首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   7879篇
  免费   589篇
  国内免费   335篇
电工技术   619篇
综合类   374篇
化学工业   1346篇
金属工艺   730篇
机械仪表   455篇
建筑科学   145篇
矿业工程   148篇
能源动力   222篇
轻工业   841篇
水利工程   29篇
石油天然气   186篇
武器工业   90篇
无线电   895篇
一般工业技术   747篇
冶金工业   325篇
原子能技术   173篇
自动化技术   1478篇
  2024年   10篇
  2023年   132篇
  2022年   187篇
  2021年   239篇
  2020年   225篇
  2019年   191篇
  2018年   160篇
  2017年   227篇
  2016年   244篇
  2015年   219篇
  2014年   410篇
  2013年   405篇
  2012年   552篇
  2011年   698篇
  2010年   568篇
  2009年   629篇
  2008年   558篇
  2007年   583篇
  2006年   506篇
  2005年   377篇
  2004年   323篇
  2003年   260篇
  2002年   221篇
  2001年   132篇
  2000年   106篇
  1999年   80篇
  1998年   71篇
  1997年   46篇
  1996年   53篇
  1995年   68篇
  1994年   63篇
  1993年   42篇
  1992年   33篇
  1991年   43篇
  1990年   24篇
  1989年   26篇
  1988年   25篇
  1987年   11篇
  1986年   7篇
  1985年   6篇
  1984年   9篇
  1983年   3篇
  1982年   2篇
  1981年   7篇
  1980年   8篇
  1979年   6篇
  1978年   2篇
  1977年   3篇
  1973年   1篇
  1968年   1篇
排序方式: 共有8803条查询结果,搜索用时 15 毫秒
1.
A double pyrovanadate CaMgV2O7 sample was synthesized via a facile solid-state route under an air atmosphere. The nonequilibrium formation pathways of the CaMgV2O7 were investigated via powder X-ray diffraction. A multistep reactions path (metavanadates–pyrovanadates–double pyrovanadate CaMgV2O7) was proposed to describe the formation of the CaMgV2O7 considering the thermodynamic and kinetic factors. The cell unit parameters of the CaMgV2O7 sample indicated the crystallization according to a monoclinic system with space group P12/c1(14), and the lattice parameters of a = 6.756 Å, b = 14.495 Å, c = 11.253 Å, β = 99.12, and V = 108.806 Å3. X-ray photoelectron spectroscopy also confirmed the +5 oxidation state vanadium in CaMgV2O7. The endothermic effects at 1033 and 1143 K were related to the incongruent melting and liquidus temperatures of CaMgV2O7, respectively. The comprehensive thermodynamic properties of CaMgV2O7 were established in both low- and high-temperature regions, utilizing a physical property measurement system and multi-high-temperature calorimetry (96 lines). The heat capacity (200 J mol K−1) and entropy (198 J mol K−1) at 298.15 K were computed based on the low-temperature heat capacity values, and the enthalpy of formation at 298.15 K was also estimated. The fitted high-temperature capacity can be used to obtain the changes in the enthalpy, entropy, and Gibbs free energy. This study is part of building a reliable thermodynamic database of the CaO–MgO–V2O5 system.  相似文献   
2.
鄂尔多斯盆地三叠系延长组7段(长7段)泥页岩发育,针对其内部富集的页岩型页岩油尚未取得勘探进展,仅在少量直井的试油阶段突破出油关,但试采效果整体较差。系统梳理了长7段3亚段(长73亚段)泥页岩的岩石学、地球化学和储层特征,优选页岩型页岩油的富集有利参数,明确了其成藏条件、勘探方向及潜力。相较于暗色泥岩,长73亚段的黑色页岩表现为多类型纹层频繁发育、有机质丰度高、生油母质类型好、主生烃期早、含油率高的特征,是页岩型页岩油勘探的有利岩性。受水平页理缝和陆源长英质、凝灰质等相对高孔高渗纹层的复合影响,黑色页岩的水平渗透率普遍高于垂直渗透率。长73亚段泥页岩的储集空间以刚性矿物支撑的粒间孔、粒内溶蚀孔、黏土矿物晶间孔及黄铁矿晶间孔为主,页理缝和超压微裂缝较发育。"有机质+陆源长英质纹层"、"有机质+凝灰质纹层"二元纹层组合与页理缝构成的复合单元对页岩油赋存最为有利。总有机碳(TOC)含量为4%~14%、镜质体反射率Ro>0.8%、页理及纹层发育、脆性矿物含量高的长英质黑色页岩是长73亚段页岩型页岩油的有利勘探目标,黑色页岩厚度相对较大、有机质丰度适中的马岭—华池深洼区是页岩型页岩油勘探的Ⅰ类有利区。鄂尔多斯盆地长73亚段页岩型页岩油资源丰富,有望成为盆地非常规石油勘探开发的现实性重大战略接替新领域。  相似文献   
3.
