Low-temperature water–gas shift reaction over supported Cu catalysts

The low-temperature water–gas shift (WGS) reaction has been carried out at a very high gas hourly space velocity (GHSV) of 36,201 h⁻¹ over supported Cu catalysts prepared by an incipient wetness impregnation method. The preparation method was optimized to get a highly active CeO₂ supported Cu catalyst for low-temperature WGS. Co-precipitated Cu–CeO₂ exhibited excellent catalytic performance as well as 100% CO₂ selectivity. The high activity and stability of co-precipitated Cu–CeO₂ catalyst is correlated to its easier reducibility, high surface area and the nano-sized CeO₂ with CuO species interacting with the support.     

An Algorithm for Reducibility of 3-arrangements

We consider a central hyperplane arrangement in a three-dimensional vector space.The definition of characteristic form to a hyperplane arrangement is given and we could make use of characteristic form to judge the reducibility of this arrangement.In addition,the relationship between the reducibility and freeness of a hyperplane arrangement is given.     

Molecular design and characterization of catalysts for NO x selective reduction by hydrocarbons in the oxygen excess based upon ultramicroporous zirconia pillared clays

Approaches to design of zirconia pillared clays via control of the properties of pillaring species in solutions were elaborated. Structural features of pillars and Pt + Cu active components fixed at these nanoparticles were shown to determine catalytic properties of pillared clays in NO_x selective reduction by hydrocarbons in the oxygen excess.     

Kalimullin Pairs of §02 w-Enumeration Degrees

We study the notion of K-pairs in the local structure of the w-enumeration degrees. We introduce the notion of super almost zero sequences and investigate their structural properties.     

ZHS添加剂对济(源)钢烧结矿性能的影响

通过对济源钢铁公司烧结矿添加ZHS添加剂的系列试验，着重研究了ZHS添加剂对烧结矿转鼓指数，还原性，低温还原粉化率及熔滴性能的影响，试验表明，ZHS添加剂对改善烧结矿冶金性能具有良好效果，为改善济（源）钢烧结矿质量提供了新的途径。     

Locally random reductions: Improvements and applications

A (t, n)-locally random reduction maps a problem instancex into a set of problem instancesy ₁,...,y _n in such a way that it is easy to construct the answer tox from the answers toy ₁,...,y _n, and yet the distribution ont-element subsets ofy ₁,...,y _n depends only on |x|. In this paper we formalize such reductions and give improved methods for achieving them. Then we give a cryptographic application, showing a new way to prove in perfect zero knowledge that committed bitsx ₁,...,x _m satisfy some predicateQ. Unlike previous techniques for such perfect zero-knowledge proofs, ours uses an amount of communication that is bounded by a fixed polynomial inm, regardless of the computational complexity ofQ. These results were presented in preliminary form at the 10th Annual Crypto Conference, Santa Barbara, CA, August 1990. The work of D. Beaver was done at Harvard University, supported in part by NSF Grant CCR-870-4513. The work of J. Kilian was done at MIT and Harvard University, supported by an NSF postdoctoral fellowship.     

含碳冷固结团矿还原性测定方法探讨

含碳冷固结团矿与天然铁矿石、烧结矿、氧化球团矿不同、其还原性不能用减量法直接测定，需要根据还原后试样的化学成分计算获得，或根据试样中碳量的变化和试样的减量计算获得，但还原速率指数无法得到，本文以沙城铁厂试样为例进行了说明。     

铁矿石冶金性能实验方法的改进

在不影响实验结果的前提下，对铁矿石的还原度实验方法进行改进。改进后每个实验时间缩短3～4．5h，且大大降低了实验成本。     

Kinetics of oxidative cracking of n‐hexane to olefins over VOx/Ce‐Al2O3 under gas phase oxygen‐free environment

The kinetics of oxidative cracking of n‐hexane to olefins using lattice oxygen of VO_x/Ce‐Al₂O₃ is investigated. The TPR/TPO analysis shows a consistent reducibility (79%) of VO_x/Ce‐Al₂O₃ in repeated redox cycles. The total acidity of the sample is found to be 0.54 mmol/g with 22% are strong acid sites that favors olefin selectivity. The oxidative cracking of n‐hexane in a fluidized CREC Riser simulator gives approximately 60% olefin selectivity at 30% n‐hexane conversion. A kinetic model is developed considering (1) cracking, (2) oxidative dehydrogenation (ODH), and (3) catalyst deactivations. The proposed cracking mechanism considers adsorption, C–H and C–C bond fission and desorption as elementary steps and implemented by pseudo steady state hypothesis. A Langmuir‐Hinshelwood mechanism is found to represent the ODH reactions. The developed model fits the experimental data with favorable statistical indicators. The estimated specific reaction rate constants are also found to be consistent with the product selectivity data. © 2016 American Institute of Chemical Engineers AIChE J, 63: 130–138, 2017     

ACr_2O_4尖晶石氧化物(A=Co,Zn,Mn,Cu)上二氯甲烷的催化燃烧:A位阳离子的影响

采用溶胶-凝胶法制备4种不同ACr_2O_4尖晶石氧化物(A=Co,Zn,Mn,Cu),考察A位阳离子对ACr_2O_4尖晶石氧化物的性质以及对二氯甲烷催化燃烧性能的影响,并对催化剂进行SEM、HRTEM、H_2-TPR、NH_3-TPD以及XPS等表征。结果表明,A位离子显著影响催化剂的可还原性和表面酸性,催化剂催化活性顺序为CoCr_2O_4Zn Cr_2O_4Mn Cr_2O_4CuCr_2O_4。结合表征结果,认为催化剂活性与其可还原性能和表面酸性存在密切关系。CoCr_2O_4由于具有最佳的可还原性和较高的表面酸性,具有最高的催化活性;而CuCr_2O_4由于具有最低的表面酸性导致其催化活性最低。