Development and characterisation of a Y2Ti2O7-based glass-ceramic as a potential oxidation protective coating for titanium suboxide (TiOx)

A silica-based glass-ceramic, with Y₂Ti₂O₇ as the major crystalline phase, is designed, characterised and tested as an oxidation-protective coating for a titanium suboxide (TiO_x) thermoelectric material at temperatures of up to 600 °C. The optimised sinter-crystallisation treatment temperatures are found to be 1300 °C and 855 °C for a duration of 30 min, and this treatment leads to a glass-ceramic with cubic Y₂Ti₂O₇ and CaAl₂Si₂O₈ as crystalline phases. An increase of ~270 °C in the dilatometric softening temperature is observed after devitrification of the parent glass, thus further extending its working temperature range.Excellent adhesion of the glass-ceramic coating to the thermoelectric material is maintained after exposure to a temperature of 600 °C for 120 h under oxidising conditions, thus confirming the effectiveness of the T1 glass-ceramic in protecting the TiO_x material.     

Improvement of sludge electrodewatering by anode flushing

An improvement of the sludge electrodewatering process is proposed: anode flushing by filtrate recirculation. According to this technique, the mixture of filtrates obtained at cathode and anode sides is used for continuous flushing of the anode chamber of the filter press during electrodewatering. Anode flushing aims to eliminate essential problems of electrodewatering: ohmic heating, rise of electric energy consumption, electrode corrosion, and filtrate contamination. This is attained by better control of the filtrate pH, the filter cake temperature, and the dryness at the anode side, where the physicochemical conditions are most aggressive. The efficiency of the proposed technique is evaluated at lab scale on drilling sludge electrodewatering with and without anode flushing. In experiments without anode flushing, increasing electric current density caused strong increase of anode temperature, desiccation of the filter cake at the anode side, rise of voltage, and significant alkaline contamination of filtrate. The application of anode flushing allowed controlling the electric field strength and temperature. Thus, the dewatering of the sludge has been extended at high electric field without damaging the filter equipment by drastic heating. Furthermore, it reduced filtrate contamination by neutralization of the electrolysis products.     

Linear amphiphilic diblock copolymers of lactide and 2-dimethylaminoethyl methacrylate using bifunctional-initiator and one-pot approaches

Linear amphiphilic diblock copolymers of polylactide (PLA) and poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) were synthesized by atom transfer radical polymerization (ATRP) of DMAEMA followed by ring-opening polymerization (ROP) of LLA using the bifunctional initiator, 2′-hydroxyethyl 2-bromoisobutyrate. NMR showed that the resulting PLA block was racemic and a quaternization/precipitation technique showed that there were significant amounts of racemic PLA homopolymer. In addition, simultaneous ATRP of DMAEMA and ROP of l-lactide by tin octoate were conducted at varied temperatures, indicating 90 °C as a suitable compromise temperature; this one-pot process also led to racemization and P(L)LA homopolymer. The racemization was attributed to reversible deprotonation of LLA by the N(CH₃)₂ moiety of (P)DMAEMA and the PLA homopolymer impurity was related to in situ formation of lactoyl lactate (LA–LA) due to nucleophilic ring opening of lactide by the amino moieties of (P)DMAEMA. The methods presented can be useful for the preparation of PDMAEMA–b–PLA/PLA composites in a two-step process or in a single step, one-pot process.     

Analysis of the effects of main design parameters variation on the vibration characteristics of a vehicle sub-frame

In the design process of an automobile part, several analysis methods are usually used to evaluate the performance of the part. However, most automobile design engineers do not directly use CAE (computer aided engineering) tools since specific skills are required to obtain practical results. Moreover, CAE requires a huge amount of computation time and cost. To resolve these problems, a new design approach, termed first order analysis (FOA), has been proposed. In this paper, the FOA technique is employed to design a vehicle sub-frame. An equivalent model of the vehicle subframe which only consists of beam elements is proposed and the modal properties obtained with the model are compared to those obtained with a full scale finite element model. The effects of some parameter variations on the modal characteristics of the vehicle sub-frame are investigated by employing the FOA equivalent model. This paper was presented at the 4th Asian Conference on Multibody Dynamics(ACMD2008), Jeju, Korea, August 20–23, 2008. Hong Hee Yoo graduated from the Department of Mechanical Design and Production Engineering at Seoul National University in 1980 and received his Master’s degree from the same department in 1982. He received his Ph.D. degree in 1989 from the Department of Mechanical Engineering and Applied Mechanics at the University of Michigan at Ann Arbor, U.S.A. He is currently working as a professor in the School of Mechanical Engineering in Hanyang University, Seoul, Korea.     

