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排序方式: 共有436条查询结果,搜索用时 15 毫秒
1.
The tetrametallic ruthenium-oxo-hydroxo-hydride complex {[(PCy(3))(CO)RuH](4)(mu(4)-O)(mu(3)-OH)(mu(2)-OH)} (1) was synthesized in two steps from the monomeric complex (PCy(3))(CO)RuHCl (2). The tetrameric complex 1 was found to be a highly effective catalyst for the transfer dehydrogenation of alcohols. Complex 1 showed a different catalytic activity pattern towards primary and secondary benzyl alcohols, as indicated by the Hammett correlation for the oxidation reaction of p-X-C(6)H(4)CH(2)OH (rho = -0.45) and p-X-C(6)H(4)CH(OH)CH(3) (rho = +0.22) (X = OMe, CH(3), H, Cl, CF(3)). Both a sigmoidal curve from the plot of initial rate vs [PhCH(OH)CH(3)] (K(0.5) = 0.34 M; Hill coefficient, n = 4.2+/-0.1) and the phosphine inhibition kinetics revealed the highly cooperative nature of the complex for the oxidation of secondary alcohols. 相似文献
2.
Borràs J Casanova J Cristea T Gheorghe A Scozzafava A Supuran CT Tudor V 《Metal-Based Drugs》1996,3(3):143-148
Ternary Ni(II) complexes of hydrazine and eight heterocyclic sulfonamides possessing carbonic anhydrase (CA) inhibitory properties, were prepared and characterized by elemental analysis, spectroscopic, magnetic, thermogravimetric, and conductimetric measurements. The complexes behave as strong inhibitors for two isozymes (I and II) of carbonic anhydrase. 相似文献
3.
Iuliana Armaş Mihaela Gheorghe Ana Maria Lendvai Paul Daniel Dumitru Octavian Bădescu Alexandru Călin 《International journal of remote sensing》2016,37(23):5565-5580
This research aims to complex validate radar displacement products over Bucharest based on Global Navigation Satellite System or GNSS. Validation was represented by the comparison of the recent TerraSAR-X (TSX) displacement results with field GNSS data. For this purpose, 24 and 27 high-resolution images acquired from the TSX satellite between 2011 and 2014 were processed by Permanent Scatterer Inteferometry (PSI) and Small BASeline Subset (SBAS) – interferometric techniques using synthetic aperture radar (SAR) images. The images were selected from a larger pool of SAR images, after consulting weather databases, which helped eliminate the images acquired under adverse weather conditions. GNSS locations were cross-checked on high-resolution optical images and 21 ground points (including three permanent stations) were selected. All these points were (1) characterized by high coherence on radar images; (2) were on the ground; (3) were situated in large vacant spaces; and (4) far away from radar obstacles such as trees. A major challenge in achieving the research goal was to overcome the lack of permanent stations at the ground level within the area of Bucharest. Instead of permanent stations, our team designed and installed forced centring systems that remained stable over time, eliminating the instalment errors of GNSS receivers. The line-of-site (LOS) components derived from GNSS data have been compared with those of the SAR scatterers closest to the GNSS markers (never coinciding). For each location, the vertical reading was projected in the LOS of the SAR sensor. These readings were compared with the displacement values determined at the locations of permanent scatterers (PSs) within 100 m from the GNSS nodes, by eliminating all scatterers on buildings. The comparison has shown a good agreement. 相似文献
4.
A model (consisting of rv-systems), a core programming language (for developing rv-programs), several specification and analysis techniques appropriate for modeling, programming and reasoning about interactive computing systems have been recently introduced by Stefanescu using register machines and space-time duality, see [Stefanescu, G. Interactive systems with registers and voices. Fundamenta Informaticae 73 (2006), 285–306. (Early draft, School of Computing, National University of Singapore, July 2004.)]. After that, Dragoi and Stefanescu have developed structured programming techniques for rv-systems and their verification, see, e.g., [Dragoi, C., and G. Stefanescu. Structured programming for interactive rv-systems. Institute of Mathematics of the Romanian Academy, IMAR Preprint 9/2006, Bucharest 2006. Dragoi, C., and G. Stefanescu. Towards a Hoare-like logic for structured rv-programs. Institute of Mathematics of the Romanian Academy, IMAR Preprint 10/2006, Bucharest, 2006. Dragoi, C., and G. Stefanescu. Implementation and verification of ring termination detection protocols using structured rv-programs. Annals of University of Bucharest, Mathematics-Informatics Series, 55 (2006), 129–138. Dragoi, C., and G. Stefanescu. Structured interactive programs with registers and voices and their verification. Draft, Bucharest, January 2007. Dragoi, C., and G. Stefanescu. On compiling structured interactive programs with registers and voices. In: “Proc. SOFSEM 2008,” 259–270. LNCS 4910, Springer, 2008.].In the present paper a kernel programming language AGAPIA v0.1 for interactive systems is introduced. The language contains definitions for complex spatial and temporal data, arithmetic and boolean expressions, modules, and while-programming statements with their temporal, spatial, and spatio-temporal versions. In AGAPIA v0.1 one can write programs for open processes located at various sites and having their temporal windows of adequate reaction to the environment. The main technical part of the paper describes a typing system for AGAPIA v0.1 programs. 相似文献
5.
Starting from the idea of determinism in membrane systems, we introduce a language generating device consisting of morphisms
placed in the nodes of a tree. Initial strings are given in the leaves; by iteratively applying the morphisms to them, we
produce new strings, which are collected in the root of the tree. Such a device is called a tree-system of morphisms (in short, a T system). We investigate here the power of T systems, both in the extended (a terminal alphabet is considered
and only strings over it are accepted) and non-extended case, mainly in comparison with classes of languages in Lindenmayer
hierarchy.
