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排序方式: 共有75条查询结果,搜索用时 375 毫秒
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Zhongkai Zhao Yohanes A. Situmorang Ping An Nichaboon Chaihad Jing Wang Xiaogang Hao Guangwen Xu Abuliti Abudula Guoqing Guan 《化学工程与技术》2020,43(4):625-640
In the future, hydrogen will be an important energy carrier and industrial raw material. Catalytic steam reforming of bio-oils is a promising and economically viable technology for hydrogen production. However, during the reforming process, the catalysts are rapidly deactivated due to coke formation and sintering. Thus, maintaining the activity and stability of catalysts is the key issue in this process. Optimized operation conditions could extend the catalyst lifetime by affecting the coke morphology or promoting coke gasification. This article summarizes the recent developments in the field of catalytic steam reforming of bio-oils, focusing on the operation conditions, the properties of the catalysts, and the effects of the catalyst supports. The expected insights into the catalytic steam reforming of bio-oils will provide further guidance for hydrogen production from bio-oils. 相似文献
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柱状晶向等轴晶转变(CET)是在一定的凝固过程中必须控制的一种显微组织转变.本文针对铝合金连铸坯凝固过程中柱状晶向等轴晶的转变,综合运用了正交试验研究、数值模拟计算、数学拟合等方法,分析了连铸过程主要工艺因素拉坯速度、一冷水量、二冷水量和浇注温度对连铸坯凝固过程中柱状晶向等轴晶转变位置的影响,提出了柱状晶向等轴晶转变的转变位置判据,即当连铸坯某一位置处的固相率等于0.3时,温度梯度G与冷却速度R满足函数关系G0.8072/R=0.469时,在该位置处将发生柱状晶向等轴晶的转变. 相似文献
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制备了Ni/YS│YSZ│LSM[YSZ——Y2O3掺杂(稳定)的ZrO2;LSM——锰酸镧即La0.85Sr0.15MnO3]阳极支撑单体固体氧化物燃料电池(SOFC)。其中阳极基底、YSZ电解质薄膜和LSM阴极分别采用干压成型方法、浆料喷覆工艺和浆料涂覆法制备。考察了电池制备过程中影响电池品质的主要因素,指出基底不均匀性和焙烧升温速率过快是导致成型压力在25~250MPa范围内阳极基底翘曲和开裂的主要原因;影响阳极基底与YSZ电解质薄膜共焙烧匹配性的主要因素是成型压力、预焙烧温度和焙烧升温速率。应用扫描电子显微镜(SEM)表征了电池微观结构,YSZ电解质薄膜的厚度约为15~20mm。考察了电池电性能,800℃下,阳极H2进气流量为250mL·min-1时,电池开路电压1.0973V,最大比功率0.13W·cm-2。进一步优化电极结构,可制备高性能的阳极支撑SOFC。 相似文献
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Treatment of solidification latent heat is a key point in solidification simulation by the finite difference method. When latent heat is dealt with in a traditional method of equivalent latent heat, it was found that heat was increased when casting with a high cooling rate, and then the simulation result was distorted. In this paper, a new method is proposed to deal with solidification latent heat. Moreover, a mathematical model was suggested, in which the latent heat can be dealt with accurately under high or normal cooling rates. By contrasting the simulation results from this new method with the traditional one, it was indicated that this new model can obtain more accurate simulation results than the traditional model under high or normal cooling rates. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(2): 115–121, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20104 相似文献
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研究了pH、金属离子、微波加热、常见氧化剂和还原剂、光线等对野生小檗色素稳定性的影响,并就色素的稳定性进行了探讨。通过对小檗色素理化性质的研究,表明该色素在化妆品及食品、染料、饮料等方面有很大的应用前景。 相似文献
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An energy analysis of three typical solid oxide fuel cell (SOFC) power systems fed by methane is carried out with detailed thermodynamic model. Simple SOFC system, hybrid SOFC‐gas turbine (GT) power system, and SOFC‐GT‐steam turbine (ST) power system are compared. The influences of air ratio and operative pressure on the performance of SOFC power systems are investigated. The net system electric efficiency and cogeneration efficiency of these power systems are given by the calculation model. The results show that internal reforming SOFC power system can achieve an electrical efficiency of more than 49% and a system cogeneration efficiency including waste heat recovery of 77%. For SOFC‐GT system, the electrical efficiency and cogeneration efficiency are 61% and 80%, respectively. Although SOFC‐GT‐ST system is more complicated and has high investment costs, the electrical efficiency of it is close to that of SOFC‐GT system. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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