The geographical distribution of plantation forests and land resources potentially available for pine plantations in the U.S. South

In this paper, we provide an assessment of plantation forests and private land resources potentially available for pine plantation development in 11 southern states of the United States. After a sustained growth for 50 years, plantation forests (softwood and hardwood on both private and public lands) amounted to 18 million ha or 24 percent of all timberlands in these states in 2007. The vast majority of the plantation forests were established on private lands with fast-growing loblolly pines and slash pines. While purposeful hardwood plantations were rare, there were hardwood stands growing on failed pine plantation sites. Using a two-stage Markov land use transition model, we forecast that private forest land in these states will decline about 7 percent or from 66 million ha in 1997 to 61 million ha in 2027, primarily due to urbanization, and that private pine plantations will rise nearly 40 percent from 11 million ha to 16 million ha. Further, growth in pine plantations will decline in coming decades, and states with low population and population growth have the greatest increase in plantations. These plantations, along with other woody biomass, are expected to play an important role in the emerging bio-energy sector.     

Fluidized bed spray granulation: Analysis of the system behaviour by means of dynamic flowsheet simulation

Nowadays, software tools for the flowsheet simulation of industrial processes are commonly used for design, simulation, balancing, troubleshooting and optimization purposes. Most of the tools are applicable to fluid processes only and cannot be effectively used for processes which involve solids.In this contribution we want to present the conceptual design of a new system applicable for the dynamic flowsheet simulation of complex solids processes. This system is developed as an enhancement to the existing simulation program.The novel software is able to simulate the unsteady behaviour of complex circuits of granulation processes. The transient behaviour during the start-up and changing of the process or material parameters can also be examined.As flowsheet examples, a typical spray granulation process with different schemes consisting of fluidized bed granulators, screens, mill and splitters was used. The mathematical model of the fluidized bed granulator is described by a one-dimensional population balance equation and coupled with heat and mass transfer and simple fluid dynamics.Received simulation results have shown that the proposed concept of the dynamic flowsheet simulation of granulation processes can be used effectively and has the potential to be generalized for other types of solids processes.     

Stochastic equations of rigid-thermo-viscoplasticity in metal forming process

Stochastic rigid-thermo-viscoplastic metal forming process is described and discussed. The theoretical formulation for stochastic equations in rigid-thermo-viscoplasticity is presented. It is based on the combination of the second-order perturbation technique and second-moment analysis. The principle allows incorporation of system uncertainties into finite-element equations. Probabilistic distributions for temperatures and strains taking into account random initial and boundary conditions are given. Example of stochastic analysis in shell nosing process is shown.     

Self-Assembly of Proteinaceous Shells around Positively Charged Gold Nanomaterials Enhances Colloidal Stability in High-Ionic-Strength Buffers

The enzyme lumazine synthase (LS) has been engineered to self-assemble into hollow-shell structures that encapsulate unnatural cargo proteins through complementary electrostatic interactions. Herein, we show that a negatively supercharged LS variant can also form organic–inorganic hybrids with gold nanomaterials. Simple mixing of LS pentamers with positively charged gold nanocrystals in aqueous buffer spontaneously affords protein-shelled gold cores. The procedure works well with differently sized and shaped gold nanocrystals, and the resulting shelled complexes exhibit dramatically enhanced colloidal stability over a wide range of pH (4.0–10.0) and at high ionic strength (up to 1 m NaCl). They are even stable over days upon dilution in buffer. Self-assembly of engineered LS shells in this way offers an easy and attractive alternative to commonly used ligand-exchange methods for stabilizing inorganic nanomaterials.     

Twinned Growth of Metal‐Free,Triazine‐Based Photocatalyst Films as Mixed‐Dimensional (2D/3D) van der Waals Heterostructures

Design and synthesis of ordered, metal‐free layered materials is intrinsically difficult due to the limitations of vapor deposition processes that are used in their making. Mixed‐dimensional (2D/3D) metal‐free van der Waals (vdW) heterostructures based on triazine (C₃N₃) linkers grow as large area, transparent yellow‐orange membranes on copper surfaces from solution. The membranes have an indirect band gap (E _g,opt = 1.91 eV, E _g,elec = 1.84 eV) and are moderately porous (124 m² g^?1). The material consists of a crystalline 2D phase that is fully sp² hybridized and provides structural stability, and an amorphous, porous phase with mixed sp²–sp hybridization. Interestingly, this 2D/3D vdW heterostructure grows in a twinned mechanism from a one‐pot reaction mixture: unprecedented for metal‐free frameworks and a direct consequence of on‐catalyst synthesis. Thanks to the efficient type I heterojunction, electron transfer processes are fundamentally improved and hence, the material is capable of metal‐free, light‐induced hydrogen evolution from water without the need for a noble metal cocatalyst (34 µmol h^?1 g^?1 without Pt). The results highlight that twinned growth mechanisms are observed in the realm of “wet” chemistry, and that they can be used to fabricate otherwise challenging 2D/3D vdW heterostructures with composite properties.