Understanding silica-supported metal catalysts: Pd/silica as a case study

Supported metal catalysts, particularly noble metals supported on SiO₂, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO₂/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO₂ films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon.     

Studies on miscibility of blends of ethylene methyl acrylate and polydimethyl siloxane rubber

Blends of ethylene methyl acrylate (EMA) and poly(dimethylsiloxane) rubber (PDMS) are demonstrated to be miscible. The miscibility results in a single and composition-dependent glass transition temperature. IR spectra of the blends provide direct evidence of chemical reaction between EMA and PDMS rubber.     

Ammonia Decomposition on Ir(100): From Ultrahigh Vacuum to Elevated Pressures

Ammonia decomposition on Ir(100) has been studied over the pressure range from ultrahigh vacuum to 1.5 Torr and at temperatures ranging from 200 to 800 K. The kinetics of the ammonia decomposition reaction was monitored by total pressure change. The apparent activation energy obtained in this study (84 kJ/mol) is in excellent agreement with our previous studies using supported Ir catalysts (Ir/Al₂O₃ 82 kJ/mol). Partial pressure dependence studies of the reaction rate yielded a positive order (0.9±0.1) with respect to ammonia and negative order (–0.7 ±0.1) with respect to hydrogen. Temperature-programmed desorption data from clean and hydrogen co-adsorbed Ir(100) surfaces indicate that ammonia undergoes facile decomposition on both these surfaces. Recombinative desorption of N₂ is the rate-determining step with a desorption activation energy of 63 kJ/mol. Co-adsorption data also indicate that the observed negative order with respect to hydrogen pressure is due to enhancement of the reverse reaction (NH _x + H NH _x+1, x=0–2) in the presence of excess H atoms on the surface.     

Propagation of correlations in local random quantum circuits

We derive a dynamical bound on the propagation of correlations in local random quantum circuits—lattice spin systems where piecewise quantum operations—in space and time—occur with classical probabilities. Correlations are quantified by the Frobenius norm of the commutator of two positive operators acting on disjoint regions of a one-dimensional circular chain of length L. For a time \(t=O(L)\), correlations spread ballistically to spatial distances \(\mathcal {D}=t\), growing at best, diffusively with time for any distance within that radius with extensively suppressed distance- dependent corrections. For \(t=\varOmega (L^2)\), all parts of the system get almost equally correlated with exponentially suppressed distance- dependent corrections and approach the maximum amount of correlations that may be established asymptotically.     

Experimental realization of quantum cheque using a five-qubit quantum computer

Quantum cheques could be a forgery-free way to make transaction in a quantum networked banking system with perfect security against any no-signalling adversary. Here, we demonstrate the implementation of quantum cheque, proposed by Moulick and Panigrahi (Quantum Inf Process 15:2475–2486, 2016), using the five-qubit IBM quantum computer. Appropriate single qubit, CNOT and Fredkin gates are used in an optimized configuration. The accuracy of implementation is checked and verified through quantum state tomography by comparing results from the theoretical and experimental density matrices.     

Electron microscopic observations on the alterations of tegumental surface of Raillietina echinobothrida treated with root-peel extract of Potentilla fulgens

Potentilla fulgens, a member of the family Rosaceae, has been known since ancient times in Northeast India for its antiparasitic, antitumour and antidiabetic properties. The crude ethanolic extract of the plant was assayed against Raillietina echinobothrida, the intestinal cestode parasite of domestic fowl to authenticate the putative anthelmintic efficacy and cestocidal potential in particular of the plant. Treatment of the worm in-vitro with 25, 50 and 100 mg of crude extract per ml of phosphate buffered saline caused paralysis leading to death taking 4.02-4.20, 3.05-3.75 and 2.05-2.83 h respectively. Scanning electron microscopic observations on treated worms revealed deformation of surface architecture, particularly in scolex and surface microtriches. Severe distortion and disorganization of the tegumental and subtegumental layer along with cytoplasmic organelle was also observed under transmission electron microscope. The possible use of the plant as a potential anthelmintic against cestode parasite is discussed.     

Surface integrity study of WEDM with various wire electrodes: experiments and analysis

Abstract

Wire electrical discharge machining (WEDM) is always significant for its high-precision machining. However, due to the generation of high discharge energy during machining, machined surfaces are often got distorted. These might be upgraded by choosing the correct tool with proper machining condition. The effects of the electrode materials and process parameters on different responses of WEDM like average surface roughness, recast layer thickness, and surface morphology are systematically examined here to enhance the knowledge of WEDM and its correlation with electrode property. The experiments have been carried out on one of the expensive steel namely Maraging steel 300 due to its applicability in tooling and aerospace industries. Plain brass wire, zinc-coated brass wire (ZCB), and silver-coated brass (SCB) wires are used as a tool electrode for analysis. Comparative experimental studies prove that among BW, ZCB, and SCB, the overall performance of SCB is commendable owing to the high-quality surface considering control parameters in low discharge energy level. However, the second-best performance is shown by ZCB.     

Interdiffusion in the Fe-Pt System

Diffusion-couple experiments are conducted in the Fe-Pt system. The phase boundary compositions of the phases measured in this study are found to be different than the compositions published previously. In the γ-FePt solid solution, the interdiffusion coefficient increases with the Pt content up to 25 at. pct Pt. Fe is the faster diffusing species in this phase. The trend in the interdiffusion coefficient is explained with the help of calculated driving force for diffusion. To reduce errors, the average interdiffusion coefficients are calculated in the FePt and FePt₃ compounds.     

Corrosion-free electrochemical synthesis of polyaniline using Cu counter electrode in acidic medium

Polyaniline (PAni) was electrochemically synthesized from aniline sulfate (AS) in the presence and in absence of H₂SO₄ using Cu counter electrode. No significant corrosion of the Cu electrode was found while synthesizing from AS in presence of H₂SO₄, whereas relatively higher corrosion of Cu as well as contamination of synthesized PAni with corroded Cu were observed for the synthesis from aniline in presence of H₂SO₄ or from AS in the absence of H₂SO₄. Corrosion-free synthesis yields PAni free from contamination of Cu and exhibits smaller particle size and superior electrical and supercapacitive behavior compared to the process exhibiting corrosion of counter electrode.     

Energy reduction schemes for multiple effect evaporator systems

In the present work different energy reduction schemes (ERSs), used to reduce the consumption of steam for a multiple effect evaporator (MEE) system, are developed. These ERSs are condensate-, feed- and product-flashing and vapor bleeding. Further, a new scheme is proposed where condensate of vapor chest of an effect is used to preheat the liquor, which is entering into that effect using a counter current heat exchanger. This work also presents a comparative study between existing ERSs and selects the best ERS amongst these based on steam consumption as well as number of units involved. Further, in the present paper a simple graphical approach named “modified temperature path (MTP)” is developed for the analysis of different feed flow sequences of a MEE system to screen best possible feed flow sequence. To study the effect of different ERSs on steam consumption and MTP analysis an example of septuple effect flat falling film evaporator (SEFFFE) system, employed for concentrating weak black liquor in an Indian Kraft Paper Mill, is considered. The results show that ERSs reduce the steam consumption up to 24.6%.