APPLICATION OF COMPUTER NUMERICAL METHOD IN PORE STRUCTURE CALCULATION

This paper compares the results Of calculat-ing pore structure and graphing differential and integralpore size distribution by hand and Computer,and presents thatlagrangian interpolation uesd by calculating pore structure issuitable and reliable.     

Electrical properties of La0.6Sr0.4Co1-yFeyO3 cathode material

The electrical properties of La0.6Sr0.4Co1-yFeyO3 （LSCF, y=0-1.0） cathode materials were measured by DC four probes, X-ray photo-electron spectrum （XPS） was also introduced to determine the chemical state of Co, F.e ions in LSCF. It is found that the electrical conductivity of each sample has a maximum value with increasing temperature. XPS analysis shows that Co ion has three different chemical states, corresponding to two with Fe ion. The analyses indicates that the small-polaron hopping mechanism dominates the electron conduction at low temperature, while at high temperature, the three factors such as the thermally activated disproportionation of Co^3＋ ions into Co^2＋ and Co^4＋ pairs, the ionic compensation of oxygen vacancies formed at high temperatures, and Fe^4＋ ions charge compensation preferential to Co^4＋, all contribute to electrical conduction.     

Preparation and properties of β-tricalcium phosphate porous bioceramic

Porous β-tricalcium phosphate bioceramic (PTCP) has important roles in surgical implants because of good biocompatibility. But the low compressive strength of the ceramic limits its application. The preparation of PTCP was improved with the adjustment of the constituents and the sintering-process. A new type of PTCP material with high compressive strength was made. The compositions, microstructure and properties of PTCP were analyzed by TG-DSC, XRD, TEM, SEM and so on. The result indicates that stearic acid burns sufficiently and gives out carbon dioxide and water vapor when slowly heated between 200 ℃ and 400 ℃ so that the porous structure like coral in β-TCP bioceramic is formed. Through crystallization at 470 ℃ and 570 ℃, more CaO-P2O5 glass-cement is converted into crystallite-glass, which is beneficial for improving the compressive strength of β-TCP bioceramic.PTCP can form a support action in bone imperfect section with good solubility.     

Microstructure of reactive sintered Al bonded Si3N4-SiC ceramics

Aluminium nitride-silicon nitride-silicon carbide （AIN-Si3N4-SiC） composite ceramics were prepared to increase the bending strength and improve the phase structure of Si3N4-based ceramics. The ceramics were made by reactive sintering in N2 atmosphere at 1 360 ℃, using Al as sintering additive. The phase composing of ceramics was identified with an X-ray diffractometer and the microstructure of the materials was studied by scanning electron microscopy. The results indicate that the phase structure is affected remarkably and the interface modality is changed. The interface between Si3N4 and SiC becomes blurry and that between SiC and AlN matches more better at the same time. But the liquid-phase appears during the reactive sintering along with the addition of AI by which the melting point of Si is decreased. The appearance of liquid Si decreases the bending strength of the ceramics. Lower temperature nitrification technic was introduced to avoid the appearance of liquid-phase Si. The optimum addition of Al was investigated by XRD and SEM analysis in order to obtain the maximal bending strength of materials.     

氯氧镁水泥浆体水化相及其对强度指标影响初探

本文力图从合成氯氧镁水泥的纯相入手,研究浆体的基本水化相及其相变规律。研究表明,用正确的配比,采用人工合成的方法,可以得到氯氧镁水泥的基本水化相,即5·1·8和3·1·8,并指出了这两种水化相的变化规律。采用不同浓度的MgCl_2溶液配制的氯氧镁水泥浆体,其水化相主要是5·1·8和Mg(OH)_2,采用半定量的计算方法,可以得到这两种水化相之比与浆体强度的对应关系,因而正确选择水化相的比例,可以获得最佳强度的水泥浆体。     

人造硅酸盐骨料在混凝土中的有效弹性模量

采用棱柱体模拟硅酸盐骨料测其弹性模量,并不能反映硅酸盐骨料在混凝土中的受力状态,测出的弹性模量不能真实反映硅酸盐骨料在混凝土中的"有效弹性模量"。对复合材料弹性模量上限公式进行修正,修正后的公式能较真实的计算出硅酸盐骨料混凝土的弹性模量值。采用外推法得壳层硅酸盐骨料的"有效弹性模量"与砂浆基体弹性模量较为接近,当硅酸盐骨料混凝土受压时,硅酸盐骨料与砂浆基体变形协调一致,硅酸盐骨料在混凝土中为三向受压的应力状态,在混凝土中表现出很强的刚性特征。     

人造硅灰结构及火山灰活性研究

以蛇纹石为原料经浓酸处理，其滤液用于制备轻质氧化镁，其残渣主要成分是二氧化硅，对残渣进一步超细粉磨加工制成人造硅灰。利用近代测试技术对人造硅灰的形貌、晶相、物相及孔结构和微结构形成过程进行研究，测试结果表明，人造硅灰是一种非晶态、隐晶质物质、具有较大的内比表面积的多孔体，具有较高的火山灰活性，是一种较为理想的替代硅灰材料。     

影响塑料制品拉伸试验结果的因素

分析了影响塑料拉伸试验结果的因素,除塑料的组成、分子结构和内部缺陷等因素直接影响拉伸性能外,试验仪器、试样制备、试样装夹、试验环境、拉伸速率、数据处理、操作人员等因素亦影响试验结果。这些外部因素对试验结果的影响,经过认真操作和严格控制是可以降低或避免的,从而可提高试验结果的准确性。     

La0.6Sr0.4Co1-yFeyO3系阴极材料的电性能

La1-xSrxCo1-yFeyO3系(LSCF)钙钛矿结构氧化物是一类性能优异的离子-电子混合导体,同时具有良好的化学稳定性和催化活性,有望作为中低温下工作的固体氧化物燃料电池阴极材料的候选材料.本文考察了La0.6Sr0.4Co1-yFeyO3(y=0.2～0.8)系材料的导电机制.XPS光电子能谱分析表明,除了存在小极化子导电机制外,同时还可能存在以下几种机理:1)热激发引起Co3 离子的电荷歧化;2)高温下氧空位生成导致的离子补偿;3)Fe4 较Co4 优先进行电荷补偿.