Chemical synthesis of some Schiff base-type polymers containing pyrrole units

Summary The synthesis of three Schiff-base type monomers containing pyrrole units was performed. Their polymerization was carried out by chemical oxidation with (NH₄)₂S₂O₈. Some preliminary thermal and electrical properties were determined.     

Long-term performance and binder chemical structure evolution of elastomeric bituminous geomembranes

This paper presents the results of uniaxial tensile tests, flow-rate measurements, and size-exclusion chromatography (SEC), which are used to evaluate the ageing of elastomeric bituminous geomembranes (BGMs) that were installed 6, 10, 15, 20, and 30 years ago in ponds at two different sites in France. SEC was used to detect oxidation and the absence of polymer in the bitumen at the surface of the 20- and 30-year-old BGMs. The results indicate that, for BGMs exposed less than 20 years, there was no oxidation or degradation of the polymer at the core. However, the elastomeric polymer was altered at the core of the 30-year-old BGM, resulting in an embrittlement of the bitumen, but this did not affect the mechanical properties of the glass veil and nonwoven polyester geotextile in the BGM core. Lastly, the flow rates through the BGM measured according to EN 14150 are still below 10^?6 m³ m^?2 d^?1, which indicates that the elastomeric bituminous GM is still watertight after 30 years of exposure.     

The photovoltaic effect and charge carrier mobility in layered compositions of bithiophene or related rotaxane copolymer with C<Subscript>70</Subscript> fullerene derivative

Organic photovoltaic cells with a bulk heterojunction have been manufactured in which the photoactive layer consists of a mixture of bithiophene copolymer or related rotaxane with a fullerene derivative (PC₇₀BM). The mobility of charge carriers in photoactive layers has been determined, the current–voltage characteristics of photovoltaic cells have been measured, and the energy level diagram of cell components has been constructed. It is established that the polyrotaxane component (macrocycle) insulates a part of thiophene fragments of the macromolecule, thus hindering the transport of carriers and leading to large energy losses for exciton dissociation, which results in a decreasing photovoltaic effect.     

Polymerization in magnetic field: XVIII. Influence of surfactant nature on the synthesis and thermal properties of poly(methyl methacrylate) and poly[(methyl methacrylate)‐co‐(epoxypropyl methacrylate)]

BACKGROUND: The possibility to use β‐cyclodextrin as biodegradable tensioactive and an electromagnetic field in order to improve the kinetic parameters of radical emulsion polymerization is of interest. Thus, the influence of different surfactants—sodium lauryl sulfate (SLS) and β‐cyclodextrin (CD)—on the pathway of emulsion polymerization of methyl methacrylate (MMA) and emulsion copolymerization of MMA with 2,3‐epoxypropyl methacrylate (GMA) performed with or without the presence of a continuous electromagnetic field (MF) was studied. RESULTS: The presence of the MF leads to a considerable increase of the conversion during the first part of the reaction if the classic surfactant (SLS) is used. The reactions performed without MF and with CD exhibit a decrease of the conversion and of the polymerization rate as compared with the variants using SLS. The swelling rate and the maximum degree of swelling vary with the surfactant nature and with the reaction conditions and MF presence. Data from thermogravimetry and differential scanning calorimetry evidence the dependences between the polymer characteristics and the preparation conditions. CONCLUSION: This research underlines the coupling possibilities of the influence of a MF—growth of the reaction rate and conversion explained through radical pairs mechanism—with a combination of the ‘cage’ effect and ‘conformational control’ afforded by CD. The presence of MF and CD during the syntheses leads to an increase of T_g and an increase of PMMA and P(MMA‐co‐GMA) thermal stability. Copyright © 2007 Society of Chemical Industry     

Synthesis and characterization of a fully aromatic polyazomethine with rotaxane architecture

This paper reports the preparation and characterization of a new aromatic polyazomethine with rotaxane architecture. The complex of β‐cyclodextrin and 1,4‐phenylenediamine was treated with N‐n‐butyl‐3,6‐diformylcarbazole, which is large enough to prevent dethreading. The polycondensation reaction was performed in N,N‐dimethylformamide leading to polyazomethine soluble in polar solvents. Measurements made by gel permeation chromatography of the dimethylformamide‐soluble (DMF) soluble polyazomethine show the presence of high molecular weight material. The structure and thermal properties of the resulting polymer were characterized by IR, ¹H NMR, TGA and DSC techniques. Copyright © 2003 Society of Chemical Industry     

Evaluation of the controlled release ability from the poly(2-hydroxyethyl methacrylate-co-3,9-divinyl-2,4,8,10-tetraoxaspiro[5.5]-undecane) polymer network synthesized in the presence of β-cyclodextrin

