DBD等离子体反应器高频电源下的放热研究

通过实验监测DBD(dielectric barrier discharge)温度变化情况,探讨了温升所引起的热转移机理,得出DBD热变化表达式,并推导出相应的能量分配式及ΔTave计算式.实验结果表明:高频放电过程中,DBD反应器温度随电压升高和时间延长而上升,它们之间呈非线性关系;DBD反应器温度随频率提高和时间延长而升高,随气体速度的提高而降低,温度变化与时间、频率及气体速度均呈现出线性关系.     

陶瓷填料与光催化剂对反应器效率的影响

目的了解陶瓷填料与光催化剂对气体放电-光催化反应器净化效率的影响.方法通过理论计算、吸附实验和电容测试等方法对气体放电-光催化反应器所用的A、B两种陶瓷填料以及附着纳米TiO2光催化剂的B类陶瓷填料物理特性进行了分析.结果A类陶瓷的介电常数计算值大于B类陶瓷的计算值;介电常数的实验值为A类陶瓷相似文献   

电凝并技术脱除PM2.5的研究现状及发展方向

针对传统除尘器无法有效捕集PM2.5的问题,笔者论述了同极荷电颗粒在交变电场中的凝并、异极性荷电粉尘的库伦凝并、异极荷电颗粒在交变电场中的凝并、异极荷电颗粒在直流电场中的凝并、四级凝并5种电凝并技术的研究现状,并提出了电凝并技术的发展方向。5种电凝并技术中,异极荷电颗粒在交变电场中的凝并效果较好;两区式异极荷电颗粒在交变电场中的凝并效果优于三区式。低温等离子体-电凝并技术将低温等离子体-电凝并设备直接置于管道中,对粉尘预荷电;基于原有布袋除尘器开发出双踪电笼布袋除尘装置,联合脱除PM2.5。利用低温等离子体-电凝并技术开发的复合反应器结构紧凑,占地面积小,对细微粒子的除尘效率高达99%,可实现脱硫脱硝脱汞的协同脱除,是电凝并技术的发展方向。     

交流高压电凝并用于铅冶炼烟尘PM_(2.5)控制

有色冶炼工业窑炉排放的PM2.5(粒径小于等于2.5μm的颗粒物)中富集铅、砷、铬、汞、铜等多种重金属元素,是空气中重金属污染物的重要贡献源。选择铅冶炼过程中产生的PM2.5作为重点控制污染物,分析其粒径特征和重金属含量,在此基础上开展交流高压电源电晕放电对细颗粒物的凝并效率研究。试验结果表明,交流高压电晕放电对于PM3.3以下的颗粒物均有明显的凝并作用,在最佳试验条件下,PM2.5的质量分数下降58%以上。该法可有效减少除尘器入口精细粉尘的含量,为有效控制冶炼烟气PM2.5排放及伴生重金属污染物的控制提供方法和工艺。     

低温等离子体反应器去除挥发性有机化合物的能效分析

为了推动等离子体技术早日商业应用,提高低温等离子体技术的能量效率,本研究采用自行研制优化的管-线式反应装置,考察了不同介质填料、电场强度E、污染物入口质量浓度ρ0和气流速度v等参数对反应器能量效率ζ的影响。希望通过优化实验参数,可以在保证污染物降解率η的同时有效提高ζ。实验结果表明,随着污染物v的增加,ζ呈现先增大后减小的趋势;随着ρ0的增加,ζ呈现先增大后减小的趋势;η和ζ由高到低依次均表现为复合催化剂、Ba0.8Sr0.2Zr0.1Ti0.9O3、MnO2/γ-Al2O3、γ-Al2O3和无填料。因此,在本实验条件下,v为2 mL/min,ρ0范围在1 500~2 000 mg/m3,E在9.6 kV/cm左右,填料为复合催化材料,可得到最佳ζ为10 g/(kW·h)。研究为等离子体技术的发展提供了新的思路,为该技术的商业应用提供了借鉴。     

