A numerical and an experimental analysis of velocity and temperature fields inside a storage tank submitted to natural convection is presented. The analysis was performed in two stages. In the first stage, the temperature profile along the vertical axis of the storage tank was obtained experimentally and numerically, for cooling time ranging from 45 to 60 h. The numerical analysis was carried out using a transient bi-dimensional model in cylindrical co-ordinates. In the second stage, after the numerical code validation, 40 cases of cooling with four aspect ratios, five insulation thicknesses, and two different volumes were simulated. In all simulations, thermal losses for the environment in all tank walls (side, top and bottom) were considered. Two correlations for the Nusselt number, encompassing all the forty cases, were obtained with these results. 相似文献
Reverse Osmosis is finding increasing use for the treatment of municipal and industrial wastewaters due to the growing demand for high quality water in large urban areas. The growing success of membranes in this application is related to improved process designs and improved membrane products. Key factors which have been determined to result in successful operation of large-scale plants will be discussed. Factors which play a key role in the use of RO membranes include ultra or microfiltration pretreatment, low fouling membranes, flux rate, recovery and control of fouling and scaling. In particular, high flux rates can be used when UF or MF pretreatment is used. These technologies remove most of the suspended particles that would normally cause heavy fouling of lead elements. Typically, fluxes in the range of 17-21 lmh lead to cleaning frequencies in the range of 3-4 months. By combining the use of membrane pretreatment and chloramination of the feed water through chlorine addition, two of the primary sources of RO membrane fouling can be controlled. The use of chloramine has become a proven means to control biofouling in a membrane for wastewater applications. The other significant problems for RO membranes result from organics fouling by dissolved organics and scaling due to saturation of marginally soluble salts. The former can be a significant problem for membranes, due to the strong attraction forces. To some extent, these can be mitigated by making the membrane surface more hydrophilic or changing the charge of the membrane surface. To minimize fouling, many plants are turning to low fouling membranes. Extensive studies have demonstrated that the membrane surface is hydrophilic, neutrally charged over a broad pH range, and more resistant to organic adsorption. Also, an analysis of the potential scaling issues will be reviewed. In particular, calcium phosphate has been found to be one of the key scalants that will limit RO system recovery rate. Calcium phosphate concentrations can reach high values in many wastewaters, and scaling of this compound is not often modeled in most RO projection software. Various process options will be presented to evaluate the most economic means of avoiding phosphate scaling. Finally, data from major RO wastewater treatment plants will be presented to show how the RO membranes operate under actual conditions, utilizing many of these design features. Long-term data from the 2.6 mgd Bedok demonstration Plant demonstrate that the RO membranes operate consistently on wastewater. Experiences from the 8.5 mgd (32,000 m3/day) Bedok and 10.5 mgd (40,000 m3/day) Kranji plants will also be presented. These large plants started operation in the fall of 2002 and have demonstrated an effective means to reclaim high quality water from difficult source waters, such as municipal wastewaters. 相似文献
The purpose of this work is to characterize the sky relative radiance and luminance distributions from the analysis of sky images acquired using a monochromatic CCD wide angle lens camera. The proposed methodology is based on the reduction of the number of the gray levels from the original image, in order to sharpen the different regions of the sky hemisphere, resulting in low level gray scale maps. In these maps each gray level is related to an intensity level and each pixel is associated to a sky direction. An experimental system that is able to simultaneously supply images from the sky and solar irradiance data was developed using a commercial CCD camera. The sky relative radiance and luminance distributions for different sky conditions were also determined. The resultant maps agree with observations of the main characteristics of sky radiance and luminance distributions. 相似文献
This work discusses the potential of three multistage zeolite drying systems (counter-, co-, and cross-current) with a varying number of stages. The evaluation showed that for 2-4 stages with heat recovery the efficiency of the systems ranges between 80 and 90%. Additionally, by introducing a compressor, the latent heat in the exhaust air from the regenerator is recovered and used to heat the inlet air for an additional drying stage. As a result, for the counter-current drying system and compressor pressure 1.5-2 bar, a maximum energy efficiency of 120% is achieved, which results in halving the energy consumption compared to conventional drying systems. 相似文献
