High energy-storage performance of lead-free AgNbO3 antiferroelectric ceramics fabricated via a facile approach

AgNbO₃ lead free AFE ceramics are considered as one of the promising alternatives to energy storage applications. In the majority of studies concerning the preparation of AgNbO₃ AFE ceramics, an oxygen atmosphere is required to achieve high performance, increasing the complexity of the fabrication process. Herein, a facile approach to preparing AgNbO₃ ceramics in the ambient air was reported, in which the AgNbO₃ ultrafine powder with stable perovskite structure was synthesized by hydrothermal method instead of the conventional ball milling process, leading to a lower temperature of phase formation and thus smaller grain size. The resulting ceramics sintered at 940 °C displayed high breakdown strength (216 kV/cm) and a recoverable energy density of 3.26 J/cm³ with efficiency of 53.5 %. Also, the high thermal stability of recoverable energy density (with minimal variation of ≤20 %) and efficiency (≤ 10 %) over 30–150℃, enables AgNbO₃ ceramics achieved to be a promising candidate for energy storage applications.     

人造金刚石填充聚酰亚胺树脂基复合材料防刺性能

为研究树脂材料的防刺性能及防刺机制,利用手糊成型与热压法成型制备了手糊分层结构和均布结构层2种结构的人造金刚石填充聚酰亚胺树脂基复合树脂片,并探讨了人造金刚石粒径、填充体积分数对树脂片防刺性能的影响。研究结果表明:经过人造金刚石填充的聚酰亚胺树脂片的防刺性能得到提高,并且均布结构层分层复合结构的树脂片的防刺性能更好;随着人造金刚石粒径的减小,树脂片防刺性能出现先减小后增加的趋势,故防刺机制基本在于碰撞概率与树脂基的防挡;比较防刺力和消耗功发现,不同填充体积分数的单层防刺树脂片的防刺性能随人造金刚石填充体积分数的增加而逐渐降低,该趋势的成因在于复合树脂片的脆化与破坏;在颗粒等效粒径为300 μm、体积分数为10%时,其防刺性能最好。     

2种灰色模型在矿区地表沉陷预计中的适用性

目前矿区地表单点沉陷动态预计方法主要基于传统的水准测量数据,监测方法单一,成本高,观测点易破坏,不能保证地表形变信息的实时性,且采用灰色模型进行地表沉陷预计时只针对单一模型的应用,没有结合模型自身特点分析其适用性。以袁店二矿7221工作面为试验区域,采用合成孔径雷达差分干涉测量技术监测矿区地表沉陷量,分别建立了描述沉陷量与时间关系的GM(1,1)与灰色Verhulst模型进行地表沉陷量预计,实现了矿区地表沉陷监测与动态预计一体化。通过比较、分析GM(1,1)与灰色Verhulst模型对地表沉陷量的拟合及预计结果,得出了2种灰色模型在矿区地表沉陷预计中的适用性:在矿区开采沉陷开始至活跃前期,若地表单点沉陷量曲线呈近似单峰型,则宜采用GM(1,1)进行短期预计;当矿区地表沉陷进入衰退阶段,单点沉陷量曲线呈平底饱和状态,则宜采用灰色Verhulst模型进行中长期预计。     

无氟防水整理在化纤高密织物上的应用

采用无氟防水剂ECO ADV对化纤高密织物进行防水整理,优化的整理工艺为:无氟防水剂ECO ADV 50 g/L、防水增效剂XCR 10 g/L、三防整理渗透剂FN 5 g/L、焙烘温度170℃、车速40 m/min。化纤高密织物经无氟防水剂ECO ADV整理后再进行后整理加工(如涂层、贴合、复合等),色变小,防水性能稳定,且贴条强力较强,手感好,手抓白痕少。     

The impact of the ICT4D project on sustainable rural development using a capability approach: Evidence from Bangladesh

