Influence of pH on the DSSC Performance of Template Assisted SnO2 Nanostructures

Journal of Inorganic and Organometallic Polymers and Materials - This paper reports the performance of alizarin based SnO2 dye-sensitized solar cells. A novel template assisted method has been...     

Deformation twinning during impact – numerical calculations using a constitutive theory based on multiple natural configurations

When materials such as Armco iron, titanium etc., are subject to impact it can be observed that two basic inelastic processes take place – slip and deformation twinning. Of these processes, inelasticity associated with the slip mechanism has received considerable attention. For example, Zerilli and Armstrong (1988) modeled the Taylor impact test for a variety of materials using traditional plasticity theories. They found that there was a significant discrepancy between the theoretical and experimental results for some materials. They attributed this to the fact that they had neglected deformation twinning in their models. Subsequent metallurgical studies have indicated that twinning had indeed taken place in these materials. In this study, we focus on the inelastic processes solely due to deformation twinning (i.e., neglecting slip). We model these processes using the approach of Rajagopal and Srinivasa (1995, 1997) and Srinivasa et al., (1997), the results of which are briefly summarized in section 2.1. In order to better understand the twinning process, we study the Taylor impact test for a 2-D slab under the assumption that only deformation twinning takes place and solve the governing dynamical equations by using the finite element method. The results show that the twinned zone is concentrated near the point of impact and indeed it contributes significantly to the overall permanent shape change due to the impact.     

Comparative effects of cobalt carboxylates on the thermo‐oxidative degradation of LDPE films

This article reports the effect of three cobalt carboxylates—cobalt stearate (CoSt₃), cobalt palmitate (CoPal₃), and cobalt laurate (CoLau₃)—on the thermo‐oxidative degradation of low‐density polyethylene (LDPE) films prepared by sheeting process. The carboxylates were blended with LDPE in the concentration range of 0.05–0.2% (w/w). The degradation was monitored by techniques such as FTIR spectroscopy, change in the mechanical properties (tensile strength and elongation at break), viscometry, surface electron microscopy, melt flow index measurements, and apparent density measurements. Studies indicate that films containing these additives are highly susceptible to thermo‐oxidative degradation. Oxygen containing functionalities such as carbonyl and vinyl species are generated on the surface of polyethylene because of thermo‐oxidation, as indicated by FTIR studies. This oxidative process is accelerated in the presence of cobalt carboxylates. The degradation of LDPE was found to increase proportionally with concentration as well as with increasing chain length of the cobalt carboxylate, and follow the order CoSt₃ > CoPal₃ > CoLau₃. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3758–3765, 2007     

Yield optimization for complex reactor systems

For complex reactions, the choice of reactor type is important for attaining optimum product yields. Strategies for specifying reactor types have beenIn this paper, product yield in a Van de Vusse reaction scheme has been studied for a wide range of the rate constants, in a reactor system consisting     

Equivalence of classicality and separability based on P phase–space representation of symmetric multiqubit states

Classical and quantum world views differ in peculiar ways. Understanding decisive quantum features—for which no classical explanation exist—and their interrelations is of foundational interest. Moreover, recognizing non-classical features carries practical significance in information processing tasks as it offers insights as to why quantum protocols work better than their classical counterparts. We focus here on two celebrated notions of non-classicality viz., negativity of P phase–space representation and entanglement in symmetric multiqubit systems. We prove that they imply each other.     

Fully developed flow of granular materials down a heated inclined plane

Summary The mechanics of flowing granular materials such as coal, sand, metal ores, etc., and their flow characteristics have received considerable attention in recent years as it has relevance to several important technological problems. In a number of instances, these materials are also heated prior to processing, or cooled after processing. The governing equations for the flow of granular materials, taking into account the heat transfer mechanism by conduction, are derived using a continuum model (cf. Goodman and Cowin [1], [2], Rajagopal and Massoudi [3]). For a fully developed flow of these materials down an inclined plane, the equations reduce to a system of coupled non-linear ordinary differential equations. The resulting boundary value problem is solved numerically and the results are presented for cases where the viscosity and thermal conductivity are assumed to be functions of the volume fraction. It is shown that the equations admit multiple solutions for certain values of the parameters.List of symbols D Symmetric part of the velocity gradient - K thermal conductivity - L velocity gradient - T Cauchy stress tensor - b body force - h characteristic height - q heat flux - r radiating heat - u velocity vector - angle of inclination of the inclined plane with the horizontal - specific internal energy - distributed mass density - temperature - volume fraction - bulk mass density     

Cross‐polarization reduction of microstrip antenna using microwave absorbers

In this article, a metamaterial inspired microwave absorber is used to reduce the cross‐polarization (XP) level of the radiated wave in microstrip antenna (MSA). A microwave absorber unit‐cell has been analyzed and implemented to reduce the cross polarization (XP) level in a single element and a 2 × 2 microstrip patch array antennas. The antennas have been designed on a FR‐4 substrate of thickness 0.8 mm at 10.1 GHz center frequency. The 2 × 2 patch array antenna with and without the absorbers have been experimentally verified for the S11 parameter, the radiation pattern, and the XP suppression in H‐plane and a good comparison has been found.