A Fullerene-Like Ball in a Second Century Roman Mosaic?

A fullerene-like ball is found in a second century mosaic from Porta Marina Roman Baths near Ostia. Although it could be an hexadecahedral ball (28 vertices, 4 hexagonal and 12 pentagonal faces), it is probably an erroneous representation of a dodecahedral ball.     

Hybrid Approach for Addressing Uncertainty in Risk Assessments

Parameter uncertainty is a major aspect of the model-based estimation of the risk of human exposure to pollutants. The Monte Carlo method, which applies probability theory to address model parameter uncertainty, relies on a statistical representation of available information. In recent years, other uncertainty theories have been proposed as alternative approaches to address model parameter uncertainty in situations where available information is insufficient to identify statistically representative probability distributions, due in particular to data scarcity. The simplest such theory is possibility theory, which uses so-called fuzzy numbers to represent model parameter uncertainty. In practice, it may occur that certain model parameters can be reasonably represented by probability distributions, because there are sufficient data available to substantiate such distributions by statistical analysis, while others are better represented by fuzzy numbers (due to data scarcity). The question then arises as to how these two modes of representation of model parameter uncertainty can be combined for the purpose of estimating the risk of exposure. This paper proposes an approach (termed a hybrid approach) which combines Monte Carlo random sampling of probability distribution functions with fuzzy calculus. The approach is applied to a real case of estimation of human exposure, via vegetable consumption, to cadmium present in the surficial soils of an industrial site located in the north of France. The application illustrates the potential of the proposed approach, which allows the uncertainty affecting model parameters to be represented in a way that is consistent with the information at hand. Also, because the hybrid approach takes advantage of the “rich” information provided by probability distributions, while retaining the conservative character of fuzzy calculus, it is believed to hold value in terms of a “reasonable” application of the precautionary principle.     

Packaging production and consumption in the world and in some industrialized countries

This paper reports on statistics concerning production and consumption of packaging (as a whole or per capita) in Europe, in the USA, in Japan and in the world. Data have been provided by National Trade Associations and by consultants specialized in packaging and in economics. It is estimated that in 1986 the global consumption of packaging reached 150 millions of tonnes valued at 1200 billions of French francs. Consumption could reach 247 million tonnes by the year 2000. Paper and board have the highest consumption rate, but plastics have the highest rate of growth. Nevertheless, consumption per capita in the industrialized countries will be more than 10 times the consumption in underdeveloped countries. The packaging industries take fourth place in the USA, sixth in Western Germany and twelfth in France. In Europe, as in the world, paper and board is the material most used (40%), with glass (a high density material) taking second place and plastics third, i.e. if we consider the quantity of materials and not their value. Some differences appear between the various countries, but the figures for USA and Japan lead to similar conclusions. The survey shows clearly that the USA as compared with Europe has twice the consumption of packaging materials per capita and this difference is even greater compared with the rest of the world.     

Object-oriented specification of a bandwidth management system for ATM-based virtual private networks

This paper describes the specification of a bandwidth management system for ATM-based virtual private networks (vpn). Such a system allows a vpn customer to dynamically modify the bandwidth allocated to vpn connections. The analysis process focuses on the service management information model and interfaces required to provide that service to the customer. The specification work is performed according to a second generation object-oriented development method called Fusion. The vpn service and management architectures as well as the different actors involved are also described in detail.     

Distributed constraint optimization with MULBS: A case study on collaborative meeting scheduling

This paper introduces MULBS, a new DCOP (distributed constraint optimization problem) algorithm and also presents a DCOP formulation for scheduling of distributed meetings in collaborative environments. Scheduling in CSCWD can be seen as a DCOP where variables represent time slots and values are resources of a production system (machines, raw-materials, hardware components, etc.) or management system (meetings, project tasks, human resources, money, etc). Therefore, a DCOP algorithm must find a set of variable assignments that maximize an objective function taking constraints into account. However, it is well known that such problems are NP-complete and that more research must be done to obtain feasible and reliable computational approaches. Thus, DCOP emerges as a very promising technique: the search space is decomposed into smaller spaces and agents solve local problems, collaborating in order to achieve a global solution. We show with empirical experiments that MULBS outperforms some of the state-of-the-art algorithms for DCOP, guaranteeing high quality solutions using less computational resources for the distributed meeting scheduling task.     