The study presents the possibility to use the 2-hydroxyethyl methacrylate--HEMA copolymer with a comonomer with spiroacetal moiety, 3,9-divinyl-2,4,8,10-tetraoxaspiro[5.5]-undecane)-U, as polymer network for loading the indomethacin--INN as drug model, and also, the controlled release evaluation of the prepared bioactive system. The macromolecular compounds were prepared by radical dispersion polymerization in the presence of a pair of surfactants. The use of cyclodextrin as surfactant allowed the building of the host-guest complexes by inclusion of hydrophobic molecules. Also, the cyclodextrin supplemented the hydrogen bonds and the hydrophobic interactions responsible for the stability of the achieved complexes. The copolymers composition and the INN inclusion onto the polymeric matrix were confirmed by FTIR analysis. The porous structure of the lyophilized P(HEMA-U) samples was illustrated by SEM images. The swelling studies evidenced the interdependence between P(HEMA-U) network properties and the spiroacetal moiety amount. Thus, the copolymers presented the increase of the equilibrium swelling degree with pH and temperature. Also, the polymeric matrices manifested dual sensitivity with pH and temperature. The in vitro release of the INN drug from the polymeric network as well as the in vivo experimental studies evidenced the benefit consequence of the spiroacetal compound presence. The clinical observation of the experimental groups does not show any behavioral modifications to suggest a possible toxic effect of these polymeric formulations with and without INN.     

Magnetic composites based on bovine serum albumin and poly(aspartic acid)

In this investigation, magnetic polymer composites were developed by using a magnetic field‐assisted strategy. To create the composite, an interpolymeric complex based on bovine serum albumin and poly(aspartic acid) used as a polymer matrix was mixed with pre‐synthesized magnetite nanoparticles and then exposed to a high‐frequency magnetic field. The formation of such composite was confirmed by FTIR‐spectra, scanning electron micrographs, dynamic light scattering measurements, and magnetic susceptibility analysis. The results revealed that the materials have a superparamagnetic behavior and an average hydrodynamic size ranging from 220 to 580 nm. The polymer matrix improved the colloidal stability of the magnetic filler. The proposed composites are expected to be promising candidates for biomedical applications, such as drug delivery systems. POLYM. ENG. SCI., 59:1409–1415 2019. © 2019 Society of Plastics Engineers     

Upon the characterization of semi-synthetic hydrogels based on poly (NIPAM) inserted onto collagen sponge

The preparation of a semi-synthetic hydrogel based on poly(N-isopropyl acrylamide-co-diethylene glycol diacrylate) inserted onto a collagen porous membrane, it was previous presented. The synthesis of the hydrogels was performed through radical copolymerization of N-isopropyl acrylamide (NIPAM) with diethylene glycol diacrylate (DEGDA) also as crosslinking agent, using ammonium persulfate as initiator and N,N,N′,N′-tetramethylethylene diamine activator, and it was achieved in the presence of the collagen matrix. In this paper the thus prepared hydrogels are characterized by Differential Scanning Calorimetry, Scanning Electron Microscopy and for their swelling capacities. A kinetic model was studied to investigate the swelling mechanism of the semi-interpenetrated polymeric network. The swelling behavior was found dependent on the hydrogel composition and to the external stimuli such as temperature and pH of environment. This manner of acting recommends these materials as smart materials with potential applications in tissue engineering and pharmaceutical field as for example bioproducts carrier matrices.     

The dual reciprocity boundary element method for solving Cauchy problems associated to the Poisson equation

This paper presents an application of the dual reciprocity method (DRM) to a class of inverse problems governed by the Poisson equation. Here the term inverse refers to the fact that the boundary conditions are not fully specified, i.e. they are not known for the entire boundary of the solution domain. In order to investigate the ability of the DRM to reconstruct the unknown boundary conditions using overspecified conditions on the accessible part of the boundary we consider some test problems involving circular, annular and square domains. Due to the ill-posed nature of the problem, i.e. the instabilities in the solution of these problems, the DRM is combined with the Tikhonov regularization method.     

Background subtraction via incremental maximum margin criterion: a discriminative subspace approach

Background subtraction is one of the basic low-level operations in video analysis. The aim is to separate static information called “background” from the moving objects called “foreground”. The background needs to be modeled and updated over time to allow robust foreground detection. Recently, reconstructive subspace learning models, such as principal component analysis (PCA) have been used to model the background by significantly reducing the data’s dimension. This approach is based on the assumption that the main information contained in the training sequence is the background meaning that the foreground has a low contribution. However, this assumption is only verified when the moving objects are either small or far away from the camera. Furthermore, the reconstructive representations strive to be as informative as possible in terms of well approximating the original data. Their objective is mainly to encompass the variability of the training data and so they give more effort to model the background in an unsupervised manner than to precisely classify pixels as foreground or background in the foreground detection. On the other hand, discriminative methods are usually less adapted to the reconstruction of data; although they are spatially and computationally much more efficient and often give better classification results compared with the reconstructive methods. Based on this fact, we propose the use of a discriminative subspace learning model called incremental maximum margin criterion (IMMC). The objective is first to enable a robust supervised initialization of the background and secondly a robust classification of pixels as background or foreground. Furthermore, IMMC also allows us an incremental update of the eigenvectors and eigenvalues. Experimental results on different datasets demonstrate the performance of this proposed approach in the presence of illumination changes.