Co-Al基三元系中B2相的溶解度间隙与稳定性

Information on phase equilibria in the Co-Al based systems which are related to some magnetic and heat resistance materials is important for their microstructural control. Recently, it was proposed with a theoretical calculation on electronic band structure that some Heusler-type alloys Co2 XAl (X: Cr and Mn) should be a new type of spinelectronic materials so-called half-metallic ferromagnet. In the case of the Co2CrAl, however, magnetic properties expected from the theoretical work can not been experimentally obtained and the reason has been still unknown. On the other hand, a tunne- ling magnetoresistance (TMR) effect due to the half-metallic properties was reported in Co2 (Cr0.6 Fe0.4 ) Al alloy, but not the Co2CrAl alloy. In the present paper, it is reported that this discrepancy with the theoretical work in the Co2CrAl alloy is bought about by phase separation between A2 and B2 phases, and that the substitution of Fe for Cr can suppress the precipitation of A2 phase in the B2 phase. Such a phase separation is originally due to the miscibility gap between CoAl and Cr formed in the Co-Al-Cr ternary system as well as that reported by Hao et al. in the Ni-Co-Al-Fe system.     

Development of Electrolytic Capacitor Less Photovoltaic Grid Connected Inverter with Boost‐Up Type Active Buffer Circuit

This paper proposes a configuration of a single‐phase voltage source inverter that features power decoupling capability. Generally, the converter connected to a single‐phase grid employs bulky dc link capacitors such as electrolytic capacitors in order to decouple the power ripple with twice the frequency of the power supply. The power ripple in the proposed circuit is compensated by an active buffer with small capacitors. In this paper, the fundamental operations of the proposed converter are confirmed by experimental results. From the experimental results, the output current total harmonic distortion (THD) is 3.51%, the ratio of the input current is 14.3%, and the output power factor is over 99%. In addition, the volume of the proposed circuit is reduced by 61% when the carrier frequency is 64 kHz compared to that with a carrier frequency of 16 kHz. Finally, from an evaluation of the power density using Pareto front curves, the proposed circuit achieves high power density in comparison with the conventional circuit.     

化学有序及磁有序在铁基合金相平衡影响方面的交互作用

It is well known that the magnetic properties such as the Curie temperature TmagC and the mean magnetic moment β of ordered compounds have different values from those of the disordered solutions. For instance, both Tcmag and β of the Ni3 Pt (L12) and NiPt (L10) and Tcmag of the CoPt (L10) and CoPt3 (L12) ordered compounds are strongly depressed due to the ordering compared with those of the metastable disordered Ni-Pt and Co-Pt alloys. On the other hand, the γ-FeNi3(L12) and the α-FeCo (B2) ordered compounds have higher Tcmag and β values comparing with the disordered solution phases, γ (A1) and α (A2), respectively. In consequence, the stability of the ordered phase is depressed or enhanced due to the interaction between the chemical and magnetic ordering caused by the decrease or increase of Tcmag and β values. The purpose of this study is to investigate the effect of the interaction between the chemical and the magnetic ordering on the phase equilibria in the Fe-X(X=Al, Co, Ni, Rh, Si) binary systems.The Gibbs energy of the α(A2), γ(A1) and liquid phases is described by a sub-regular solution approximatior. The ordering contribution to the Gibbs energy ,ΔGmorder, and deviations of magnetic properties, ΔTcmag and Δβ, of the ordered compounds, FeAl(B2), Fe3 Al (D03), FeCo (B2), FeRh (B2), FeSi (B2), Fe3 Si (D03) and FeNi3 (L12) is introduced by the split compound energy formalism. Effect of the interaction between the chemical ordering, B2, D03 and L12 and the magnetic ordering on the phase equilibria will be discussed according to the calculated phase diagrams of the Fe-X binary systems.     

Thermodynamic assessment of the Ni-Sb binary system

The Ni-Sb binary alloy system was thermodynamically assessed using CALPHAD approach in this article.Excess Gibbs energies of solution phases,liquid and fcc phases,were formulated using the Redlich-Kister expression.The intermediate phases were modeled by the sublattice model with (Ni,Va)0.5(Ni,Sb)0.25(Ni)0.25 for Ni3Sb_HT phase and (Ni,Va)0.3333(Sb)0.3333(Ni,Va)0.3333 for NiSb phase.The other phases including Ni3Sb,Ni7Sb3,and NiSb2 were treated as stoichiometric compound owing to their narrow composition ranges.Based on the reported thermodynamic properties and phase diagram data,the thermodynamic parameters of these phases were optimized,and the obtained values can reproduce the available experimental data well.     

