost, and the reduction temperatures of 350 °C and 550 °C were compared. The activity based on catalyst weight follows the order of Si > Ce > Zr > Ti when reduced at 350 °C. The reduction temperature leads to the surface reconstruction over the SiO₂, CeO₂ and TiO₂ catalysts, while results in phase transition over Cu–Pd/ZrO₂. The effect of reduction temperature on catalytic performance is prominent for the SiO₂ and ZrO₂ supported catalysts but not for the CeO₂ and TiO₂ ones. Among the investigated catalysts, Zr-350 exhibits the highest methanol yield. This work reveals the importance of the supports and pretreatment conditions on the physical-chemical properties and the catalytic performance of the Cu–Pd bimetallic catalysts.     

Numerical study of strain development in high-density polyethylene geomembrane liner system in landfills using a new constitutive model for municipal solid waste

Tensile strain development in high-density polyethylene (HDPE) geomembrane (GMB) liner systems in landfills was numerically investigated. A new constitutive model for municipal solid waste (MSW) that incorporates both mechanical creep and biodegradation was employed in the analyses. The MSW constitutive model is a Cam-Clay type of plasticity model and was implemented in the finite difference computer program FLAC?. The influence of the friction angle of the liner system interfaces, the biodegradation of MSW, and the MSW filling rate on tensile strains were investigated. Several design alternatives to reduce the maximum tensile strain under both short- and long-term waste settlement were evaluated. Results of the analyses indicate that landfill geometry, interface friction angles, and short- and long-term waste settlement are key factors in the development of tensile strains. The results show that long-term waste settlement can induce additional tensile strains after waste placement is complete. Using a HDPE GMB with a friction angle on its upper interface that is lower than the friction angle on the underlying interface, increasing the number of benches, and reducing the slope inclination are shown to mitigate the maximum tensile strain caused by waste placement and waste settlement.     

A novel 4D resolution imaging method for low and medium atomic number objects at the centimeter scale by coincidence detection technique of cosmic-ray muon and its secondary particles

The muon radiography imaging technique for high-atomic-number objects(Z) and large-volume objects via muon transmission imaging and muon multiple scattering imaging remains a popular topic in the field of radiation detection imaging. However, few imaging studies have been reported on low and medium Z objects at the centimeter scale. This paper presents an imaging system that consists of three layers of a position-sensitive detector and four plastic scintillation detectors. It acquires data by co...     

Microstructural and mechanical properties assessment of transient liquid phase bonding of CoCuFeMnNi high entropy alloy

The transient liquid phase (TLP) bonding of CoCuFeMnNi high entropy alloy (HEA) was studied. The TLP bonding was performed using AWS BNi-2 interlayer at 1050 °C with the TLP bonding time of 20, 60, 180 and 240 min. The effect of bonding time on the joint microstructure was characterized by SEM and EDS. Microstructural results confirmed that complete isothermal solidification occurred approximately at 240 min of bonding time. For samples bonded at 20, 60 and 180 min, athermal solidification zone was formed in the bonding area which included Cr-rich boride and Mn₃Si intermetallic compound. For all samples, the γ solid solution was formed in the isothermal solidification zone of the bonding zone. To evaluate the effect of TLP bonding time on mechanical properties of joints, the shear strength and micro-hardness of joints were measured. The results indicated a decrement of micro-hardness in the bonding zone and an increment of micro-hardness in the adjacent zone of joints. The minimum and maximum values of shear strength were 100 and 180 MPa for joints with the bonding time of 20 and 240 min, respectively.     

Acidification of the electrolyte during the galvanic corrosion of AA7075: A numerical and experimental study

The electrochemical interactions between aluminum alloy 7075 and low-carbon steels under gelled electrolytes were studied. Such electrolytes provided the opportunity to investigate both thick and thin electrolyte systems. The electrolyte was chemically modified to visually track the acidic fronts during the anodic reaction and the subsequent hydrolysis process. Two mathematical models were validated for both thick and ultrathin electrolytes. The acidification of thick electrolytes was extended some millimeters beyond the aluminum alloy surface, whereas the acidic front was localized next to the metallic joint using ultrathin electrolytes. The combination of both numerical and experimental results allows proving (and explaining why) that the acidification process is more aggressive under dilute than under concentrated electrolytes.     

一种植物油中苯并（a）芘含量测定的固相萃取前处理方法

为了建立一种准确性高、成本低的植物油中苯并(a)芘测定的样品前处理方法，基于GB 5009.7—2016以自制氧化铝柱为固相萃取柱，采用单因素试验对称样量、洗脱剂量、洗脱流速、吸附剂存放时间、吸附剂量这5个影响植物油中苯并（a）芘洗脱的因素进行研究，优化前处理条件，并对测定方法进行考察。结果表明：优化的前处理条件为称样量0.100 0 g、洗脱剂量120 mL、吸附剂（氧化铝）量22 g、洗脱流速1滴/2 s、吸附剂存放时间少于12周；方法检出限为0.2 μg/L，样品加标回收率为94.23%～100.00%，RSD为1.20%～7.36%；同一样品测定结果与SGS测定值接近，相对平均偏差为2.36%～3.50%。说明本试验方法测定结果准确，可应用于油脂企业植物油中痕量苯并（a）芘的测定。     

Reconstructed Water Oxidation Electrocatalysts: The Impact of Surface Dynamics on Intrinsic Activities

Electroreduction of small molecules such as H₂O, CO₂, and N₂ for producing clean fuels or valuable chemicals provides a sustainable approach to meet the increasing global energy demands and to alleviate the concern on climate change resulting from fossil fuel consumption. On the path to implement this purpose, however, several scientific hurdles remain, one of which is the low energy efficiency due to the sluggish kinetics of the paired oxygen evolution reaction (OER). In response, it is highly desirable to synthesize high-performance and cost-effective OER electrocatalysts. Recent advances have witnessed surface reconstruction engineering as a salient tool to significantly improve the catalytic performance of OER electrocatalysts. In this review, recent progress on the reconstructed OER electrocatalysts and future opportunities are discussed. A brief introduction of the fundamentals of OER and the experimental approaches for generating and characterizing the reconstructed active sites in OER nanocatalysts are given first, followed by an expanded discussion of recent advances on the reconstructed OER electrocatalysts with improved activities, with a particular emphasis on understanding the correlation between surface dynamics and activities. Finally, a prospect for clean future energy communities harnessing surface reconstruction-promoted electrochemical water oxidation will be provided.