Heat-integrated reactor concepts for catalytic reforming and automotive exhaust purification

Optimal solutions in environmental catalysis require a well-coordinated development of catalysts and of process design. This contribution is devoted to energy integrated design concepts for fuel reforming and for automotive exhaust purification. The examples presented demonstrate the importance of an innovative process design for optimal utilization of existing catalysts and show the potential of future developments.

New concepts for steam reforming through the efficient coupling of the endothermic reforming reaction with an exothermic combustion reaction are discussed in the first part. These concepts have been implemented for methanol steam reforming in a counter-current reactor with distributed side feed of burner gas and for methane steam reforming in a modular reactor with a co-current reaction section for the endothermic and the combustion reaction and attached counter-current heat exchangers. Both applications employ the so-called folded sheet reactor design, which ensures an excellent heat transfer between the reforming and combustion channels and efficient heat recovery.

A similar design solution is introduced for the apparently different case of automotive exhaust purification. The proposed concept aims at decoupling exhaust after-treatment from engine control. Its main component is a counter-current heat exchanger with integrated purification stages for HC-oxidation, NO_X storage and reduction and soot filtering. A small catalytic burner at the hot end of the heat exchanger provides both heat and oxidizing or reducing agents on demand. A new soot filter design allows for safe soot filter regeneration.     

Kinetic instabilities in heterogeneously catalyzed reactions—I: Rate multiplicity with langmuir-type kinetics

The question under which conditions kinetic instabilities can be described by Langmuir type kinetics is studied using a fairly general model for the surface reactionpA + qB → C. This paper is concerned with the occurrence of rate multiplicities (ignition-extinction phenomena). It is shown that rate multiplicity can be caused by the competing chemisorption of A and B upon the same active sites of the catalyst. Rate multiplicity can occur if at least one of the chemisorption or reaction steps is of second order. No rate multiplicity can be expected, if either A or B reacts via an Eley-Rideal type mechanism.     

SOLAR ASSISTED DRIER FOR SEEDS

A high performance solar assisted seed dryer has been designed and constructed at a seed processing station in Hungary.

The dryer is arranged in a building specially designed for this purpose, the roof of it serves as solar air collector field. Two drying cells with individual fans of two RPM stages are formed in the building. Drying air preheated by the collector can optionally be distributed between the two drying cells. Material to be dried can be arranged either in a static bed or in containers depending on the requirements. Moist air leaving the bed streams out of the drying cells through openings of the side walls. As auxiliary air heater a natural gas generator is used.