Dynamic response and safety assessment of a batch process on cooling breakdown

Cooling breakdown in highly exothermic reaction processes may lead to runaway. The sensitivity and the safety assessment of a batch process on cooling breakdown are studied. The dependence of the minimum cooling time and the maximum allowable time of cooling breakdown for safe operation on the process parameters is investigated.     

Hand dexterity assessment based on mouse pointer trajectory measurements in children with learning disabilities

Universal Access in the Information Society - We present an investigation of the systematic differences in upper limb motor skills between children with learning disabilities (LDs) and children...     

A comparative study of important risk factors involved in offshore and domestic outsourcing of software development projects: A two-panel Delphi study

We investigated the risk factors of outsourced software development. Our first objective was to create empirically generated lists of risk factors for both domestically- and offshore-outsourced projects. Our second objective was to compare these two contexts: how do the risk factors change and which ones are most important in each. To address these objectives, we conducted two Delphi surveys to identify the important risk factors from a client perspective, in domestic and offshore settings. We qualitatively compared the results of the surveys to identify similarities and differences across their risk profiles. We identified three types of risks: those that appeared in both contexts; those that appeared in both but were exacerbated in the offshore context; and those that were unique to the offshore context. Our findings suggested that traditional project management risks were important in both contexts; however, the offshore context seemed to be more vulnerable to some traditional risks as well as factors that were unique to it.     

Decentralized optimality conditions of stochastic differential decision problems via Girsanov’s measure transformation

In this paper, we apply two methods to derive necessary and sufficient decentralized optimality conditions for stochastic differential decision problems with multiple Decision Makers (DMs), which aim at optimizing a common pay-off, based on the notions of decentralized global optimality and decentralized person-by-person (PbP) optimality. Method 1: We utilize the stochastic maximum principle to derive necessary and sufficient conditions which consist of forward and backward Stochastic Differential Equations (SDEs), and conditional variational Hamiltonians, conditioned on the information structures of the DMs. The sufficient conditions for decentralized PbP optimality are local conditions, closely related to the necessary conditions for decentralized PbP optimality. However, under certain convexity condition on the Hamiltonian, and a global version of the sufficient conditions for decentralized PbP optimality, we show decentralized global optimality. Method 2: We utilize the value processes of decentralized PbP optimal policies, we relate them to solutions of backward SDEs, we identify sufficient conditions for decentralized PbP optimality, and we show these are precisely those derived via the maximum principle. For both methods, as usual, we utilize Girsanov’s theorem to transform the initial decentralized stochastic optimal decision problems, to equivalent decentralized stochastic optimal decision problems on a reference probability space, in which the controlled process and the information processes which generate part of the information structures of the DMs, are independent of any of the decisions.     

Probing Protein Folding with Sequence-Reversed α-Helical Bundles

Recurrent protein folding motifs include various types of helical bundles formed by α-helices that supercoil around each other. While specific patterns of amino acid residues (heptad repeats) characterize the highly versatile folding motif of four-α-helical bundles, the significance of the polypeptide chain directionality is not sufficiently understood, although it determines sequence patterns, helical dipoles, and other parameters for the folding and oligomerization processes of bundles. To investigate directionality aspects in sequence-structure relationships, we reversed the amino acid sequences of two well-characterized, highly regular four-α-helical bundle proteins and studied the folding, oligomerization, and structural properties of the retro-proteins, using Circular Dichroism Spectroscopy (CD), Size Exclusion Chromatography combined with Multi-Angle Laser Light Scattering (SEC-MALS), and Small Angle X-ray Scattering (SAXS). The comparison of the parent proteins with their retro-counterparts reveals that while the α-helical character of the parents is affected to varying degrees by sequence reversal, the folding states, oligomerization propensities, structural stabilities, and shapes of the new molecules strongly depend on the characteristics of the heptad repeat patterns. The highest similarities between parent and retro-proteins are associated with the presence of uninterrupted heptad patterns in helical bundles sequences.     

Isotopic and Elemental Authenticity Markers: a Case Study on Cypriot Wines

This study monitors variations in isotopes and elements in relation to grape variety, environmental factors and provenance in order to address the wine authenticity issue. Inductively coupled plasma atomic emission spectroscopy (ICP-AES) assessed the wines’ elemental content. Site-specific nuclear isotope fractionation-nuclear magnetic resonance and isotope ratio mass spectrometry methodologies determined in authentic and commercial wines the distribution of the naturally occurring stable isotopes of the deuterium/hydrogen (D/H) ratios and carbon (¹³C/¹²C) in ethanol of wine and oxygen ratio (¹⁸O/¹⁶O) in wine water. Chemometrics delineated the elements and isotopes responsible for wine classification. Specifically, unsupervised principal component analysis (PCA) framed the importance of grape variety and provenance, while supervised analysis pinpointed the vineyard effect and highlighted the contribution of the vintage year. Validation steps ensured that the extracted models do not predict randomly and their results are reliable. In fact, the acquired results can be incorporated to the EU Wine Isotopic Databank database providing both a guide and a tool for eventual candidatures for denomination of origin and support both Cypriot wine and winemakers. In this context, this research contributes to authenticity assurance of wines and adds value to final products, while it helps controlling hazards arising from environmental changes.     