针对高强铝合金航空复杂构件室温成形难问题,通过电阻炉加热及冲压成形试验探究了温热条件对7B04铝合金硬度及成形性能的影响规律,通过差示扫描量热仪及透射电镜探讨其性能变化机理。研究结果表明:7B04铝合金加热后,升温速率越快,材料硬度下降越快;在400 ℃以上炉温条件下加热较长时间,硬度会先降后升;在200~450 ℃温度范围内,7B04板材冲压成形性能随出炉温度提高而提高,加热至400 ℃以上出炉冲压成形效果较好,升温速率的提高可以使7B04铝合金在硬度降幅相同的情况下,达到更高的成形温度,获得更好的成形性能。  相似文献   
4.
SnO2-coated TiNb2O7 powders were synthesized via the solution coating method in the present research. The SnO2 layers with a thickness of 3–5 nm were homogeneously coated on the surface of TiNb2O7 particles. TiNb2O7 coated with SnO2 of 5 mol% with high Li+ diffusion coefficient delivered the discharge capacity of 319.5 mAh/g, which was 6.6% higher than that of the non-coated samples. The enhancement of capacity for the coated TiNb2O7 was owing to the low charge-transfer resistance of 17.5 Ω in contrary to the non-coated TiNb2O7 (27.8 Ω). SnO2-coated TiNb2O7 possessed an improved capacity retention of 85.2% at 5 C after 100 cycles, superior to the non-coated TiNb2O7 (79.8%). On the other hand, the excessive amounts of SnO2 coating led to the reduction in the capacity of the prepared samples. The excessive amounts of SnO2 layers suppressed the Li+ diffusion and increased the charge-transfer resistance. The obtained results in this study indicated that coating of TiNb2O7 with appropriate amounts of SnO2 significantly improved the electrochemical performance of TiNb2O7.  相似文献   
5.
In the present investigation, systematic grinding experiments were conducted in a laboratory ball mill to determine the breakage properties of low-grade PGE bearing chromite ore. The population balance modeling technique was used to study the breakage parameters such as primary breakage distribution (Bi, j) and the specific rates of breakage (Si). The breakage and selection function values were determined for six feed sizes. The results stated that the breakage follows the first-order grinding kinetics for all the feed sizes. It was observed that the coarser feed sizes exhibit higher selection function values than the finer feed size. Further, an artificial neural network was used to predict breakage characteristics of low-grade PGE bearing chromite ore. The predicted results obtained from the neural network modeling were close to the experimental results with a correlation of determination R2 = 0.99 for both product size and selection function.  相似文献   
6.
目的 以分离纯化的大豆7S球蛋白为实验材料,研究脉冲强光处理对大豆7S球蛋白理化特性、分子结构等变化及潜在致敏性的影响。方法 采用高剪切分散乳化机、激光粒度仪、圆二色谱、荧光分光光度计、紫外分光光度计、酶联免疫试剂盒探究7S球蛋白理化、结构及潜在致敏性的变化。结果 与对照相比,脉冲强光处理能够提高大豆7S球蛋白的溶解性、乳化活性及乳化稳定性,降低蛋白的平均粒径;二级结构中α-螺旋下降,β-折叠上升,荧光强度显著下降(P<0.05),表面疏水性显著增加(P<0.05),紫外吸光强度增加;采用酶联免疫技术测定大豆7S球蛋白抗原抑制率,能量700J时其抑制率最低为46.13%,这可能是因为脉冲强光处理影响大豆7S球蛋白的构象。结论脉冲强光处理能够改善大豆球蛋白的理化特性,且通过其构象的变化影响其潜在致敏性,为脉冲强光在低致敏大豆蛋白食品中的应用提供一定的理论参考。  相似文献   
7.
