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Liu Yang Pengfei Yu Wenyuan Li Fengliang Cao Xin Jin Sheng Xue Xianglong Zhang Tingwei Zhang Mingbo Wu Wenting Wu 《American Institute of Chemical Engineers》2022,68(9):e17760
Hydrogen peroxide (H2O2) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H2O2 is hard to timely decomposed into O2 and H2O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H2O2 decomposition, and Co core further enhance this decomposition. Benefiting from it, the H2O2 decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O2 generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H2O2 with little deep oxidation and protect the process of H2O2 utilization to achieve a safer world. 相似文献
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大规模多输入多输出(Multiple-Input Multiple-Output, MIMO)可以有效提升5G SA网络的上行链路数据传输速率以及可靠性。针对5G SA网络上行链路速率和覆盖不均衡的情况,提出了基于大规模MIMO的分组算法,将发送信号矢量进行分组,组内采用最大似然检测,组外采用基于正交三角分解(QR分解)的干扰消除检测,并且结合5G频谱的叠加策略,在降低算法复杂度的同时,有效提升网络覆盖和速率。通过5G SA现网实测,通过MIMO降低分组数量能够提升分组检测性能,结合上行低频段频谱叠加策略能够有效提升5G SA网络上行覆盖30%,提升5G SA网络上行平均速率40%~80%,特别是弱覆盖边缘的网络速率,最高可达600%。 相似文献
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《International Journal of Hydrogen Energy》2022,47(52):22203-22214
The gas purging states affect electricity output and energy storage capacity of unitized regenerative fuel cells. In this study, a model of unitized regenerative fuel cell is established. Cell voltages and operating temperatures influences on the dynamic distribution of thermal fluid during purging process and the discharge of residual liquid water in electrolytic cell mode are investigated. The motivation of the present study is better understanding the gas purging characteristics and its effect on reaction behaviors of unitized regenerative fuel cells. Simulation results reveal a significant influence of purging gas temperature on the water flooding and a great effect of operating voltage on the water diffusion. The operating temperature of electrolytic cell model almost has little effect on purging results at different cell temperature and the same purging gas temperature. When the purging gas temperature is changed, higher temperatures of cell and purging gas facilitate liquid water discharging out from the cell regions. In cell water flooding situation, when having large liquid content, the purging gas has little effects on the water expelling process. 相似文献
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《International Journal of Hydrogen Energy》2022,47(78):33272-33281
According to the International Energy Agency, only a small part of the full potential of biomass energy is currently used in the world. The annual amount of agricultural waste in the Russian Federation is estimated at about 152 million tons, and the energy potential of animal waste is 201 PJ/year. Anaerobic digestion is an efficient method of converting organic waste into renewable energy sources. Previously, the positive effect of pretreatment of various organic feedstocks in vortex layer apparatus (VLA) on the characteristics of anaerobic digestion and energy efficiency was shown. Currently, there is a significant interest in the world in obtaining biohydrogen from organic waste using the dark fermentation (DF) process. During pretreatment in the VLA, the iron working bodies are abraded and iron particles are introduced into the feedstock of the DF reactor. This may have a positive effect on the production rate and yield of hydrogen, which has not been previously studied. This work is aimed at evaluating the possibility of using the VLA as a method for pretreatment of a dark fermentation feedstock for the intensification of biohydrogen production. To achieve this goal, an experimental setup was constructed. It consisted of a 45 L DF reactor, a VLA and a process control system to collect data on the DF process parameters every 5 min. At a hydraulic retention time in the DF reactor of 24 h and in the VLA of 30 s, the hydrogen content in the biogas increased from 51.1% to 52.2%. At the same time, the pH increased from 3.85 to 4.8–4.9, and the hydrogen production rate increased by 16% to 1.941 L/(L day). The hydrogen yield was 80.9 ml/g VS. Thus, pretreatment of the feedstock in VLA can be an effective way to intensify the DF process; however, further study of the VLA operating modes is required in order to optimize the concentrations of iron particles introduced into the feedstock for the most efficient continuous production of dark fermentative biohydrogen. 相似文献
7.
Flow phenomena of three-dimensional conducting Casson fluid through a stretching sheet are proposed in the present investigation with the impact of the magnetic parameter in a permeable medium. The adaptation of particular transformations is useful to modify the governing equations into their nondimensional as well as the ordinary form. However, these transformed equations are nonlinear and approximate analytical methods for the solution of the complex form of governing equations. In particular, the Adomian decomposition method is proposed for the solution. The behavior of several variables, such as the magnetic and porous matrix, on the flow profile as well as the rate of shear stress, are discussed via graphs and tables. The conformity of the current result with the earlier study shows a road map for further investigation. The major concluding remarks are; the retardation in the velocity distribution is rendered due to an increase in the Casson parameter moreover, the Casson parameter favors in reducing the rate of shear stress coefficient in magnitude. 相似文献
8.
《International Journal of Hydrogen Energy》2022,47(29):13815-13827
Partial gasification of coal char was conducted with addition of metal oxides for co-production of fuel gas and methane decomposition catalysts. Effect of the metal composition (Ni, Co and Fe based mono- or bi-metals) was investigated on the fuel gas production and the resultant catalyst surface and textural properties, morphology and performance in catalytic methane decomposition (CMD). Besides H2-rich fuel gas production (the combustion energy up to 11.03–23.42 MJ/kgchar) from the gasification, the gasification residue can directly serve as the effective and efficient catalyst for CMD. The Fe and Fe–Co composite oxides were found to be better among the mono- and bi-metallic oxides for the fuel gas production during the gasification, respectively. The Ni-based mono-/bi-metallic catalysts could display high and stable methane conversion (up to 80%) during the 600-min CMD test at 850 °C. Promotional role of the second metal in CMD was discussed on the carbon diffusion, metal mobility and reducibility, formation and growth of the deposited carbons. The formed carbon morphology after CMD was analyzed based on the Kirkendall effect and Tammann temperature and further correlated to the potential catalyst deactivation. 相似文献
9.
《Mechatronics》2022
This paper considers the shared path following control of an unmanned ground vehicle by a single person. A passive measure of human intent is used to blend the human and machine inputs in a mixed initiative approach. The blending law is combined with saturated super-twisting sliding mode speed and heading controllers, so that exogenous disturbances can be counteracted via equivalent control. It is proven that when the proposed blending law is used, the combined control signals from both the human and automatic controller respect the actuator magnitude constraints of the machine. To demonstrate the approach, shared control experiments are performed using an unmanned ground vehicle, which follows a lawn mower pattern shaped path. 相似文献
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