A light refractory concrete for thermal insulation

Compositions have been developed for nonshrinking vibrocast thermally insulating light refractory concretes with densities of 1.0, 1.3, 1.5, and 1.8 g/cm³ for temperatures of use up to 1400°C. The structure and properties have been examined for the concrete of density 1.3 g/cm³. __________ Translated from Novye Ogneupory, No. 4, pp. 29–32, April, 2008.     

Turbulent flow of a chemically reactive gas suspension in a channel with a blow

The influence of the chemical reactions occurring in the gas phase of a gas suspension flowing in a channel with penetrable walls and the combustion of the condensed-impurity particles in this flow on its gasdynamic structure has been investigated. It is shown that the order of the system of equations defining a flow of a chemically reactive gas suspension with a homogeneous exothermic reaction proceeding at a definite rate and a heterogeneous combustion of the condensed-phase particles can be decreased if certain assumptions are mode. The distributions of the parameters of the gas and dispersed phases were calculated as functions of the rate of blow and the sizes of the particles. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 4, pp. 91–98, July–August, 2007.     

Measurement of forming trajectories during drilling

Results are provided for an experimental study of forming trajectories during drilling and the effect on them of cutting speed and drilling depth. __________ Translated from Izmeritel’naya Tekhnika, No. 8, pp. 31–33, August, 2006.     

Effect of coke quality on blast-furnace performance indices

The quality of coke has a strong effect on the performance indices of a blast furnace. For a furnace to operate with high productivity and a low coke rate, it is necessary to use coke with high strength characteristics. The Novolipetsk Metallurgical Combine has conducted studies of the effect of coke quality on the operation of blast furnaces of different sizes. The quality of the coke was evaluated on the basis of the following indices: CSR, CRL, the cold-strength indices M₁₀ and M₂₅, and the integral coke-quality index I_g.c used by the Sidmar company. Furnace productivity, coke rate, and the totterman index (DMI) were also used for the sake of comparison.     

Release of salicylic acid through poly(vinyl alcohol)/poly(vinyl pyrrolidone) and poly(vinyl alcohol‐g‐N‐vinyl‐2‐pyrrolidone) membranes

A controlled release profile of salicylic acid (SA) for transdermal administration has been developed. Poly (vinyl alcohol) (PVA) and Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) (PVP) blended preparations were used to prepare the membranes by solvent‐casting technique. The release of the drug from the membranes was evaluated at in vitro conditions. The effects of PVA/PVP (v/v) ratio, pH, SA concentration and temperature were investigated. 60/40 (v/v) PVA/PVP ratio was found to be the best ratio for the SA release. Increase in pH and temperature was observed to increase the transport of SA. Instead of blending PVA with PVP, N‐Vinyl‐2‐pyrrolidone (VP) was grafted onto the PVA and the delivery performance for SA was compared with that of the blended PVA/PVP membranes. Grafted membranes gave higher transport percentages than the blended membranes. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:1244–1253, 2006     

Preparation of segmented, high molecular weight, aliphatic poly(ether-urea) copolymers in isopropanol. In-situ FTIR studies and polymer synthesis

The use of isopropanol (IPA) as the reaction solvent for the preparation of high molecular weight segmented polyether-urea copolymers based on cycloaliphatic diisocyanates was investigated. Reactivity of IPA with bis(4-isocyanatohexyl)methane (HMDI) and isophorone diisocyanate (IPDI) was studied between 0 and 40 °C using in-situ FTIR spectroscopy. HMDI, which has secondary isocyanate groups, shows a very slow reaction with a large excess of IPA at 0 and 23 °C. Analysis of the kinetic data indicates an activation energy of 51 kJ/mol for the reaction between HMDI and IPA. As expected, IPDI, which has both a primary and a secondary isocyanate (NCO) group, reacts faster with IPA compared with HMDI, which only has secondary NCO groups. However, the rate of reaction of IPDI with IPA at 0 °C is extremely slow (approximately 1% consumption of isocyanate in 60 min) thus allowing the use of IPA as the reaction solvent for polyether-urea synthesis. Preparation of high molecular weight, high-strength HMDI and IPDI based polyether-urea segmented copolymers in IPA has been demonstrated. Thermal analysis and stress-strain analyses were used to characterize the products.     

Modification of polyolefins with silicone copolymers. II. Thermal,mechanical, and tribological behavior of PP and HDPE blended with silicone copolymers

Thermoplastic polyolefin (TPO) films with permanent, silicone‐rich, low‐friction, low‐abrasion surfaces were obtained by melt blending of high‐density polyethylene (HDPE) and polypropylene (PP) with polydimethylsiloxane (PDMS)‐containing block copolymers. Two different block copolymers, a siloxane–urea segmented copolymer and a polycaprolactone‐b‐PDMS triblock copolymer were used as modifiers at levels between 0.1 and 5.0% by weight. Blends were prepared in a twin‐screw extruder. Modified films displayed surfaces with very low friction coefficients and high abrasion resistance, which depended on the type and the level of additive incorporated into the system. Bulk properties of these modified systems, such as crystallization and melting behavior or tensile properties, were not affected. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 535–540, 2002; DOI 10.1002/app.10279     

Stochastic two-sided U-type assembly line balancing: a genetic algorithm approach

In this paper, a novel stochastic two-sided U-type assembly line balancing (STUALB) procedure, an algorithm based on the genetic algorithm and a heuristic priority rule-based procedure to solve STUALB problem are proposed. With this new proposed assembly line design, all advantages of both two-sided assembly lines and U-type assembly lines are combined. Due to the variability of the real-life conditions, stochastic task times are also considered in the study. The proposed approach aims to minimise the number of positions (i.e. the U-type assembly line length) as the primary objective and to minimise the number of stations (i.e. the number of operators) as a secondary objective for a given cycle time. An example problem is solved to illustrate the proposed approach. In order to evaluate the efficiency of the proposed algorithm, test problems taken from the literature are used. The experimental results show that the proposed approach performs well.