赵文武  周海静  黄雁  王秀文  郝斌  刘剑 《化工进展》2022,41(11):5843-5849
采用高温固相反应法制备了一系列镝离子掺杂Bi2ZnB2O7(BZBO)光催化剂。通过XRD、TEM和HRTEM等手段对BZBO: xDy3+材料的结构及形貌等进行了表征,通过RhB溶液在紫外灯下的光降解实验研究了不同浓度镝离子掺杂对BZBO光催化性能的影响。RhB光降解实验结果表明,当Dy3+在BZBO中的掺杂量为4%时,BZBO: 4%Dy3+具有最好的光降解活性,其光降解活性为纯BZBO的1.56倍。通过光吸收性能分析可知,Dy3+的引入增强了BZBO的紫外吸收强度,并稍降低了其禁带宽度。光吸收性能、光致发光光谱、光电流和EIS实验结果表明,BZBO: 4%Dy3+的光催化活性增强的主要原因是BZBO中掺杂的镝不仅提高了BZBO光催化剂的光吸收能力,更促进了光生电子-空穴对的分离和转移。因此,在稀土元素和极化电场的作用下,BZBO: 4%Dy3+的光催化活性要高于其他所制备的样品。  相似文献   
8.
Endoplasmic reticulum (ER) stress response is an adaptive program to cope with cellular stress that disturbs the function and homeostasis of ER, which commonly occurs during cancer progression to late stage. Late-stage cancers, mostly requiring chemotherapy, often develop treatment resistance. Chemoresistance has been linked to ER stress response; however, most of the evidence has come from studies that correlate the expression of stress markers with poor prognosis or demonstrate proapoptosis by the knockdown of stress-responsive genes. Since ER stress in cancers usually persists and is essentially not induced by genetic manipulations, we used low doses of ER stress inducers at levels that allowed cell adaptation to occur in order to investigate the effect of stress response on chemoresistance. We found that prolonged tolerable ER stress promotes mesenchymal–epithelial transition, slows cell-cycle progression, and delays the S-phase exit. Consequently, cisplatin-induced apoptosis was significantly decreased in stress-adapted cells, implying their acquisition of cisplatin resistance. Molecularly, we found that proliferating cell nuclear antigen (PCNA) ubiquitination and the expression of polymerase η, the main polymerase responsible for translesion synthesis across cisplatin-DNA damage, were up-regulated in ER stress-adaptive cells, and their enhanced cisplatin resistance was abrogated by the knockout of polymerase η. We also found that a fraction of p53 in stress-adapted cells was translocated to the nucleus, and that these cells exhibited a significant decline in the level of cisplatin-DNA damage. Consistently, we showed that the nuclear p53 coincided with strong positivity of glucose-related protein 78 (GRP78) on immunostaining of clinical biopsies, and the cisplatin-based chemotherapy was less effective for patients with high levels of ER stress. Taken together, this study uncovers that adaptation to ER stress enhances DNA repair and damage tolerance, with which stressed cells gain resistance to chemotherapeutics.  相似文献   
9.
为了突破铝合金表面等离子喷涂热防护涂层结合强度低的技术瓶颈,采用三阴极等离子喷涂系统,在7A04-T6超高强铝合金基材表面制备了8YSZ热防护涂层,借助扫描电镜、X射线衍射仪、显微硬度计及万能力学试验机,分析表征了不同气体流量参数对涂层显微形貌、物相组成、显微硬度及结合强度的影响,并提出了气体流量参数对涂层结合强度影响的临界值。研究结果表明:不同的气体流量参数下制备的涂层上表面均存在着熔融及半熔融的粉末粒子形貌、不同尺寸的孔隙结构及不同程度的裂纹扩展形貌。伴随着气体流量的增加,涂层的致密度增加,涂层的夯实形貌则呈现先增加后减少的变化趋势。不同气体流量参数下制备的涂层的物相结构与喂料粉末基本一致,都仅存在单一成分的Zr0.92Y0.08O1.96组元。伴随着气体流量参数的增大,涂层的平均显微硬度呈现逐渐增大的变化趋势,涂层的平均结合强度呈现先增大后减小的变化趋势。  相似文献   
10.
Flexible scintillating fiber plays an important role in X-ray radiation monitoring and high-resolution medical imaging, while construction of scintillating fiber derived from the commercial material system meet with limited success. Here, we report the design and successful fabrication of the Ce-activated lutetium aluminum silicate glass, nanostructured glass, and fiber, and explore their scintillating properties. The scintillating glass with optimized composition and optical properties is determined. The crystallization behavior of lutetium aluminum silicate glass is studied and the nanostructured glass embedded with orthorhombic Lu2Si2O7 phase is successfully constructed for the first time. Importantly, the crystalline layer thickness of the nanostructured glass can be finely tuned and ~172.89% enhancement in the scintillating performance can be achieved. Furthermore, the fiber with large sized core is fabricated and its radiation response properties are tested. The results show that it exhibits high sensitivity and its scintillating emission is lineally dependent on the X-ray power, indicating the potential application for radiation detection.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号