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二甲醚燃烧用掺杂钡、镍六铝酸盐催化剂的研究 总被引:4,自引:0,他引:4
二甲醚是易液化,便于运输,清洁化的新能源。当作为燃料使用时,采用催化燃烧的方法能使得燃烧的起燃温度降低和提高燃烧转化率,克服了普通燃烧的缺点,实现了清洁燃烧。对二甲醚催化燃烧用的催化剂BaNiAl11O19-δ进行了制备与研究。采用溶胶-凝胶法制备六铝酸盐催化剂BaNiAl11O19-δ,考察其对新能源二甲醚催化燃烧反应的活性,并用TG—DTA对催化剂的性质进行考察。结果表明,加入经800℃焙烧4h后又在1200℃焙烧了2h的催化剂,比未加催化剂的燃烧体系T10降低了50℃。用溶胶一凝胶法制备的六铝酸盐催化剂BaNiAl11O19-δ对二甲醚催化燃烧反应具有较高的催化活性。 相似文献
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Catalytic combustion of dimethyl ether (DME) over hexaaluminate catalyst BaNi0.2Mn0.8Al11O19-δ has been investigated. The catalysts were prepared with the sol-gel method and reverse microemulsion method respectively and characterized by thermogravimetry-differential thermal analysis, X-ray diffraction and transimission electron microscope. It was found that the formation of Mn, Ni modified hexaaluminate was a relatively slow process via two solid state reactions and spinel structure was a transition phase. At the same calcined temperature and time, the catalyst prepared with the reverse microemulsion method could form the hexaaluminate phase more easily than that prepared with the sol-gel method. The catalyst BaNi0.2Mn0.8Al11O19-δ prepared with the reverse micro-emulsion method appeared a plate-like morphology, while it appeared a needle-like morphology when using the sol-gel method. The catalytic activities of catalysts BaNi0.2Mn0.8Al11O19-δ prepared with two different methods for DME combustion were tested. It showed that catalyst prepared with the reverse microemulsion method had better catalytic activity, i.e. T10% of DME had decreased by 45℃, about 90% conversion of diemthyl ether at 380℃. 相似文献
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制备方法对BaNi0.2Mn0.8Al11O19-δ催化燃烧二甲醚的催化活性的影响 总被引:1,自引:0,他引:1
Catalytic combustion of dimethyl ether (DME) over hexaaluminate catalyst BaNi0.2Mn0.8Al11O19-δ has been investigated. The catalysts were prepared with the sol-gel method and reverse microemulsion method respectively and characterized by thermogravimetry-differential thermal analysis, X-ray diffraction and transimission electron microscope. It was found that the formation of Mn, Ni modified hexaaluminate was a relatively slow process via two solid state reactions and spinel structure was a transition phase. At the same calcined temperature and time, the catalyst prepared with the reverse microemulsion method could form the hexaaluminate phase more easily than that prepared with the sol-gel method. The catalyst BaNi0.2Mn0.8Al11O19-δ prepared with the reverse micro-emulsion method appeared a plate-like morphology, while it appeared a needle-like morphology when using the sol-gel method. The catalytic activities of catalysts BaNi0.2Mn0.8Al11O19-δ prepared with two different methods for DME combustion were tested. It showed that catalyst prepared with the reverse microemulsion method had better catalytic activity, i. e. T10% of DME had decreased by 45℃, about 90% conversion of diemthyl ether at 380℃. 相似文献
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