Solvothermal synthesis,nanostructural characterization and gas cryo-adsorption studies in a metal–organic framework (IRMOF-1) material

A nanoporous metal–organic framework material, exhibiting an IRMOF-1 type crystalline structure, was prepared by following a direct solvothermal synthesis approach, using zinc nitrate and terephthalic acid as precursors and dimethylformamide as solvent, combined with supercritical CO₂ activation and vacuum outgassing procedures. A series of advanced characterization methods were employed, including scanning electron microscopy, Fourier-transform infrared radiation spectroscopy and X-ray diffraction, in order to study the morphology, surface chemistry and structure of the IRMOF-1 material directly upon its synthesis. Porosity properties, such as Brunauer–Emmet–Teller (BET) specific area (～520 m²/g) and micropore volume (～0.2 cm³/g), were calculated for the activated sample based on N₂ gas sorption data collected at 77 K. The H₂ storage performance was preliminary assessed by low-pressure (0–1 bar) H₂ gas adsorption and desorption measurements at 77 K. The activated IRMOF-1 material of this study demonstrated a fully reversible H₂ sorption behavior combined with an adequate gravimetric H₂ uptake relative to its BET specific area, thus achieving a value of ～1 wt.% under close-to-atmospheric pressure conditions.     

Experimental investigation on the combustion behaviour of pre-dried Greek lignite

The present paper includes the results of the combustion tests with Greek dried lignite performed at a 1 MWth semi industrial scale pulverized coal combustion facility. Scope of the campaign is the investigation of the combustion behaviour of Greek lignite, i.e. temperature fields, ignition, burnout, emissions, as well as slagging and fouling tendency, while firing with varying levels of recirculated flue gas. Dry coal co-firing conditions in a large scale boiler are simulated by adjusting the volume flow of recirculated flue gas.Two test series representing different boiler operation modes are performed. During the first series the maximum flue gas temperature increase, when co-firing dry coal, is determined, while in the second test series the needed load decrease, in order to keep constant furnace outlet temperature in dry coal co-firing conditions is recorded. A detailed measurement set is carried out including temperature profiles, emissions, fuel, fly ash sampling and slagging and fouling investigations through the installation of dedicated deposition probes.The anticipated increase of the furnace temperature profiles by decreasing the inserted recirculated flue gas is confirmed by the experimental results. No clear trend of dry coal co-combustion on the emissions' behaviour is noticed, while dry coal firing appears to have a moderate effect on the deposition behaviour of Greek lignite. These preliminary investigations indicate that no significant operational problems are expected during a potential future demonstration of dry lignite co-firing in a Greek large scale boiler.     

Si nanowires by a single-step metal-assisted chemical etching process on lithographically defined areas: formation kinetics

In this paper, we investigate the formation kinetics of Si nanowires [SiNWs] on lithographically defined areas using a single-step metal-assisted chemical etching process in an aqueous HF/AgNO₃ solution. We show that the etch rate of Si, and consequently, the SiNW length, is much higher on the lithographically defined areas compared with that on the non-patterned areas. A comparative study of the etch rate in the two cases under the same experimental conditions showed that this effect is much more pronounced at the beginning of the etching process. Moreover, it was found that in both cases, the nanowire formation rate is linear with temperature in the range from 20°C to 50°C, with almost the same activation energy, as obtained from an Arrhenius plot (0.37 eV in the case of non-patterned areas, while 0.38 eV in the case of lithographically patterned areas). The higher etch rate on lithographically defined areas is mainly attributed to Si surface modification during the photolithographic process.PACS: 68; 68.65-k.     

Dependence of off-leakage current on channel film quality in poly-Si thin-film transistors and analysis using device simulation

The dependence of off-leakage current on channel film quality in poly-Si thin-film transistors has been analyzed using two-dimensional device simulation. It is found that the off-leakage current decreases as the intragrain trap density decreases for the low V_gs. This is because the Phonon-assisted tunneling with Poole-Frenkel effect is the dominant mechanism of the carrier generation and the generation rate of carrier pair decreases as the intragrain trap density decreases. On the other hand, the off-leakage current slightly increases as the intragrain trap density decreases for the high V_gs. This is because the band-to-band tunneling is the dominant mechanism and the influence of the intragrain trap density to the carrier conductance is larger than that to the generation rate.