Factors influencing the formation of elongated morphologies in immiscible polymer blends during melt processing

The morphology of the dispersed phase in immiscible polymer blends plays an important role in the determination of the final physical properties. This paper considers factors that influence the final state of deformation of the dispersed phase, and in particular, the formation of fibers and lamellae. Blends of polyethylene and nylon-6 were extruded by ribbon extrusion at different draw ratios. Prior to single-screw extrusion the materials were blended in a co-rotating twin-screw extruder, and the size of the dispersed phase was studied as a function of the viscosity ratio. As the blends are extruded into ribbons and drawn through the calender rolls, the morphology of the dispersed phase undergoes drastic transformations. The fiber formation is enhanced by increasing the draw ratio. At high draw ratios, long thin fibers are observed. Some biaxial deformation is obtained for the noncompatibilized systems when the extruded materials enter the calender with the maximum closing pressure applied to the rolls. The same effect is observed for the compatibilized systems with lower values of the viscosity ratio. As a general rule, it has been observed that the final dispersed phase deformation is diminished in interfacially compatibilized systems.     

AXIAL PHASES DISTRIBUTION AND HOMOGENIZATION IN THREE-PHASE FLUIDIZED BEDS

We have investigated the axial distribution of the liquid phase in a three-phase fluidized bed in which the particles were glass beads of two different diameters, 710-850 μm and 2 mm. Two methods were used to reduce the axial heterogeneity and homogenize the bed: the use of packing elements and the addition of a small quantity of a high molecular weight polymer. The use of packing elements was shown to be very efficient in controlling phases distribution in the bed. The packing consisted of 1 mm thick steel horizontal plates punched and stretched to obtain parallelogram-shaped openings. The addition of a high molecular weight polyisobutylene (BASF Oppanol B246, M_u, =6.15 Lo⁶) on the phase distribution was also studied. Low polymer concentrations up to 397 ppm (based on the liquid phase) were investigated. The addition of the polymer reduced bubble coalescence and allowed for a better distribution of the phases.     

Property stabilization in filled,drawn polyethylene

Mechanical properties of high density polyethylene (HDPE) extended to draw ratios in the 20–40 range have been determined and compared with corresponding properties of the polymers containing particulates including rutile, carbon black, iron oxide, and mica. Shrinkage of drawn structures was studied to temperatures near the fusion of the polymer host. The degree of interaction at polymer/additive interfaces was varied by surface coating certain of the solids with standard coupling agents. Solids were found to increase tensile moduli and to decrease shrinkage, particularly at higher exposure temperatures. The magnitude of changes due to the presence of solids was shown to depend on the apparent interaction at contacts between host and additive. In a dispersion–force matrix, like HDPE, benefits were optimized when the particulates were amphoteric or neutral, rather than having pronounced acid or base interaction potentials.     

Characterisation and behaviour of Ti/TiO2/noble metal anodes

The morphology, composition and the electrical and electrochemical behaviour of the anodic microporous layer, prepared by the galvanostatic anodisation of Ti after sparking, followed by galvanostatic deposition of Pt or Ir have been investigated. These electrodes are proposed to function as dimensionally stable anodes (DSAs). For Ti/TiO₂/Pt electrodes, Pt is deposited within some of the micropores of the oxide film. In contrast, for Ti/TiO₂/Ir, the metal is deposited preferentially on the top surface. This difference is thought to result from the position of the metal deposition potential with respect to the flat band potential of n-TiO₂. Optical imaging of both types of DSA suggests that only a few sites on the surface are responsible for electron exchange at the DSA-electrolyte interface. C-AFM measurements of Ti/TiO₂/Pt samples subjected to long-term anodic polarisation, suggest that the Ti-noble metal contact is progressively insulated by thickening of the TiO₂ barrier layer, promoting passivation of the DSA. For Ir coated anodes, catalytic activity is directly related to the presence of Ir and to the stability of the catalytic oxide layer. Under Cu electrowinning conditions, the electrochemically formed hydrated Ir oxide was found to be catalytically less stable, than the iridium oxide film subjected to a heat treatment.     

Hepatic Δ9 and Δ6 desaturase activities during the recovery period following carbon tetrachloride poisoningdesaturase activities during the recovery period following carbon tetrachloride poisoning

The liver microsomal Δ⁹ and Δ⁶ desaturase activities have been studied in rats with carbon tetrachloride-induced hepatitis. Immediately after poisoning, significant decreases were observed for both types of desaturase activity. However, recovery kinetics were slower for the Δ⁶ desaturase than for the Δ⁹ desaturase. The activities of NADH-ferricyanide and NADH-cytochrome C reductases, proteins involved in the electron transfers associated with microsomal desaturation, were also measured. There was a fall in both activities after poisoning, but this decrease was less than that of the desaturase activities.