Information and Communication Technology for Development (ICT4D) projects have shown a great promises in recent years. However, simply materializing of ICT4D projects is not enough for minimizing the prevalent digital divide in rural areas in developing countries. For the success of an Information and Communication Technology (ICT) intervention, it is important to consider the capabilities of users, who are responsible for converting ICT resources into outcome. While most of the ICT-related studies are focused on the adoption of actual technologies and influences of different internal and external factors on intervention outcomes, very few studies are focused on evaluating intervention outcomes and redesigning intervention strategies. In this study, I opted for using a conceptual framework following the Capability Approach that simultaneously identifies the influence factors for intervention outcome as well as evaluates the outcome based on Noble Laureate Amartya Sen’s five freedoms concept. A qualitative technique has been chosen to conduct the study. As part of the impact evaluation of an ICT4D intervention, a project known as Union Digital Centres (UDCs) in Bangladesh was selected. A total of ten themes are identified indicating that the outcome of the intervention is contributing to socio-economic and human development. However, the study has revealed that lack of capabilities of users (e.g. prior knowledge and financial inability) bar the UDC programs to fulfill their goals at highest level. This study would practically help the UDC policy makers to adjust the UDC intervention design by addressing the shortcomings of the users to yield higher UDC program outcome. Additionally, this study theoretically contributes in ICT adoption literature by showing that there is a mutual influence between users’ capabilities and ICT-related project outcomes. Finally, using specific case study (ICT4D project in Bangladesh), this study contextualizes Amartya Sen’s five freedoms concept in the ICT-specific context.     

An Artificial Skyrmion Platform with Robust Tunability in Synthetic Antiferromagnetic Multilayers

Magnetic skyrmions are topologically nontrivial spin structures, and their existence in ferromagnetically coupled multilayers has been widely reported with a disordered arrangement. Here, a nucleation scenario of ordered skyrmions in nanostructured synthetic antiferromagnetic (SAF) multilayers is proposed and experimentally demonstrated using direct magnetization imaging, indirect magnetometer and magnetoresistance measurement, and micromagnetic simulation. Instead of relying on Dzyaloshinskii–Moriya interaction, the antiferromagnetic interlayer exchange coupling in the SAF multilayers fulfills the role of nucleation and stabilization of skyrmions. The robustness of the proposed skyrmion nucleation scenario is examined against temperature from 4.5 to 300 K and device size from 400 to 1200 nm. Interestingly, these synthetic skyrmions still behave well with a size less than 100 nm. The higher stability than generic magnetic domains can be attributed to topological protection. The results thus provide an artificial skyrmion platform to meet the functional needs of high density and designable arrangement in magnonic and spintronic applications.     

饮料中柠檬黄的测定能力验证情况分析

目的了解和评价全国食品检验系统实验室对人工合成着色剂柠檬黄的检测能力,促进各参加实验室在人工合成着色剂检测方面能力的提高。方法在全国食检系统内组织开展饮料中柠檬黄的测定能力验证项目。制备阳性及空白考核样品,完成均匀性稳定性实验,确保样品满足能力验证发样要求,向167家参加实验室随机发放样品,并在规定时间内回收有效数据,采用稳健(Robust)统计进行分析并给出结论。结果在反馈结果的163家实验室中,16家实验室的检测结果为不满意,8家实验室的检测结果为可疑,139家实验室的检测结果为满意,满意率为85.3%。结论本次能力验证活动中,85.3%的满意率表明绝大部分实验室具备饮料中柠檬黄的检测能力。但依然存在部分实验室的评价结果为可疑或不满意的情况,应分析原因并进一步提高实验室的检测能力。     

基于数字单元法的三维正交织物微观几何结构建模

为了反映织物内部纱线的空间构型和微观几何结构,针对在织物建模过程中,因忽略纤维间的相互作用而引起的纱线截面形状变化的问题,基于数字单元法理论,提出了一种计算纤维间摩擦力的方法。通过纱线纤维化离散,用数值模拟和仿真方法模拟三维正交织物成型过程,建立了5种精度递进的微观几何结构数值模型。5种模型中的每根纱线分别由4、7、12、19和37根数字纤维表征。研究结果表明:随着纱线纤维化离散程度的提高,仿真时间延长,织物厚度减小,纤维体积分数增大,节点平均作用力下降速度变缓,势能变小;当每根纱线由19根数字纤维组成时,所建织物的微观几何结构数值模型与真实织物样本在显微镜下的内部切片图像较为吻合。     

基于模糊综合评判方法的水文地质类型评价

以开元矿井为例,在水文地质资料基础上,选定合适的指标,根据不同指标的重要程度确定各个指标权重,运用模糊综合评判理论建立矿井水文地质类型划分模型,运用该模型进行水文地质类型评价。