Received: 8 February 2001 / 18 September 2001 相似文献
6.
We propose an alternative approach to generate languages by means of P systems: building up an appropriate representation
for a string by means of a corresponding membrane structure and then generating the string by visiting the membrane structure
according to a well-specified strategy. To this aim, we consider P systems with active membranes, allowing membrane creation
or division or duplication and dissolution, where the output of a computation may be obtained either by visiting the tree
associated with the membrane structure, or by following the traces of a specific object, called traveller, or sending out
the objects. For each of these approaches, we provide characterizations of recursively enumerable languages based on P systems
that use different sets of operations for modifying the membrane structure.
Francesco Bernardini: He started his Ph.D. at the University of Sheffield in December 2002 after having previously got a master degree in Computer
Science from the University of Pisa in Italy. His research is dedicated to the study of theoretical aspects of membrane computing
(P systems) and discrete models of biological systems based on P systems.
Marian Gheorghe, Ph.D.: His main research interests are in computational models and their applications to software modelling and testing, formal
specifications of agent based systems, software engineering. He was investigating computational power of various generative
devices (regular, context-free, fully initial; grammar systems; L-systems and variants). He is currently interested in natural
computing (membrane calculus) and biological modelling. 相似文献
7.
Laura Mannarino Lara Paracchini Federica Pezzuto Gheorghe Emilian Olteanu Laura Moracci Luca Vedovelli Irene De Simone Cristina Bosetti Monica Lupi Rosy Amodeo Alessia Inglesi Maurizio Callari Serena Penpa Roberta Libener Sara Delfanti Antonina De Angelis Alberto Muzio Paolo Andrea Zucali Paola Allavena Giovanni Luca Ceresoli Sergio Marchini Fiorella Calabrese Maurizio DIncalci Federica Grosso 《International journal of molecular sciences》2022,23(10)
8.
R Manjarres-García GE Escorcia-Salas ID Mikhailov J Sierra-Ortega 《Nanoscale research letters》2012,7(1):489
ABSTRACT: The electronic states of a singly ionized on-axis double-donor complex (D2+) confined in two identical vertically coupled, axially symmetrical quantum dots in a threading magnetic field are calculated. The solutions of the Schrodinger equation are obtained by a variational separation of variables in the adiabatic limit. Numerical results are shown for bonding and antibonding lowest-lying artificial molecule states corresponding to different quantum dot morphologies, dimensions, separation between them, thicknesses of the wetting layers, and magnetic field strength. 相似文献
9.
Smaranda Iliescu Aurelia Pascariu Nicoleta Plesu Adriana Popa Lavinia Macarie Gheorghe Ilia 《Polymer Bulletin》2009,63(4):485-495
Polyphosphonates, polyphosphates, polyarylazophosphonates and polyarylazophosphates were synthesized by a new alternative to the classical phase transfer catalysis, respectively, the modified inverse phase transfer catalysis (IPTC) polycondensation of various phenylphosphonic (phosphoric) dichlorides (phenylphosphonic dichloride, phenylphosphoric dichloride, p-chlorophenylphosphoric dichloride) with bisphenols: bisphenol A, tetrabromobisphenol A, bis-(4-hydroxyphenyl)methane (bisphenol F), 4,4′-dihydroxyazobenzene. The polymers were characterized by infrared spectroscopy and magnetic resonance (1H-NMR, 31P-NMR, 13C-NMR) spectroscopy. Yields in the range of 63.5–85% and molecular weights (M w) of ~2,000–8,200 g mol?1 were obtained. Polyphosphonates were stable up 210–270 °C and polyphosphates up 190–220 °C in air atmosphere. For a correct estimation of the thermal behavior of similar compounds, a kinetic analysis using a modified version of Non Parametric Kinetic method for representative polyphosphonate and polyphosphate was realized. The studies made on the hydrolytic degradation of the synthesized polyphosphates show that the most stable polymer under alkali-catalyzed degradation is the polyphosphate obtained by IPTC of phenylphosphoric dichloride and bisphenol A. 相似文献
10.
Alexander Balatskiy Ilia Ozhimalov Maria Balatskaya Alexandra Savina Julia Filatova Natalia Kalinina Vladimir Popov Vsevolod Tkachuk 《International journal of molecular sciences》2022,23(3)
The local development of atherosclerotic lesions may, at least partly, be associated with the specific cellular composition of atherosclerosis-prone regions. Previously, it was demonstrated that a small population of immature vascular smooth muscle cells (VSMCs) expressing both CD146 and neuron-glial antigen 2 is postnatally sustained in atherosclerosis-prone sites. We supposed that these cells may be involved in atherogenesis and can continuously respond to angiotensin II, which is an atherogenic factor. Using immunohistochemistry, flow cytometry, wound migration assay xCELLigence system, and calcium imaging, we studied the functional activities of immature VSMCs in vitro and in vivo. According to our data, these cells do not express nestin, CD105, and the leptin receptor. They are localized in atherosclerosis-prone regions, and their number increases with age, from 5.7% to 23%. Immature VSMCs do not migrate to low shear stress areas and atherosclerotic lesions. They also do not have any unique response to angiotensin II. Thus, despite the localization of immature VSMCs and the presence of the link between their number and age, our study did not support the hypothesis that immature VSMCs are directly involved in the formation of atherosclerotic lesions. Additional lineage tracing studies can clarify the fate of these cells during atherogenesis. 相似文献