The application of municipal solid waste (MSW) compost increases both the trace metal loading and the organic matter in the soil. To characterize the quality and metal-binding capacity of the compost OM, we extracted humic acid (HA) and fulvic acid (FA) from mature MSW compost and analyzed them for elemental composition, acid-titratable functional groups, total metal content, and structural components (by 13C NMR). HA constituted 67% of all extracted humic substances and differed significantly from HAs of cultivated lands: The compost HA exhibited smaller molecular size, a higher N content, and lower aromaticity due to large amounts of saturated aliphatic components. Metal complexation studies of the extracted HA and FA were performed by equilibrium dialysis titration. The complexing capacity (CC) was highest for Cu: CCHA = 3357 and CCFA = 5221 μmol Cu g−1 of dissolved organic carbon (DOC) at pH 5. Zn and Cd were bound (at pH 7) in smaller concentrations: CCHA(Zn) = 2167, CCFA(Zn) = 2809, CCHA(Cd) = 2386, and CCFA(Cd) = 2468 μmol metal g−1 of DOC. Stability constants for binding on the strongest sites (pKint) were determined as pKintHA = 6.6 and pKintFA = 7.3 for Cu at pH 5; and pKintHA = 8.0 and pKintFA = 6.4 for Cd at pH 7. Since these measured parameters fall within the ranges of values obtained for soil humic substances, we conclude that in soils with little organic matter, compost addition will significantly increase the amount of highly reactive organic complexing agents for trace metals in the soil. 相似文献
When catalysts developed for crude oil hydroprocessing are used for syncrude, there are syncrude-specific peculiarities to consider. These relate to differences in the nature and abundance of heteroatoms, olefins, metal species, waxes and aqueous products. Some important aspects are (a) heat release during naphtha and distillate hydroprocessing is very high, but wax hydrocracking is almost isothermal; (b) syncrude is sulphur-free and the use of sulphided base-metal hydroprocessing catalysts require the addition of sulphur-containing compounds to the syncrude; (c) oxygenates strongly adsorb on some catalytic surfaces to affect catalytic behaviour; (d) carbonyl–carboxylic acid interconversion and water produced by hydrodeoxygenation (HDO) may result in catalyst degradation by acid and hydrothermal attack; (e) carboxylic acids in syncrude result in equipment corrosion and catalyst leaching; (f) metal carboxylates are the main metal-containing species in syncrude and are not removed by hydrodemetallation (HDM) catalysis, but by thermal decomposition. 相似文献
A system for the interactive editing and contouring of surfaces derived from empirical fields is described. The approach taken begins with the representation of a field as a general-order, nonuniform, tensor-product, B-spline surface. It provides an interactive display for editing the surface by control-vertex manipulation and a contouring algorithm that is specifically designed for the fast and robust contouring of B-spline surfaces. Interactive editing of the resulting model is feasible because of the local nature of editing changes when B-splines are used. The use of nonuniform B-splines gives the flexibility required to model highly irregular data efficiently 相似文献
Poly-p-phenylene (PPP) was synthesized from benzene according to the Kovacic method. Electrodes were made from this electronic insulator by cold- or hot-pressing of the loose, brown powder, under the addition of 7.5 wt. % soot (Corax L®, Degussa AG). The electrochemical insertion and removal of anions HSO−4, ClO−4 in this material in aqueous solutions of the corresponding acids was investigated by slow cyclic voltammetry.
Initially, only a surface layer of about 0.1 mm thickness takes part in the electrochemical processes, which are reversible. A maximum concentration of anions in the solid of [(−C6H4−)+7 A−] is attainable. The maximum degree of insertion is equal to 0.14. The insertion potential UI shifts strongly into the negative direction with increasing concentration c of the acid. A linear UI/c relationship is observed as in the case of graphite, where the intercalation potential is more positive by 20–200 mV for the same electrolyte. The round trip current efficiency for the insertion/removal cycle increases with increasing acid concentration attaining 100% in 14 M H2SO4 or 11.3 M CHlO4. For a given concentration, increases in the same order as with graphite (H2SO4 < HClO4 < HBF4), being somewhat lower for a given electrolyte composition. From anodic current limitation (jlim = 5–10 mA cm−2), a diffusion coefficient of about D = 2 × 10−7 cm2 s−1 is derived for the transport of anions in the bulk of PPP. The striking similarity of our results to former findings with graphite is thoroughly discussed. Some general conclusions are derived thereof. 相似文献