Copper Immobilization on Fe3O4@Agar: An Efficient Superparamagnetic Nanocatalyst for Green Ullmann-Type Cross-Coupling Reaction of Primary and Secondary Amines with Aryl Iodide Derivatives

Journal of Inorganic and Organometallic Polymers and Materials - Immobility of copper on magnetic nanoparticles was performed using surface rectification of Fe3O4 with Agar. The magnetic...     

The medial scaffold of 3D unorganized point clouds

We introduce the notion of the medial scaffold, a hierarchical organization of the medial axis of a 3D shape in the form of a graph constructed from special medial curves connecting special medial points. A key advantage of the scaffold is that it captures the qualitative aspects of shape in a hierarchical and tightly condensed representation. We propose an efficient and exact method for computing the medial scaffold based on a notion of propagation along the scaffold itself, starting from initial sources of the flow and constructing the scaffold during the propagation. We examine this method specifically in the context of an unorganized cloud of points in 3D, e.g., as obtained from laser range finders, which typically involve hundreds of thousands of points, but the ideas are generalizable to data arising from geometrically described surface patches. The computational bottleneck in the propagation-based scheme is in finding the initial sources of the flow. We thus present several ideas to avoid the unnecessary consideration of pairs of points which cannot possibly form a medial point source, such as the "visibility of a point from another given a third point and the interaction of clusters of points. An application of using the medial scaffold for the representation of point samplings of real-life objects is also illustrated     

Guest Editorial: Computational Vision at Brown

International Journal of Computer Vision -     

On the intrinsic reconstruction of shape from its symmetries

The main question we address is: What is the minimal information required to generate closed, nonintersecting planar boundaries? For this paper, we restrict "shape" to this meaning. More precisely, we examine whether the medial axis, together with dynamics, can serve as a language to design shapes and to effect shape changes. We represent the medial axis together with a direction of flow along the axis as the shock graph and examine the reconstruction of shape along each of the three types of medial axis points, A/sub 1//sup 2/, A/sub 1//sup 3/, A/sub 3/, and the associated six types of shock points. First, we show that the tangent and curvature of the medial axis and the speed and acceleration of the shock with respect to time of propagation are sufficient to determine the boundary tangent and curvature at corresponding points of the boundary. This implies that a rather coarse sampling of the symmetry axis, its tangent, curvature, speed, and acceleration is sufficient to regenerate accurately a local neighborhood of shape at regular axis points (A/sub 1//sup 2/). Second, we examine the reconstruction of shape at branch points (A/sub 1//sup 3/) where three regular branches are joined. We show that the three pairs of geometry (that is, curvature) and dynamics (that is, acceleration) must satisfy certain constraints. Finally, we derive similar results for the end points of shock branches (A/sub 3/ points). These formulas completely specify the local reconstruction of a shape from its shock-graph or medial axis and the conditions required to form a coherent shape from the medial axis.     

Drought Occurrence Probability Analysis Using Multivariate Standardized Drought Index and Copula Function Under Climate Change

This study aims to investigate the effect of climate change on the probability of drought occurrence in central Iran. To this end, a new drought index called Multivariate Standardized Drought Index (MSDI) was developed, which is composed of the Standardized Precipitation Evapotranspiration Index (SPEI) and the Standardized Soil Moisture Index (SSI). The required data included precipitation, temperature (from CRU TS), and soil moisture (from the ESA CCA SM product) on a monthly time scale for the 1980–2016 period. Moreover, future climate data were downloaded from CMIP6 models under the latest SSPs-RCPs emission scenarios (SSP1-2.6 and SSP5-8.5) for the 2020–2056 period. Based on the normalized root mean square error (NRMSE), Cramer-von mises statistic (S_n), and Nash Sutcliffe (NS) evaluation criteria, the Galambos and Clayton functions were selected to derive copula-based joint distribution functions in both periods. The results showed that more severe and longer droughts will occur in the future compared to the historical period and in particular under the SSP5-8.5 scenario. From the derived joint return period, a drought event with defined severity or duration will happen in a shorter return period as compared with the historical period. In other words, the joint return period indicated a higher probability of drought occurrence in the future period. Moreover, the joint return period analysis revealed that the return period of mild droughts will remain the same, while it will decrease for extreme droughts in the future.

     

Micromorphology analysis of TiO2 thin films by atomic force microscopy images: The influence of postannealing

This work describes an analysis of titanium dioxide (TiO₂) thin films prepared on silicon substrates by direct current (DC) planar magnetron sputtering system in O₂/Ar atmosphere in correlation with three‐dimensional (3D) surface characterization using atomic force microscopy (AFM). The samples were grown at temperatures 200, 300, and 400°C on silicon substrate using the same deposition time (30 min) and were distributed into four groups: Group I (as‐deposited samples), Group II (samples annealed at 200°C), Group III (samples annealed at 300°C), and Group IV (samples annealed at 400°C). AFM images with a size of 0.95 μm × 0.95 μm were recorded with a scanning resolution of 256 × 256 pixels. Stereometric analysis was carried out on the basis of AFM data, and the surface topography was described according to ISO 25178‐2:2012 and American Society of Mechanical Engineers (ASME) B46.1‐2009 standards. The maximum and minimum root mean square roughnesses were observed in surfaces of Group II (Sq = 7.96 ± 0.1 nm) and Group IV (Sq = 3.87 ± 0.1 nm), respectively.     

Improving image inpainting quality by a new SVD-based decomposition

Multimedia Tools and Applications - In this paper, we present a new algorithm for image inpainting using structure and texture information. Our image decomposition to texture and structure is...     

Symmetry Maps of Free-Form Curve Segments via Wave Propagation

This paper presents an approach for computing the symmetries (skeletons) of an edge map consisting of a collection of curve segments. This approach is a combination of analytic computations in the style of computational geometry and discrete propagations on a grid in the style of the numerical solutions of PDE's. Specifically, waves from each of the initial curve segments are initialized and propagated as a discrete wavefront along discrete directions. In addition, to avoid error built up due to the discrete nature of propagation, shockwaves are detected and explicitly propagated along a secondary dynamic grid. The propagation of shockwaves, integrated with the propagation of the wavefront along discrete directions, leads to an exact simulation of propagation by the Eikonal equation. The resulting symmetries are simply the collection of shockwaves formed in this process which can be manipulated locally, exactly, and efficiently under local changes in an edge map (gap completion, removal of spurious elements, etc). The ability to express grouping operations in the language of symmetry maps makes it an appropriate intermediate representation between low-level edge maps and high level object hypotheses.