煤矸石资源化利用现状与进展

在实现“碳达峰与碳中和”目标的背景下,煤炭作为国家能源安全的基石,其绿色开发对我国经济建设和社会发展起到了至关重要的作用。然而,在煤矿开采及分选加工过程中,煤矸石作为煤炭主要伴生副产物,已成为我国急需处理的大宗固废之首。然而,目前煤矸石的综合利用率仍处于较低水平,尚未形成较为规范可行的研究体系。因此,针对煤矿开采与煤矸石堆积所造成的水、大气与土壤环境污染问题,通过煤矸石在生产能源、有价金属回收、建筑材料生产与其他方向的资源化利用的相关研究进展,结合煤矸石在防止重金属污染、土壤修复、防止水土流失等方面的应用,最后提出了煤矸石资源化利用未来的发展方向,根据整体进行规划与资源整合,不仅有大量用于常规目的的煤矸石资源化利用方向,同时还有用于生产高附加值产品的特殊用途,通过两者相结合,实现煤矸石的综合化和资源化利用,为其“减量化、资源化、循环化”发展提供借鉴。总之,煤矸石资源化利用是我国煤炭产业转型升级的重要方向,也是实现绿色可持续发展的必由之路。只有通过不懈的努力和持续的创新,才能更好地解决煤矸石堆积问题,推动煤矸石资源化利用向更加高效、环保、可持续的方向发展,为我国经济社会可持续发展做出更大...     

1,2,4-trichlorobenzene decomposition using non-thermal plasma technology

Non-thermal plasma(NTP)is regarded as a potential application for environmental pollution control due to its ability to remove pollutants.As a major precursor of dioxins,the influence of the parameters of 1,2,4-trichlorobenzene(TCB)decomposition using NTP technology was investigated through a series of experiments,including voltage,frequency,water content,initial concentration,flow rate,and oxygen content.The experimental results show that the energy injected into the NTP system has a positive correlation to voltage and frequency.Oxygen has the greatest influence on TCB decomposition.The optimal reaction condition was at 15 kV,1000 Hz,an initial concentration of 20 mg m^?3,a flow rate of 2 l min^?1,H2O at 4%,and O2 at 0%.Under this condition,the TCB removal efficiency could reach 92%.According to the generated product backstepping,the hydroxyl radical(·OH)plays an important role in TCB decomposition due to its strong oxidation,which participates in the dechlorination and oxidation reactions as free radicals,and the possible decomposition pathway of TCB by NTP is inferred from the identified byproducts.It is of great significance to investigate the influence of the parameters of TCB decomposition using NTP technology in order to provide references for industrial application.     

Influence of gas atmosphere on synergistic control of mercury and dioxin by nonthermal plasma

In this paper, narrow-pulse power discharge is used to study the synergistic control of mercury and dioxins, in which 1,2,4-trichlorobenzene (TCB) was used as a dioxin analog, by using a self- designed experimental system. The competitive effects of NO, SO₂ and HCl on the TCB removal by non-thermal plasma are discussed. The influence of acid gas on TCB degradation is reflected in the competitive effect. NO has the greatest influence on TCB degradation efficiency. The oxidation efficiency of Hg⁰ decreased by about 10% in all three acidic gas atmospheres, and the effect of each gas component on Hg⁰ oxidation is complex. In the flue gas atmosphere of ‘acid gas+Hg⁰ +TCB’, the mechanism of the synergistic control of Hg⁰ and TCB by the non- thermal plasma is different, which has competition and promotion relationship between each other. The contribution of various flue gas components to the results was complicated, but the overall experimental results show that the synergistic control effect of the system can continue to improve. According to the generated product backstepping, ·OH plays an important role in the synergistic control of the degradation of Hg⁰ and TCB. Through this study, we hope to provide basic research data for the collaborative control of flue gas in the incineration industry.     

水泥窑低温SCR脱硝技术中试研究

以锐钛型工业级蜂窝状催化剂为材料,在新型干法水泥生产线窑尾布袋除尘器后进行了10 000 m3/h的低温选择性催化还原脱硝（SCR）试验研究。结果显示,空速对脱硝效率的影响受制于催化剂活性温度,5 000h-1空速值设计是可行的。温度是SCR脱硝的关键因素。脱硝效率随着温度升高而增高,130 ℃时脱硝效率大约30%,150 ℃脱硝效率达50%,170 ℃可实现80%以上脱硝效率,稳定实现100 mg/Nm3以内排放,氨逃逸浓度小于1 ppm。