电子组装无铅焊料的热力学、动力学计算及合金设计

Computational thermodynamics and kinetics were used to design the Pb-free micro-solders for replacing the conventional Sn-Pb solders because of the health and environmental safety problem.On the basis of CALPHAD (Calculation of Phase Diagrams) method we can easily calculate properties such as the liquidus projection, isothermal and vertical sectional diagrams and phase fraction in multicomponent system including Ag, Bi, Cu, In, Sb, Sn, Zn and Pb elements. In addition, other related information such as the surface tension, viscosity of the liquid phase and solidification simulation can also be obtained. DICTRA (Diffusion Controlled Transformation) software was used to simulate the interfacial reactions between substrate and Pb-free solders, which can easily give the information on the growth of intermetallic compounds and moving speed of interface between substrate and solders etc.     

多元系B2相的热力学描述

B2相广泛存在于铁基、钴基和镍基合金中.B2相的析出对于合金组织和性能具有重要影响.本文指出了合理描述B2相的热力学模型,并就如何简单有效地描述多元合金系中的B2相,以及如何处理在此过程中可能出现的各种问题,进行了深入的探讨和研究.     

自组装Cu-Fe基复合材料的设计与开发

The Cu-Fe base alloys with liquid immiscible were prepared by gas atomization technique and conventional solidification process, the self-assemble composite microstructures in powders and bulk materials can be obtained under gravity conditions, respectively, and the minor liquid phase always forms the center of composite microstructure. It is shown that the formation of the core-type macroscopic morphology is strongly connected with the existence of a stable miscibility gap of the liquid phase in the Cu-Fe base alloys. This result can be explained by a mechanism that the minor droplets as the second phase are forced to move into the thermal center due to Marangoni motion, which is caused by the temperature dependence of interracial energy between two liquid phases.     

EFFECTS OF CURING ON MORPHOLOGICAL AND THERMAL PROPERTIES OF SALMON-NOSE CARTILAGE AS A VINEGARED DISH IN JAPAN

ABSTRACT Sliced salmon-nose cartilage was cured in 4% acetic acid up to 168h. Using optical microscopy, we observed the reddish-purple color produced by staining with toluisine-blue turned lighter during curing. This meant that the mucopoly-saccharide level of cartilage matrix decreased, causing the structure of the cartilage to become porous. In addition, using scanning electron microscopy, loosenings of collagen fibers was observed after 72 h of curing, thus making the structure of the cartilage fragile. DSC thermograms showed that the denaturation temperature of the native collagen fibers was lowered and an additional peak appeared during curing. These findings lead us to suggest that the collagen in salmon-nose cartilage changes qualitatively during curing.     

Converter Using SiC‐MOSFET for Ultra‐High‐Speed Elevator

In this study, we developed a converter based on SiC (Silicon Carbide)‐MOSFET for use in ultra‐high‐speed elevators, with a reduced volume of 15% compared with the conventional converter. We succeeded in reducing the power loss of the converter unit by 56% compared to the conventional converter in one round trip under high temperature condition. Recently, because of their useful characteristics, wide‐gap semiconductors, such as SiC and GaN, have gained considerable attention for use in various applications in the power electronics systems. Therefore, we studied the use of a converter in elevator systems based on SiC‐MOSFET. We used a 1200 V/800 A SiC‐MOSFET module for the converter unit. We developed a prototype of the converter unit and the control panel by applying for the SiC‐MOSFET module for an ultra‐high‐speed elevator. As a result, the setting area of the control panel (main part) becomes less than 43% of the conventional panel. We tried to demonstrate the working of a 68‐kW elevator by applying the prototype control panel. Because of the characteristic of the switching loss of SiC‐MOSFET, the power loss of the converter unit has almost no dependence on temperature. An energy‐saving effect of approximately 17% was achieved in the total elevator system in one round trip under high‐temperature condition.